Multilayer structure and packaging material including same
The present invention provides a novel multilayer structure having good gas barrier properties and good water vapor barrier properties and further having high retort resistance and a packaging material including the multilayer structure. The present invention relates to a multilayer structure including a base (X) and a layer (Y) stacked on the base (X). The layer (Y) contains an aluminum-containing compound (A) and an organic phosphorus compound (BO), and the organic phosphorus compound (BO) contains a phosphorus atom-containing functional group and at least one metal ion (Z) selected from ions of metals of Groups 1 to 12 of the periodic table, the content of the metal ion (Z) being 0.4 to 8.0 mol % relative to the content of the phosphorus atom-containing functional group.
1. A multilayer structure comprising a base (X) and a layer (Y) stacked on the base (X), wherein
the layer (Y) contains an aluminum-containing compound (A) and an organic phosphorus compound (BO), and
the organic phosphorus compound (BO) contains a phosphorus atom-containing functional group and at least one metal ion (Z) selected from ions of metals of Groups 1 to 12 of the periodic table, the content of the metal ion (Z) being 0.4 to 8.0 mol % relative to the content of the phosphorus atom-containing functional group.
2. The multilayer structure according to claim 1 , wherein the aluminum-containing compound (A) is a compound (Ab) comprising a reaction product (D) of an aluminum-containing metal oxide (Aa) and an inorganic phosphorus compound (BI).
3. The multilayer structure according to claim 1 , wherein a ratio W BO /W BI between a weight W BI of an inorganic phosphorus compound (BI) and a weight W BO of the organic phosphorus compound (BO) in the layer (Y) satisfies a relationship of 0.01/99.99 ≤W BO /W BI <1.00/99.00.
4. The multilayer structure according to claim 1 , wherein the organic phosphorus compound (BO) is a polymer having at least one functional group selected from the group consisting of a phosphoric acid group, a phosphorous acid group, a phosphonic acid group, a phosphonous acid group, a phosphinic acid group, and a phosphinous acid group.
5. The multilayer structure according to claim 1 , wherein the metal ion (Z) is at least one metal ion selected from the group consisting of a lithium ion, a potassium ion, a sodium ion, a magnesium ion, a calcium ion, a manganese ion, an iron ion, a cobalt ion, a nickel ion, a copper ion, and a zinc ion.
6. The multilayer structure according to claim 1 , wherein the base (X) comprises at least one layer selected from the group consisting of a thermoplastic resin film layer and a paper layer.
7. A packaging material comprising the multilayer structure according to claim 1 .
8. The packaging material according to claim 7 , used for a retort food.
9. The multilayer structure according to claim 2 , wherein
the organic phosphorus compound (BO) is a polymer having at least one functional group selected from the group consisting of a phosphoric acid group, a phosphorous acid group, a phosphonic acid group, a phosphonous acid group, a phosphinic acid group, and a phosphinous acid group,
the metal ion (Z) is at least one metal ion selected from the group consisting of a lithium ion, a potassium ion, a sodium ion, a magnesium ion, a calcium ion, a manganese ion, an iron ion, a cobalt ion, a nickel ion, a copper ion, and a zinc ion,
the base (X) comprises at least one layer selected from the group consisting of a thermoplastic resin film layer and a paper layer.