Photocurable composition, cured product formed from photocurable composition, and method for manufacturing said cured product

1. A photocurable composition comprising:

A. a difunctional (meth)acrylate ester monomer, wherein the glass transition temperature of a polymer formed only from said monomer is 20° C. or higher;

B. a polyrotaxane comprising a pseudopolyrotaxane, which has a linear molecule and a cyclic molecule(s) in which the linear molecule is included in a cavity (cavities) of the cyclic molecule(s) in a skewered manner, and capping groups, each of which locates at each end of the pseudopolyrotaxane in order to prevent the dissociation of the cyclic molecule(s), wherein the cyclic molecule has a (meth)acrylic group; and

C. a photopolymerization initiator;

wherein a weight ratio of the A. difunctional (meth)acrylate ester monomer to the B. polyrotaxane, that is, A:B, is 100:0.5 to 100:35.

2. The composition according to claim 1 , wherein a viscosity of the composition at 25° C. is 100,000 mPa·s or less.

3. The composition according to claim 1 , further comprising at least one selected from the group consisting of metal oxides, metal chlorides, metal carbonates, metal phosphates, carbon fine particles, and resin fine particles.

4. The composition according to claim 1 , wherein the A. difunctional (meth)acrylate ester monomer is derived from A-1. two molecules each comprising a monofunctional (meth)acrylic group having an amine or hydroxyl group; and A-2. one molecule of dioxiranes, dioxetanes, diisocyanates, or carboxylic dianhydrides.

5. The composition according to claim 1 , wherein the A. difunctional (meth)acrylate ester monomer is a monomer represented by any one of the following Formulae I to III:

wherein R 21 and R 22 each independently represents a hydrogen atom or a methyl group;

R 11 and R 12 each independently represents one selected from the group consisting of a linear or branched alkylene group having 2 to 18 carbon atoms, a cycloalkylene group, which may have (a) substituent(s), having 3 to 18 carbon atoms, an arylene group, which may have (a) substituent(s), having 6 to 18 carbon atoms, a (poly)alkyleneoxy group, and a (poly)ethyleneamine group;

X 1 to X 3 each independently represents one selected from the group consisting of a linear or branched alkylene group having 2 to 18 carbon atoms (when the linear or branched alkylene group has 3 or more carbon atoms, a carbon(s) on the linear chain or branched chain may be substituted with an oxygen(s) to form an ether bond, and one or more of hydrogens of the alkylene group may be substituted with a hydroxyl group or a carboxyl group), a cycloalkylene group, which may have (a) substituent(s), having 3 to 18 carbon atoms, and an arylene group, which may have (a) substituent(s), having 6 to 18 carbon atoms; and

Y 11 , Y 12 , Y 21 , Y 22 , Y 31 , and Y 32 each independently represents an —O— group or an —NH— group.

6. The composition according to claim 1 , wherein an amount of the (meth)acrylic group of the B. polyrotaxane is 0.015 to 2.0 mmol in 1 g of the B. polyrotaxane.

7. The composition according to claim 1 , wherein the cyclic molecule of the B. polyrotaxane has a ring-opening polymerization site formed from lactone monomers.

8. A cured product formed by photo-irradiating and curing the photocurable composition according to claim 1 .

9. The cured product according to claim 8 , wherein a tensile elastic modulus of the cured product is 100 MPa or more.

10. The cured product according to claim 8 , wherein an impact strength ratio determined by an Izod impact strength test of the cured product (M) according to claim 9 to the cured product (N) formed from components excluding the B. polyrotaxane from the composition constituting the cured product ((the impact strength of M)/(the impact strength of N)) is 1.10 or more.

11. A method for manufacturing a cured product, comprising the steps of:

i) preparing the photocurable composition according to claim 1 ;

ii) forming the composition in a predetermined shape; and

iii) irradiating the resulting predetermined shape with light;

to obtain the cured product.