Composition for window film, flexible window film formed therefrom, and flexible display device comprising same
Provided are a composition for a window film, a flexible window film formed therefrom, and a flexible display device comprising the same, wherein the composition for a window film, contains: (1) a siloxane resin comprising (R 1 SiO 3/2 ) x (R 2 SiO 3/2 ) y (wherein, R 1 is a cross-linkable functional group, R 2 is a UV absorbing functional group or a UV absorbing functional group-containing group, and 0<x<1, 0<y<1, x+y=1) and (2) an initiator.
1. A composition for window films, comprising: a siloxane resin comprising a compound represented by Formula 1; and an initiator:
(R 1 SiO 3/2 ) x (R 2 SiO 3/2 ) y <Formula 1>
wherein R 1 is a crosslinkable functional group; R 2 is a UV absorption functional group or a UV absorption functional group-containing group; and 0<x<1, 0<y<1, and x+y=1, and
wherein R 2 comprises a group selected from an unsubstituted or substituted benzotriazole group, an unsubstituted or substituted benzophenone group, an unsubstituted or substituted hydroxybenzophenone group, an unsubstituted or substituted triazine group, an unsubstituted or substituted salicylate group, an unsubstituted or substituted cyanoacrylate group, an unsubstituted or substituted oxanilide group, an unsubstituted or substituted hydroxyphenyltriazine group, an unsubstituted or substituted hydroxyphenylbenzotriazole group, and an unsubstituted or substituted hydroxyphenylbenzophenone group.
2. The composition for window films according to claim 1 , wherein the siloxane resin comprises at least one of compounds represented by Formulae 1-1 to 1-12:
(EcSiO 3/2 ) x (RaSiO 3/2 ) y <Formula 1-1>
(EcSiO 3/2 ) x (RbSiO 3/2 ) y <Formula 1-2>
(ECSiO 3/2 ) x (RCSiO 3/2 ) y <Formula 1-3>
(EcSiO 3/2 ) x (RdSiO 3/2 ) y <Formula 1-4>
(GpSiO 3/2 ) x (RaSiO 3/2 ) y <Formula 1-5>
(GpSiO 3/2 ) x (RbSiO 3/2 ) y <Formula 1-6>
(GpSiO 3/2 ) x (RCSiO 3/2 ) y <Formula 1-7>
(GpSiO 3/2 ) x (RdSiO 3/2 ) y <Formula 1-8>
(OpSiO 3/2 ) x (RaSiO 3/2 ) y <Formula 1-9>
(OpSiO 3/2 ) x (RbSiO 3/2 ) y <Formula 1-10>
(OpSiO 3/2 ) x (RCSiO 3/2 ) y <Formula 1-11>
(OpSiO 3/2 ) x (RdSiO 3/2 ) y <Formula 1-12>
wherein Ec is a (3,4-epoxycyclohexyl)ethyl group, Gp is a 3-glycidoxypropyl group, Op is a 3-oxetanylpropyl group, and Ra is a compound represented by Formula i, Rb is a compound represented by Formula ii, Rc is a compound represented by Formula iii, and Rd is a compound represented by Formula iv:
wherein * is a linking site, 0<x<1, 0<y<1, and x+y=1.
3. The composition for window films according to claim 1 , further comprising: a crosslinking agent.
4. The composition for window films according to claim 3 , wherein the crosslinking agent comprises at least one of a non-cyclic aliphatic epoxy monomer, a cyclic aliphatic epoxy monomer, an aromatic epoxy monomer, a hydrogenated aromatic epoxy monomer, and an oxetane monomer.
5. A flexible window film comprising:
a base layer, and
a coating layer formed on one surface of the base layer, the coating layer formed of a composition for window films, the composition comprising: a siloxane resin comprising a compound represented by Formula 1; and an initiator:
(R 1 SiO 3/2 ) x (R 2 SiO 3/2 ) y <Formula 1>
wherein R 1 is a crosslinkable functional group;
R 2 is a UV absorption functional group or a UV absorption functional group-containing group; and
0<x<1, 0<y<1, and x+y=1.
6. The flexible window film according to claim 5 , further comprising: an adhesive layer formed on the other surface of the base layer.
7. The flexible window film according to claim 5 , wherein the flexible window film has a pencil hardness of 7H or higher, a radius of curvature of 5.0 mm or less, and ΔY.I. of 5.0 or less.
8. A flexible display comprising a flexible window film, the flexible window film comprising:
a base layer, and
a coating layer formed on one surface of the base layer, the coating layer formed of a composition for window films, the composition comprising: a siloxane resin comprising a compound represented by Formula 1; and an initiator:
(R 1 SiO 3/2 ) x (R 2 SiO 3/2 ) y<Formula 1>
wherein in Formula 1, R 1 is a crosslinkable functional group;
R 2 is a UV absorption functional group or a UV absorption functional group-containing group; and
0<x<1, 0<y<1, and x+y=1.
9. The flexible display according to claim 8 , comprising: a display unit; an adhesive layer formed on the display unit; a polarizing plate formed on the adhesive layer; a touchscreen panel formed on the polarizing plate; and the flexible display film formed on the touchscreen panel.
10. The flexible display according to claim 8 , comprising: a display unit; a touchscreen panel formed on the display unit; a polarizing plate formed on the touchscreen panel; and the flexible display film formed on the polarizing plate.
11. The flexible display according to claim 8 , comprising: a display unit; an adhesive layer formed on the display unit; and the flexible window film formed on the adhesive layer.
12. The flexible display according to claim 11 , wherein the display unit further comprises a polarizing plate disposed at an upper or lower side thereof.