IP Library Granted Patent US 10,392,678
Granted Patent B2
US 10,392,678 · App. 15/527,241 · Granted Aug 27, 2019

Energy efficient integrated process for production of metals or alloys

Inventor: Havard Ingvald Moe (Oslo, NO)
Assignee: ELKEM ASA
C22B5/10C10B53/02C10L5/442C10L5/447C22B4/00C22B4/08Y02E50/14Y02P10/122Y02P10/132
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Quick Facts
Patent No.
US 10,392,678
App. No.
15/527,241
Granted
Aug 27, 2019
Kind
B2
Abstract

A method for the energy efficient production of metals and alloys by carbothermic reduction of minerals and ores in electric reduction reactors is disclosed. The method includes conveying a wood containing material to at least one pyrolysis step for producing charcoal; conveying the produced charcoal, possibly other carbon-containing reduction materials and metal containing raw materials to the at least one reactor for producing metal or alloy; conveying off-gas from the at least one pyrolysis step and off-gas from the at least one reactor to at least one energy recovery step.

Claims (29)

1. Method for the energy efficient production of metals and alloys by carbothermic reduction of minerals and ores in electric reduction reactors said method comprising at least the following steps:

conveying a wood containing material to a pyrolysis reactor to at least one pyrolysis step for producing charcoal and off-gas;

conveying said produced charcoal, possibly other carbon-containing reduction materials, and metal containing raw materials to at least one electric reduction reactor for producing metal or alloy and off-gas;

conveying said produced off-gas from said at least one pyrolysis step to a second gas processing reactor and conveying said produced off-gas from said at least one electric reduction reactor for producing metal or alloy to a first gas processing reactor to process the respective off-gasses;

conveying the respectively processed off-gasses from the previous step to a common energy recovery plant to conduct at least one energy recovery step, wherein the energy recovery plant comprises at least a combustion chamber, a heat exchanger, a steam turbine and an electric generator, wherein electric energy produced in the energy recovery step is used to supply at least a part of the electric energy for the electric reduction reactor,

wherein the pyrolysis reactor is in direct connection with the at least one electric reduction reactor for producing metal or alloy,

wherein solid particles are extracted from said off-gas from said at least one electric reduction reactor conveyed to the first gas processing reactor for the off-gas processing step, and

wherein said metal and alloy comprises at least silicon or ferrosilicon.

2. Method according to claim 1 , wherein the energy recovery step comprises a combined cycle gas turbine power generation system.

3. Method according to claim 1 , wherein said off-gas from said at least one pyrolysis step prior to the energy recovery step is transferred to the second gas processing reactor for a gas and oil processing step for producing bio-oil and synthesis gas.

4. Method according to claim 3 , wherein produced synthesis gas from said gas and oil processing step is transferred to said at least one energy recovery step.

5. Method according to claim 3 , wherein said bio-oil from said gas and oil processing step is transferred to a refining step.

6. Method according to claim 3 , wherein said bio-oil from said gas and oil processing step is transferred to the energy recovery step.

7. Method according to claim 1 , wherein said off-gas from said at least one pyrolysis step is transferred to a gas and oil processing step for producing synthesis gas and/or bio-oil and said off-gas from said at least one electric reduction reactor is transferred to an off-gas processing step in which solid particles are extracted from the off-gas.

8. Method according to claim 1 , wherein part of the produced energy in the energy recovery step is used as a heating source for the wood pyrolysis step.

9. Method according to claim 1 , wherein the reactor is an open reactor.

10. Method according to claim 1 , wherein the reactor is a closed reactor.

11. Method for the energy efficient production of metals and alloys by carbothermic reduction of minerals and ores in electric reduction reactors said method comprising at least the following steps:

conveying a wood containing material to a pyrolysis reactor to at least one pyrolysis step for producing charcoal and off-gas;

conveying said produced charcoal, possibly other carbon-containing reduction materials, and metal containing raw materials to at least one electric reduction reactor for producing metal or alloy and off-gas;

conveying said produced off-gas from said at least one pyrolysis step and conveying said produced off-gas from said at least one electric reduction reactor for producing metal or alloy to common energy recovery plant to conduct at least one energy recovery step, wherein the energy recovery plant comprises at least a combustion chamber, a heat exchanger, a steam turbine and an electric generator, wherein the electric energy produced in the energy recovery step is used to supply at least a part of the electric energy for the electric reduction reactor,

wherein the pyrolysis reactor is in direct connection with the at least one electric reduction reactor for producing metal or alloy,

wherein said produced off-gas from said at least one electric reduction reactor, prior to the energy recovery step, is transferred to a gas processing reactor for a gas processing step in which solid particles are extracted from the off-gas, and

wherein said metal and alloy comprises at least silicon or ferrosilicon.

12. Method according to claim 11 , wherein said produced off-gas from said at least one pyrolysis step, prior to the energy recovery step, is transferred to a gas and processing reactor for a gas and oil processing step for producing synthesis gas and/or bio-oil, and

wherein said produced off-gas from said at least one electric reduction reactor, prior to the energy recovery step, is transferred to a gas processing reactor for an off-gas processing step in which solid particles are extracted from the off-gas.

13. Method according to claim 11 , wherein part of the produced electric energy in the energy recovery step is used as a heating source for the wood pyrolysis step.

14. Method according to claim 11 , wherein the reactor is an open reactor.

15. Method according to claim 11 , wherein the reactor is a closed reactor.

Assignments (2)
CHANGE OF NAME Recorded Mar 19, 2019
From: ELKEM AS
To: ELKEM ASA
Reel/Frame 048639/0477 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 16, 2017
From: MOE, HAVARD INGVALD
To: ELKEM AS
Reel/Frame 042398/0752 →
Priority Claims (1)
NO 20141486 · Dec 9, 2014 · national
Continuity (1)
Related Publication 20170356064A1 · Dec 14, 2017