Light emitting device having at least two quantum dot light emitting layers and fabricating method thereof
A light emitting device, a fabricating method thereof, and a display device are disclosed. In the light emitting device, a light emitting functional layer includes at least two QD light emitting layers which emit light of different colors, and a transparent insulating layer which is arranged between any two neighboring QD light emitting layers. The light emitting device has a reduced power consumption, and the problem of shift in color of the emitted light due to high-energy excitons transfer is overcome.
1. A light emitting device comprising:
an anode,
a cathode arranged opposite to the anode,
a hole transport layer arranged close to the anode,
an electron transport layer arranged close to the cathode,
a light emitting functional layer arranged between the hole transport layer and the electron transport layer,
wherein the light emitting functional layer comprises at least two quantum dot (QD) light emitting layers which emit light of different colors; and
a transparent insulating layer arranged between any two neighboring QD light emitting layers.
2. The light emitting device of claim 1 , wherein among the at least two QD light emitting layers which emit light of different colors, as compared with a QD light emitting layer which emits light at a relatively long wavelength, a QD light emitting layer which emits light at a relatively short wavelength is arranged closer to a light exit side of the light emitting device.
3. The light emitting device of claim 2 , wherein the at least two QD light emitting layers which emit light of different colors comprise a blue light QD light emitting layer and a yellow light QD light emitting layer.
4. The light emitting device of claim 3 , wherein as compared with the yellow light QD light emitting layer, the blue light QDs layer is arranged closer to the light exit side.
5. The light emitting device of claim 2 , wherein the at least two QD light emitting layers which emit light of different colors comprise a blue light QD light emitting layer, a green light QD light emitting layer, and a red light QD light emitting layer.
6. The light emitting device of claim 5 , wherein as compared with the green light QD light emitting layer and the red light QD light emitting layer, the blue light QDs layer is arranged closer to the light exit side.
7. The light emitting device of claim 1 , wherein one of the anode and the cathode is a transparent electrode, and the light emitted by the QD light emitting layer exits through the transparent electrode.
8. The light emitting device of claim 1 , wherein the transparent insulating layer comprises at least one of PMMA, CsCO 3 , Ba(OH) 2 .
9. The light emitting device of claim 1 , wherein the transparent insulating layer has a thickness of about 5-100 nm.
10. The light emitting device of claim 1 , wherein the hole transport layer comprises at least one of poly[3,4-ethylenedioxythiophene]-Polystyrene sulfonic acid, NiO, MoO 3 , WO 3 , poly[9-vinylcarbazole monomer], poly[(9,9-dioctylfluorenyl-2,7-diyl)-co-(4,4′-(N-(4-sec-butyl phenyl)diphenylamine)], poly(N,N′-bis(4-butylphenyl)-N,N′-bisphenyl)benzidine, 4,4′-Bis(N-carbazolyl)-1,1′-biphenyl, and N,N′-Di(1-naphthyl)-N,N′-diphenyl-(1,1′-biphenyl)-4,4′-diamine.
11. The light emitting device of claim 1 , wherein the electron transport layer comprises at least a semiconductor material selected from TiO 2 , ZnO and SnO 2 ; or at least a semiconductor material selected from TiO 2 , ZnO and SnO 2 which is doped with at least a metallic ion selected from Al, Mg and Ag.
12. The light emitting device of claim 3 , wherein the blue light QD light emitting layer comprises at least a semiconductor nano-crystal selected from II-VI semiconductor nano-crystal, semiconductor nano-crystal, III-V semiconductor nano-crystal, and semiconductor nano-crystal.
13. The light emitting device of claim 3 , wherein the yellow light QD light emitting layer comprises at least a semiconductor nano-crystal selected from II-VI semiconductor nano-crystal, semiconductor nano-crystal, III-V semiconductor nano-crystal, and semiconductor nano-crystal which is doped with at least a metallic ion selected from Cu, Mn, and Ag.
14. A display device comprising: the light emitting device of claim 1 .
15. A method for fabricating a light emitting device comprising: forming an anode, a hole transport layer, a light emitting functional layer, an electron transport layer and a cathode in this order, wherein forming the light emitting functional layer comprises
forming at least two quantum dot (QD) light emitting layers which emit light of different colors; and
forming a transparent insulating layer which is arranged between any two neighboring QD light emitting layers.
16. The method of claim 15 , wherein the QD light emitting layers are formed by any one of spin coating, micro-contact printing, ink jet printing, and roll-to-roll printing.
17. The method of claim 15 , wherein the anode is directly formed on the base plate, and prior to forming the hole transport layer close to the anode, the method further comprises:
performing a surface treatment on the anode, so that the anode has a surface profile arithmetic average Ra<2 nm or a distance between the highest point and the lowest point in the surface profile of the anode Rmax<20 nm.
18. The method of claim 15 , wherein the anode is directly formed on the base plate, and prior to forming the hole transport layer close to the anode, the method further comprises:
performing a plasma treatment or UV radiation treatment on the anode to increase work function of the anode.
19. The method of claim 15 , wherein the cathode is directly formed on the base plate, and prior to forming the electron transport layer close to the cathode, the method further comprises:
performing a surface treatment on the formed cathode, so that the cathode has a surface profile arithmetic average Ra<2 nm or a distance between the highest point and the lowest point in the surface profile of the cathode Rmax<20 nm.