Analysis system for online-transferred analysis sample
The present invention relates to an analysis system capable of online transferring an analysis sample and promptly acquiring an analysis result. The analysis system capable of analyzing the analysis samples supplied from at least two sites, with one analysis apparatus, and requiring no cleaning process for a nebulizer and a spray chamber, is provided. The present invention relates to analysis system including at least two sample individually transferring units. Each sample transferring path of the sample individually transferring units is coupled to a plasma torch of a common analysis unit including the one analysis apparatus with inductively-coupled plasma or microwave plasma. Each sample transferring path has a main flow path, a makeup gas supply path, and a drain flow path. The plasma torch has a sample introducing pipe that introduces the atomized analysis sample, provided at a substantially center. The inner diameter of the drain flow path is equivalent to or larger than the inner diameter of an inlet portion of the sample introducing pipe of the plasma torch.
1. An analysis system comprising:
a sample individually transferring unit comprising a nebulizer that atomizes an analysis sample, a spray chamber that selects the atomized analysis sample based on a particle diameter, and a sample-transferring path that online transfers the analysis sample from the spray chamber to a plasma torch; and
a common analysis unit comprising the plasma torch that supplies the online-transferred analysis sample, into plasma flames, and an analysis apparatus with inductively-coupled plasma or microwave plasma,
wherein at least a pair of the sample individually transferring units is provided and each of the sample transferring paths of the sample individually transferring units is coupled to the plasma torch of the common analysis unit,
each of the sample transferring paths has a main flow path that transfers the analysis sample from the spray chamber to the plasma torch, a makeup gas supply path that supplies makeup gas to the main flow path, and a drain flow path interposed between the makeup gas supply path and the spray chamber, the drain flow path that discharges the makeup gas and/or the analysis sample from the main flow path,
the main flow path includes no pump and valve in a transferring path of the analysis sample,
the plasma torch has a sample introducing pipe that introduces the atomized analysis sample, and
the inner diameter (D d ) of the drain flow path is equivalent to or larger than the inner diameter (D t ) of the sample introducing pipe of the plasma torch near the side of plasma introduction (D d =D t or D d >D t ).
2. The analysis system according to claim 1 ,
wherein the drain flow path in at least one of the sample transferring paths has a reducing portion that reduces a flow path space.
3. The analysis system according to claim 2 , wherein the sample individually transferring units each comprise a desolvation device, and the spray chamber is arranged in the desolvation device.
4. The analysis system according to claim 3 , further comprising: a standard sample adding device that adds a standard sample to the analysis sample before the atomization due to the nebulizer.
5. The analysis system according to claim 2 , further comprising: a standard sample adding device that adds a standard sample to the analysis sample before the atomization due to the nebulizer.
6. The analysis system according to claim 1 , wherein the sample individually transferring units each comprise a desolvation device, and the spray chamber is arranged in the desolvation device.
7. The analysis system according to claim 6 , further comprising: a standard sample adding device that adds a standard sample to the analysis sample before the atomization due to the nebulizer.
8. The analysis system according to claim 1 , further comprising: a standard sample adding device that adds a standard sample to the analysis sample before the atomization due to the nebulizer.
9. An analysis method comprising the steps of:
online transferring an analysis sample through a sample transferring path from a spray chamber to a plasma torch after a nebulizer atomizes the analysis sample and the spray chamber selects the atomized analysis sample based on a particle diameter; and
performing a common analysis with inductively-coupled plasma or microwave plasma to the analysis sample with an analysis apparatus by supplying the online-transferred analysis sample into plasma flames by the plasma torch,
wherein the step of online transferring individually online transfers the analysis samples through at least a pair of the sample transferring paths, supplies any one of the analysis samples to the plasma torch, and alternately supplies each of the analysis samples to the common analysis step,
the online transfer transfers the analysis samples through main flow paths from the spray chambers to the plasma torch, supplies makeup gas to the main flow paths through makeup gas supply paths, and discharges the makeup gas and/or the analysis samples through drain flow paths, and
when the sample transferring path of the analysis sample during the step of performing the common analysis is performed is defined as an action path, and the sample transferring path of the analysis sample with the step of performing the analysis, being not performed, is defined as a standby path, only the makeup gas is supplied between the makeup gas supply path and a path end portion on the side of the plasma torch, in the standby path.
10. The analysis method according to claim 9 , wherein a standard addition method adds a standard sample to the analysis sample before the atomization.