Polymer compositions and nonwoven materials prepared therefrom
The invention relates to a fiber comprising a blend of 10-50 wt % of a polymer blend modifier and 50-90 wt % of a propylene-based elastomer; 5-50 wt % of a propylene-modifier and 50-95 wt % of a propylene-based elastomer; and 5-35 wt % of a polymer blend modifier and 65-95 wt % of a propylene-modifier. The polymer blend modifier has a first propylene-based polymer and a different second propylene-based polymer that is a propylene homopolymer or a copolymer of propylene and ethylene and a C 4 to C 10 alpha-olefin. The propylene-modifier is a propylene homopolymer or a copolymer of propylene with 0.5-4 wt % ethylene or C 4 to C 10 alpha-olefins. The propylene-based elastomer is propylene and 5-25 wt % of one or more C 2 to C 4 -C 12 alpha-olefins and has a triad tacticity greater than 90% and a heat of fusion less than 75 J/g.
1. A fiber comprising a polymer blend of
(a) about 10 to about 50 wt % of a polymer blend modifier, comprising a first propylene-based polymer, wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin, and a second propylene-based polymer, wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin, wherein the second propylene-based polymer is different than the first propylene-based polymer,
wherein the polymer blend modifier has a MFR of greater than about 1,000 g/10 min to less than about 10,000 g/10 min; and
(b) about 50 to about 90 wt % of a propylene-based elastomer, having a MFR of less than about 100 g/10 min.
2. The fiber of claim 1 , further comprising a propylene-modifier, comprising a homopolymer of propylene or a copolymer of propylene with from about 0.5 to about 4 wt % ethylene or C 4 to C 10 alpha-olefin comonomer derived units.
3. The fiber of claim 1 , wherein the propylene-based elastomer comprises propylene and from about 5 to about 25 wt % units derived from one or more C 2 or C 4 -C 12 alpha-olefins and has a triad tacticity greater than about 90% and a heat of fusion less than about 75 J/g.
4. The fiber of claim 1 , wherein the propylene-modifier has a MFR of greater than about 100 g/10 min to less than about 10,000 g/10 min.
5. The fiber of claim 1 , wherein the propylene-based elastomer has a polydispersity index of about 1.8 to about 3.
6. The fiber of claim 1 , wherein the polymer blend modifier has a melt viscosity of about 800 to about 15,000 cP at 190° C.; and wherein the propylene-based elastomer has a melt viscosity of about 50,000 to about 10,000,000 cP at 190° C.
7. A fiber comprising a polymer blend of
(a) about 5 to about 35 wt % of a polymer blend modifier, comprising a first propylene-based polymer wherein the first propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin and a second propylene-based polymer wherein the second propylene-based polymer is a homopolymer of propylene or a copolymer of propylene and ethylene or a C 4 to C 10 alpha-olefin, wherein the second propylene-based polymer is different than the first propylene-based polymer,
wherein the polymer blend modifier has a MFR of greater than about 1,000 g/10 min to less than about 10,000 g/10 min; and
(b) about 65 to about 95 wt % of a propylene-modifier,
wherein the propylene-modifier has a MFR of greater than about 100 g/10 min to less than about 10,000 g/10 min.
8. The fiber of claim 7 , wherein the polymer blend modifier has an Mw of about 10,000 g/mol to about 150,000 g/mol.
9. The fiber of claim 7 , wherein the polymer blend modifier has a polydispersity index of about 1.5 to about 6.
10. The fiber of claim 7 , wherein the polymer blend modifier has a melt viscosity of about 1,000 to about 10,000 cP at 190° C.
11. The fiber of claim 7 , wherein the fiber comprises from about 5 to about 30 wt % of the polymer blend modifier.
12. A fiber comprising a polymer blend of
(a) about 5 to about 50 wt % of a propylene-modifier, comprising a homopolymer of propylene or a copolymer or propylene units with from about 0.5 to about 4 wt % ethylene or C 4 to C 10 alpha-olefin comonomer derived units; and
(b) about 50 to about 95 wt % of a propylene-based elastomer, comprising propylene and from about 5 to about 25 wt % units derived from one or more C 2 to C 4 -C 12 alpha-olefins and has a triad tacticity greater than about 90% and a heat of fusion less than about 75 J/g.
13. The fiber of claim 12 , wherein the propylene-modifier has a MFR of greater than about 100 g/10 min to less than about 10,000 g/10 min.
14. The fiber of claim 12 , wherein the propylene-modifier is present in the amount of about 5 to about 15 wt % based on the polymer blend.
15. The fiber of claim 12 , wherein the propylene-based elastomer has a polydispersity index of about 1.8 to about 3.
16. The fiber of claim 12 , wherein the propylene-modifier has a melt viscosity of about 2,000 to about 20,000 cP at 190° C.
17. The fiber of claim 12 , wherein the propylene-modifier is visbroken or a peroxide masterbatch.
18. The fiber of claim 12 , wherein the fiber has a monocomponent structure.
19. The fiber of claim 12 , wherein the polymer blend is visbroken or a peroxide masterbatch.
20. A nonwoven composition comprising the fiber of claim 12 .
21. The fiber of claim 12 , further comprising a slip additive.
22. The fiber of claim 12 , wherein the polymer blend has a melt flow rate of about 100 g/10 min to about 5,000 g/10 min.