IP Library Granted Patent US 10,655,007
Granted Patent B2
US 10,655,007 · App. 15/539,958 · Granted May 19, 2020

Polyalkylene terephthalate resin composition

Inventors: Kouichi Sakata (Fuji, JP); Shinya Yamada (Fuji, JP); Nobuhiro Yamamoto (Takasago, JP); Tetsuro Yamamoto (Takasago, JP); Yoshiaki Matsuoka (Takasago, JP); Toyohisa Fujimoto (Takasago, JP)
Assignees: POLYPLASTICS CO., LTD.; KANEKA CORPORATION
C08L67/02B29C45/14C08K3/00C08L51/06B29C45/0001B29C45/16B29C45/1671B29C45/1676B29K2067/003B29K2705/00B29K2709/00B29K2833/04B29K2833/08B29K2833/12B29K2867/00B29K2867/006B29K2995/0012B29K2995/0089B32B3/02B32B3/26B32B15/04B32B15/08B32B15/09B32B27/06B32B27/18B32B27/20B32B27/30B32B27/308B32B27/36B32B2264/02B32B2264/025B32B2264/0214B32B2307/30B32B2367/00B32B2457/00B32B2457/04C08J2333/04C08J2333/06C08J2333/08C08J2333/10C08J2333/12C08J2367/00C08J2367/02C08J2367/03C08K3/013C08L33/04C08L33/06C08L33/08C08L33/10C08L33/12C08L51/003C08L67/03C08L2201/00C08L2203/20C08L2205/02C08L2205/06C08L2207/53Y10T428/24777Y10T428/254Y10T428/263Y10T428/2982Y10T428/2989Y10T428/2991Y10T428/31681Y10T428/31786
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Quick Facts
Patent No.
US 10,655,007
App. No.
15/539,958
Granted
May 19, 2020
Kind
B2
Abstract

Disclosed are: a polyalkylene terephthalate resin composition comprising (A) a polyalkylene terephthalate resin and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of the core layer component is more than 80% by mass but less than 100% by mass relative to a total mass of the core layer component and a shell layer component; and a molded article which is obtained by molding the polyalkylene terephthalate resin composition.

Claims (27)

1. An insert molded article obtained by performing insert molding using a polyalkylene terephthalate resin composition and an insert member comprising a metal or an inorganic solid, wherein

the polyalkylene terephthalate resin composition comprises (A) a polyalkylene terephthalate resin, and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of a core layer component is at least 85% by mass but not more than 95% by mass relative to a total mass of the core layer component and a shell layer component, an amount of (B) the acrylic-based core-shell polymer is at least 10 parts by mass but not more than 30 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,

the polyalkylene terephthalate resin composition further comprises (C) a filler in an amount of at least 10 parts by mass but not more than 100 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,

(A) the polyalkylene terephthalate resin comprises a polybutylene terephthalate resin, the core layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 12 alkyl acrylate, the shell layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 20 alkyl methacrylate, and

the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article A is produced, the insert molded article A satisfies the following heat shock resistance condition A, wherein

insert molded article A: an insert molded article into which an L-shaped iron plate with 21 mm in a width×90 mm×90 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an L-shaped plate with 25 mm in a width×70 mm×70 mm and a thickness of 3.6 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and

heat shock resistance condition A: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 100, and

the insert member is a plate-like electrical connection conductor, and the insert member has a ratio of 12.5 or greater for a maximum width relative to a maximum thickness in a cross-section perpendicular to a lengthwise direction of a planar surface of the plate-like conductor.

2. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is at least 2.5 μm but not more than 20 μm, and the amount of the core layer component is at least 85% by mass but not more than 95% by mass relative to the total mass of the core layer component and the shell layer component.

3. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is at least 3 μm but not more than 10 μm, and the amount of the core layer component is at least 90% by mass but not more than 92% by mass relative to the total mass of the core layer component and the shell layer component.

4. The insert molded article according to claim 1 , wherein the average particle size of the component (B) is about 3 μm, and the amount of the core layer component is about 90% by mass relative to the total mass of the core layer component and the shell layer component.

5. The insert molded article according to claim 1 , wherein the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article B is produced, the insert molded article B satisfies the following heat shock resistance condition B, wherein

insert molded article B: an insert molded article into which an I-shaped iron plate with 20 mm in a width×150 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an I-shaped plate with a 25 mm in a width×120 mm and a thickness of 4 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and

heat shock resistance condition B: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 40.

6. An insert molded article obtained by performing insert molding using a polyalkylene terephthalate resin composition and an insert member comprising a metal or an inorganic solid, wherein:

the polyalkylene terephthalate resin composition comprises (A) a polyalkylene terephthalate resin, and (B) an acrylic-based core-shell polymer which has an average particle size of 2 μm or greater and in which an amount of a core layer component is at least 85% by mass but not more than 95% by mass relative to a total mass of the core layer component and a shell layer component, an amount of (B) the acrylic-based core-shell polymer is at least 10 parts by mass but not more than 30 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin,

the polyalkylene terephthalate resin composition further comprises (C) a filler in an amount of at least 10 parts by mass but not more than 100 parts by mass per 100 parts by mass of (A) the polyalkylene terephthalate resin, (A) the polyalkylene terephthalate resin comprises a polybutylene terephthalate resin, the core layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 12 alkyl acrylate, the shell layer component of (B) the acrylic-based core-shell polymer comprises a polymer formed using a C 1 to C 20 alkyl methacrylate, and

the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article B is produced, the insert molded article B satisfies the following heat shock resistance condition B, wherein

insert molded article B: an insert molded article into which an I-shaped iron plate with 20 mm in a width×150 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an I-shaped plate with a 25 mm in a width×120 mm and a thickness of 4 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and

heat shock resistance condition B: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 40, and

the insert member is a plate-like electrical connection conductor, and the insert member has a ratio of 12.5 or greater for a maximum width relative to a maximum thickness in a cross-section perpendicular to a lengthwise direction of a planar surface of the plate-like conductor.

7. The insert molded article according to claim 6 , wherein the average particle size of the component (B) is at least 2.5 μm but not more than 20 μm, and the amount of the core layer component is at least 85% by mass but not more than 95% by mass relative to the total mass of the core layer component and the shell layer component.

8. The insert molded article according to claim 6 , wherein the average particle size of the component (B) is at least 3 μm but not more than 10 μm, and the amount of the core layer component is at least 90% by mass but not more than 92% by mass relative to the total mass of the core layer component and the shell layer component.

9. The insert molded article according to claim 6 , wherein the average particle size of the component (B) is about 3 μm, and the amount of the core layer component is about 90% by mass relative to the total mass of the core layer component and the shell layer component.

10. The insert molded article according to claim 6 , wherein the polyalkylene terephthalate resin composition is a composition wherein, when the following insert molded article A is produced, the insert molded article A satisfies the following heat shock resistance condition A, wherein

insert molded article A: an insert molded article into which an L-shaped iron plate with 21 mm in a width×90 mm×90 mm and a thickness of 1.6 mm is inserted, and in which a resin portion is an L-shaped plate with 25 mm in a width×70 mm×70 mm and a thickness of 3.6 mm, in which a minimum wall thickness in part of the resin portion is 1 mm, and

heat shock resistance condition A: in a heat shock resistance test using a thermal shock tester in which a process of performing heating at 140° C. for 1 hour and 30 minutes, subsequently lowering a temperature to −40° C. and performing cooling for 1 hour and 30 minutes, and then raising a temperature back to 140° C. is deemed one cycle, a number of cycles performed before cracking appears in the molded article is at least 100.

Assignments (2)
MERGER AND CHANGE OF NAME Recorded Jan 29, 2020
From: WINTECH POLYMER LTD.; POLYPLASTICS CO., LTD.
To: POLYPLASTICS CO., LTD.
Reel/Frame 051650/0416 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2017
From: SAKATA, KOUICHI; YAMADA, SHINYA; YAMAMOTO, NOBUHIRO; YAMAMOTO, TETSURO; MATSUOKA, YOSHIAKI; FUJIMOTO, TOYOHISA
To: WINTECH POLYMER LTD.; KANEKA CORPORATION
Reel/Frame 042825/0250 →
Priority Claims (1)
JP 2014-265294 · Dec 26, 2014 · national
Continuity (1)
Related Publication 20170342260A1 · Nov 30, 2017