Electrophotographic printing and foiling

1. A method of electrostatic printing and foiling comprising:

forming a coloured toner image on a print substrate by electrostatically printing an electrostatic ink comprising a first resin component comprising an ethylene acrylic acid resin, an ethylene methacrylic acid resin or combinations thereof;

forming an adhesive toner image disposed on the coloured toner image on the print substrate by electrostatically printing a liquid electro photographic (LEP) printing composition comprising a first resin component comprising an ethylene acrylic acid resin, an ethylene methacrylic acid resin or combinations thereof, and a second resin component present in an amount of about 20% to about 80% by weight of total solids content of the LEP printing composition, the second resin component having a melting point of from about 50° C. to about 75° C., which is below the melting point of the first resin component; and

forming a foiled image disposed on the adhesive toner image by heating the print substrate to at least partially melt the adhesive toner image and applying a foiling material to the print substrate such that the foiling material adheres to the at least partially molten adhesive toner image.

2. A method according to claim 1 , wherein the second resin component is present in in the LEP printing composition in an amount of at least 40% by weight of total solids content of the composition.

3. A method according to claim 1 , wherein the first resin component has a melting point from about 80° C. to about 120° C.

4. A method according to claim 1 , wherein the second resin component has a melting point from about 50° C. to about 75° C.

5. A method according to claim 1 , wherein the second resin component is a resin selected from an urethane acrylate, a copolyester, and an ethylene vinyl acetate resin.

6. A method according to claim 1 , wherein a foiling film is applied to the print substrate to apply a foiling material to the least partially molten adhesive toner image to form a foiled image.

7. A method according to claim 6 , further comprising cooling the print substrate and removal of the foiling film from the foiled image on the print substrate.

8. An electrostatic printing and foiling apparatus comprising:

at least one coloured toner reservoir containing a coloured toner being an electrostatic ink comprising a first resin component comprising an ethylene acrylic acid resin, an ethylene methacrylic acid resin or combinations thereof;

an adhesive toner reservoir containing an adhesive toner comprising a liquid electro photographic (LEP) printing composition comprising a first resin component comprising an ethylene acrylic acid resin, an ethylene methacrylic acid resin or combinations thereof; and a second resin component present in an amount of about 20% to about 80% by weight of total solids content of the composition, the second resin component having a melting point of from about 50° C. to about 75° C., which is below the melting point of the first resin component;

a photoconductive member having a surface on which can be created a latent electrostatic image;

a print substrate input station;

a foiling station; and

a print substrate output station,

wherein, the electrostatic printing apparatus is adapted, in use, on contacting the surface of the photoconductive member with the coloured toner and/or the adhesive toner to form a coloured toner image and/or an adhesive toner image on the surface of the latent electrostatic image, then transfer the coloured toner image and/or the adhesive toner image to a print substrate delivered from a print substrate input station, then transfer the print substrate through the foiling station, at which the adhesive toner image is at least partially melted and a foiling material applied to the print substrate such that the foiling material adheres to the at least partially molten adhesive toner image, and then transfer the print substrate to the print substrate output station.

9. An apparatus according to claim 8 , wherein the apparatus is adapted in use to transfer a coloured toner image and an adhesive toner image to a print substrate such that the adhesive toner image is disposed on the coloured toner image, and on transfer of the print substrate through the foiling station foiling material adheres to the at least partially molten adhesive toner image without adhering to the coloured toner image.

10. An apparatus according to claim 8 , wherein the foiling station comprises a temperature controller to control the temperature to which the print substrate is heated on passing through the foiling station to at least partially melt the adhesive toner image.

11. An apparatus according to claim 8 , wherein the foiling station comprises a pressure controller to control pressure applied to the print substrate as the print substrate passes through the foiling station.

12. An apparatus according to claim 8 , wherein the foiling station comprises a plurality rollers for heating and applying pressure to the print substrate.

13. An apparatus according to claim 8 , wherein the foiling station comprises a foiling film feed to supply a foiling film to the print substrate as the print passes through the foiling station to apply a foiling material to the adhesive toner image.

14. An apparatus according to claim 11 , wherein the foiling station comprises a temperature controller configured to independently control the temperature of each of the plurality of rollers to allow the temperature of the print substrate to be gradually raised as the print substrate passes through the foiling station to at least partially melt the adhesive toner image.