Thermoplastic elastomer composition, thermoplastic elastomer, and method for producing thermoplastic elastomer
The present invention provides a thermoplastic elastomer (TPE), in particular a polyurethane-based thermoplastic elastomer (TPU), that has exceptional elongation, strength, and wear resistance, and in particular has exceptional wear resistance. The present invention provides: a thermoplastic elastomer composition containing A) a thermoplastic urethane elastomer composition having A1) at least one polyol selected from the group consisting of polyether polyols, polyesterpolyols, and polycarbonate polyols, A2) a diisocyanate, and A3) a chain extender, and B) polyrotaxane formed by arranging blocking groups, at both ends of pseudo-polyrotaxane formed by inclusion of the openings of cyclic molecules in a shape skewered by linear molecules, so that the cyclic molecules are not eliminated; and a thermoplastic elastomer derived from this composition.
1. A composition used for a thermoplastic elastomer comprising:
A) a thermoplastic urethane elastomer composition comprising A1) at least one polyol selected from the group consisting of polyether polyols, polyester polyols, and polycarbonate polyols, A2) a diisocyanate, and A3) a chain extender; and
B) a polyrotaxane comprising a pseudopolyrotaxane, which has a linear molecule and a cyclic molecule(s) in which the linear molecule is included in a cavity (cavities) of the cyclic molecule(s) in a skewered manner, and capping groups, each of which locates at each end of the pseudopolyrotaxane in order to prevent the dissociation of the cyclic molecule(s).
2. The composition used for a thermoplastic elastomer according to claim 1 , wherein the cyclic molecule in the B) polyrotaxane comprises:
B1) a hydrophobic modifying group; and
B2) at least one functional group selected from the group consisting of —OH, —NH2 and —SH.
3. The composition used for a thermoplastic elastomer according to claim 2 , wherein the B1) hydrophobic modifying group is a hydrophobic modifying group derived from caprolactone and the B2) functional group is —OH.
4. The composition used for a thermoplastic elastomer according to claim 1 , wherein the B) polyrotaxane is 0.10 to 10.0 parts by weight based on 100 parts by weight of the A) thermoplastic urethane elastomer composition.
5. A thermoplastic elastomer derived from the composition used for a thermoplastic elastomer according to claim 1 , wherein the A) thermoplastic urethane elastomer composition and the B) polyrotaxane are partially bonded to each other.
6. The thermoplastic elastomer according to claim 5 , wherein a ratio X/Y of a first Taber abrasion amount X, which is a measurement value of the thermoplastic elastomer in a Taber abrasion test T, to a second Taber abrasion amount Y, which is a measurement value of a comparative thermoplastic elastomer formed by excluding the B) component from the thermoplastic elastomer in the Taber abrasion test T, is 0.85 or less.
7. A method for producing a thermoplastic elastomer comprising the steps of:
1) preparing a A) thermoplastic urethane elastomer composition comprising A1) at least one polyol selected from the group consisting of polyether polyols, polyester polyols, and polycarbonate polyols, A2) a diisocyanate, and A3) a chain extender;
2) preparing a B) polyrotaxane comprising a pseudopolyrotaxane, which has a linear molecule and a cyclic molecule(s) in which the linear molecule is included in a cavity (cavities) of the cyclic molecule(s) in a skewered manner, and capping groups, each of which locates at each end of the pseudopolyrotaxane in order to prevent the dissociation of the cyclic molecule(s);
3) mixing the A) thermoplastic urethane elastomer composition and the B) polyrotaxane, to obtain a composition used for a thermoplastic elastomer; and
4) heating and forming the composition used for a thermoplastic elastomer, followed by cooling, to obtain the thermoplastic elastomer.