Aluminum alloy brazing sheet having high strength, high corrosion resistance and high material elongation, and method of manufacturing heat exchanger
An aluminum alloy brazing sheet has high strength, corrosion resistance and elongation, and includes an aluminum alloy clad material. The material includes a core material, one surface of which is clad with a sacrificial material and an other surface of which is clad with an Al—Si-based or Al—Si—Zn-based brazing filler metal. The core material has a composition containing 1.3 to 2.0% Mn, 0.6 to 1.3% Si, 0.1 to 0.5% Fe and 0.7 to 1.3% Cu, by mass, with the balance Al and impurities. The sacrificial material has a composition containing more than 4.0% to 8.0% Zn, 0.7 to 2.0% Mn, 0.3 to 1.0% Si, 0.3 to 1.0% Fe and 0.05 to 0.3% Ti, by mass, with the balance Al and impurities. At least the core material has a lamellar crystal grain structure. Elongation of material is at least 4% and a tensile strength after brazing is at least 170 MPa.
1. An aluminum alloy brazing sheet configured to be subjected to brazing, the brazing sheet comprising an aluminum alloy clad material comprising a core material having a first surface and a second surface, the first surface of the core material being clad with a sacrificial material, and the second surface of the core material being clad with a brazing filler metal which is Al—Si-based or Al—Si—Zn-based, wherein:
the core material has a composition containing 1.3 to 2.0% Mn, 0.6 to 1.3% Si, 0.2 to 0.5% Fe and 0.85 to 1.3% Cu, by mass, with the balance comprising Al and unavoidable impurities;
the sacrificial material has a composition containing more than 4.0% and up to and including 8.0% Zn, 0.7 to 2.0% Mn, 0.3 to 1.0% Si, 0.3 to 1.0% Fe and 0.05 to 0.3% Ti, by mass, with the balance comprising Al and unavoidable impurities;
the core material has a lamellar crystal grain structure;
the brazing sheet has an elongation of at least 4%; and
the brazing sheet has a tensile strength of at least 170 MPa after a heat treatment corresponding to brazing, the heat treatment comprising heating the brazing sheet of 600° C. in about 7 minutes, maintaining the brazing sheet at 600° C. for 3 minutes, and then cooling the brazing sheet at a cooling rate of 100° C./min.
2. The aluminum alloy brazing sheet according to claim 1 , wherein the crystal grain size of the core material in a longitudinal section parallel to a rolling direction after the heat treatment corresponding to brazing is in a range of 30 to 200 μm.
3. The aluminum alloy brazing sheet according to claim 1 , wherein the core material, before brazing, comprises second phase particles having a crystal grain size of 0.2 to 0.7 μm in terms of an equivalent circle diameter, which have a density of 1 to 30 pieces/μm 2 .
4. The aluminum alloy brazing sheet according to claim 1 , wherein the aluminum alloy brazing sheet is a heat exchanger member.
5. The aluminum alloy brazing sheet according to claim 2 , wherein the core material, before brazing, comprises second phase particles having a crystal grain size of 0.2 to 0.7 μm in terms of an equivalent circle diameter, which have a density of 1 to 30 pieces/μm 2 .
6. The aluminum alloy brazing sheet according to claim 2 , wherein the aluminum alloy brazing sheet is a heat exchanger member.
7. The aluminum alloy brazing sheet according to claim 3 , wherein the aluminum alloy brazing sheet is a heat exchanger member.
8. The aluminum alloy brazing sheet according to claim 5 , wherein the aluminum alloy brazing sheet is a heat exchanger member.
9. A method of manufacturing a heat exchanger, the method comprising:
forming the aluminum alloy brazing sheet according to claim 1 into a first heat exchanger member; and
brazing said heat exchanger member and a second heat exchanger member.