Thin-film transistor including carbon nanotubes, manufacturing method, and array substrate
The present disclosure provides a thin-film transistor having a plurality of carbon nanotubes in its active layer, its manufacturing method, and an array substrate. The manufacturing method as such comprises: forming an insulating layer to at least substantially cover a channel region of the active layer between a source electrode and a drain electrode of the thin-film transistor, wherein the insulating layer is configured to substantially insulate from an environment, and have substantially little influence on, the plurality of carbon nanotubes in the active layer.
1. A method for manufacturing a bottom-gate thin-film transistor including a plurality of carbon nanotubes in an active layer, comprising:
forming a source and drain metal layer by optical exposure;
forming a carbon nanotube film etching layer containing the plurality of carbon nanotubes by optical exposure;
etching away unneeded portion of the carbon nanotube film etching layer by reactive ion etching (RIE);
measuring transition characteristics curve of the carbon nanotube bottom-gate thin-film transistor exposed in air;
depositing a 20 nm-100 nm yttrium metal layer over a channel region of the active layer via electron beam coating;
forming an insulating layer by UV oxidization (UVO) of the yttrium metal layer to at least substantially cover a channel region of the active layer between a source electrode and a drain electrode of the bottom-gate thin-film transistor, wherein the insulating layer is configured to substantially insulate the channel region of the active layer from an environment, and have substantially little influence on the plurality of carbon nanotubes in the active layer; and
thereby obtaining the bottom-gate thin-film transistor with improved electron mobility and reliability compared with the measured transition characteristics curve prior to the forming of the insulating layer.
2. The method of claim 1 , wherein the insulating layer comprises an yttrium metal oxide.
3. The method of claim 2 , wherein the forming an insulating layer comprises defining a pattern of the insulating layer.
4. The method of claim 2 , wherein the forming an insulating layer comprises at least one round of:
the depositing the yttrium metal layer; and
oxidizing the yttrium metal layer to form a metal oxide layer composing the insulating layer.
5. The method of claim 4 , wherein the oxidizing the yttrium metal layer to form a metal oxide layer is performed by heating the metal layer in an oxygen-containing environment.
6. The method of claim 4 , wherein the forming an insulating layer to at least substantially cover a channel region of the active layer between the source electrode and the drain electrode of the thin-film transistor comprises three rounds of the depositing the yttrium metal layer and the oxidizing the yttrium metal layer.
7. The method of claim 1 , wherein the plurality of carbon nanotubes comprise at least one type of single-walled carbon nanotubes, double-walled carbon nanotubes, or carbon nanotube bundles.
8. A bottom-gate thin-film transistor formed according to the method of claim 1 , comprising:
the active layer, including a plurality of carbon nanotubes; and
the yttrium metal oxide layer, disposed over a channel region of the active layer between a source electrode and a drain electrode of the thin-film transistor and configured to insulate the plurality of carbon nanotubes in the channel region of the active layer from an environment to thereby improve the electron mobility of the bottom-gate thin-film transistor.
9. The bottom-gate thin-film transistor of claim 8 , wherein the plurality of carbon nanotubes comprise at least one type of single-walled carbon nanotubes, double-walled carbon nanotubes, or carbon nanotube bundles.
10. An array substrate, comprising the bottom-gate thin-film transistor according to claim 8 .