IP Library Granted Patent US 10,249,572
Granted Patent B2
US 10,249,572 · App. 15/536,185 · Granted Apr 2, 2019

Method for electromagnetic shielding and thermal management of active components

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Quick Facts
Patent No.
US 10,249,572
App. No.
15/536,185
Granted
Apr 2, 2019
Kind
B2
Abstract

The present invention concerns a method for forming a metal layer for electromagnetic shielding and thermal management of active components, preferably by wet chemical metal plating, using an adhesion promotion layer on the layer of molding compound and forming at least one metal layer on the adhesion promotion layer or forming at least one metal layer on the adhesion promotion layer by wet chemical metal plating processes.

Claims (39)

1. Method for forming a metal layer for electromagnetic shielding and thermal management of active components, comprising the following steps

(i) providing at least one active component, said active component having a front side comprising at least one chip encased by a layer of molding compound, a back side and side walls;

(ii) forming on the back side a protective layer selected from a layer formed by lamination of an adhesive tape, a UV peelable tape and a layer of temporary ink;

(iii) forming on the front side and optionally on the side walls an adhesion promotion layer;

(iv) forming at least one metal layer on the adhesion promotion layer or

forming at least one metal layer on the adhesion promotion layer by wet chemical metal plating processes,

(v) heating of the at least one metal plated layer to a temperature of between 100° C. and 300° C.,

wherein the protective layer is removed after step (iv) or (v).

2. Method of claim 1 , wherein the back side of the active component comprises electrical interconnects or I/Os with optional solder balls.

3. Method of claim 1 , wherein forming an adhesion promotion layer applied according to step (iii) comprises

iiia. depositing on the layer of molding compound a layer of silane based adhesion promoter.

4. Method according to claim 3 , wherein the silane based adhesion promoter is an organosilane compound selected from the group represented by the formula

A (4-x) SiB x

wherein

each A is independently a hydrolyzable group,

x is 1 to 3, and

each B is independently selected from the group consisting of C 1 -C 20 alkyl, aryl, amino aryl and a functional group represented by the formula

C n H 2n X,

wherein

n is from 0 to 15, and

X is selected from the group consisting of amino, amido, hydroxy, alkoxy, halo, mercapto, carboxy, carboxy ester, carboxamide, thiocarboxamide, acyl, vinyl, allyl, styryl, epoxy, epoxycyclohexyl, glycidoxy, isocyanato, thiocyanato, thioisocyanato, ureido, thioureido, guanidino, thioglycidoxy, acryloxy, methacryloxy groups; or X is a residue of a carboxy ester; or X is Si(OR) 3 , and wherein R is a C 1 -C 5 alkyl group.

5. Method according to claim 4 wherein the hydrolyzable group A is selected from the group consisting of —OH, —OR 1 and wherein R 1 is C 1 -C 5 alkyl, —(CH 2 ) y OR 2 and wherein y is 1, 2 or 3 and R 2 is H or C 1 -C 5 alkyl, —OCOR 3 and wherein R 3 is H or C 1 -C 5 alkyl.

6. Method according to claim 3 , wherein the layer of silane based adhesion promoter has a thickness of between 5 to 100 nm.

7. Method of claim 1 , wherein forming a metal layer according to step (iv) comprises

iva. contacting the substrate with a noble metal colloid or a noble metal ion containing solution; and then

ivb. contacting the substrate with at least one electroless metal plating solution.

8. Method of claim 1 , wherein forming a metal layer according to step (iv) comprises

iva. contacting the substrate with a noble metal colloid or a noble metal ion containing solution; next

ivb. contacting the substrate with at least one electroless metal plating solution; and then

ivc. contacting the substrate with at least one electrolytic metal plating solution.

9. Method for electromagnetic shielding, comprising carrying out the method according to claim 1 , wherein the overall thickness of the metal layers ranges between 1 and 100 μm.

10. Method for thermal management, comprising carrying out the method according to claim 1 , wherein the overall thickness of the metal layers ranges between 20 to 300 μm.

11. Method according to claim 7 , wherein the electroless metal plating according to step ivb comprises both electroless nickel plating resulting in a nickel layer having a thickness of between 0.5 and 20 μm and electroless copper plating resulting in a copper layer having a thickness of between 0.5 and 20 μm.

12. Method according to claim 8 , wherein the electrolytic metal plating according to step ivc comprises electrolytic nickel plating resulting in a nickel layer having a thickness of between 0.5 and 300 μm and electrolytic copper plating resulting in a copper layer having a thickness of between 0.5 and 300 μm.

13. Method according to claim 8 , wherein the electroless metal plating according to step ivb comprises both electroless nickel plating resulting in a nickel layer having a thickness of between 0.5 and 20 μm and electroless copper plating resulting in a copper layer having a thickness of between 0.5 and 20 μm.

14. Method according to claim 1 , wherein the at least one active component in step (i) is selected from pre-diced strips, singulated chips with solder balls, and singulated chips without solder balls.

15. Method according to claim 1 , wherein the adhesion promotion layer comprises one or more than one organic compound.

16. Method according to claim 1 , wherein the adhesion promotion layer does not contain iron, nickel and zinc.

17. Method according to claim 1 , wherein the active component is fully diced after the protective layer is removed.

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Aug 18, 2022
From: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
To: ATOTECH DEUTSCHLAND GMBH & CO. KG (F/K/A ATOTECH DEUTSCHLAND GMBH); ATOTECH USA, LLC
Reel/Frame 061521/0103 →
SECURITY INTEREST Recorded Mar 18, 2021
From: ATOTECH DEUTSCHLAND GMBH; ATOTECH USA, LLC
To: GOLDMAN SACHS BANK USA, AS COLLATERAL AGENT
Reel/Frame 055650/0093 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 13, 2017
From: MUKAI, KENICHIROH; KIM, KWONIL; GAHERTY, LEE; BRANDT, LUTZ; MAGAYA, TAFADZWA
To: ATOTECH DEUTSCHLAND GMBH
Reel/Frame 042992/0474 →