Metal soap and manufacturing method therefor
A metal soap, including metal soap particles in which a fatty acid has from 6 to 22 carbons, and an inorganic crystal nucleating agent with an average particle size of 0.01 to 20 μm absorbed internally into the metal soap particles, wherein the cumulative diameter at 50% of the metal soap particles on a volumetric basis is 1.0 to 30.0 μm, and the internal absorption rate A, represented by formula (1) below, is 30% or greater. Internal absorption rate A =100−( X/X ′)=100 Formula (1) X; amount of inorganic crystal nucleating agent contained within metal soap X′; amount of inorganic crystal nucleating agent contained within pulverized metal soap passed through a 325-mesh filter (wherein X and X′ are average values obtained by elemental analysis at three locations in an area of 15 μm square, using a scanning electron microscope/energy dispersive X-ray spectroscopy (SEM/EDX).
1. A metal soap, comprising metal soap particles in which a fatty acid has from 6 to 22 carbons, and an inorganic crystal nucleating agent with an average particle size of 0.01 to 20 μm absorbed internally into the metal soap particles, wherein the cumulative diameter at 50% of the metal soap particles on a volumetric basis is 1.0 to 30.0μm, and the internal absorption rate A, represented by formula (1) below, is 30% or greater:
Internal absorption rate A =100−( X/X ′)×100 Formula (1)
X; amount of inorganic crystal nucleating agent contained within metal soap,
X′; amount of inorganic crystal nucleating agent contained within pulverized metal soap passed through a 325-mesh filter
wherein X and X′ are average values obtained by elemental analysis at three locations in an area of 15 μm square, using a scanning electron microscope/energy dispersive X-ray spectroscopy (SEM/EDX), under conditions of an accelerating voltage of 10 kV and a height of 15 mm.
2. The metal soap according to claim 1 , wherein the metal soap satisfies a relationship of B <2.00, where B denotes a granularity summary value represented by formula (2) below, C <20, where (C) denotes an aggregation degree (%), and E being from 0.810 to 1.000, where E denotes an average circularity of particle groups having particle size at 10% to particle size at 90%, measured by a flow type particle image analyzer:
Granularity summary value B =( D 90- D 10)/ D 50(wherein 1.0 < D 50 <30.0) Formula (2)
D10: Cumulative diameter (μm) at 10% of metal soap particles on volumetric basis,
D50: Cumulative diameter (μm) at 50% of metal soap particles on volumetric basis,
D90: Cumulative diameter (μm) at 90% of metal soap particles on volumetric basis.
3. The metal soap according to claim 1 , wherein the metal soap is a zinc salt or a calcium salt.
4. The metal soap according to claim 1 , wherein the inorganic crystal nucleating agent is one or more agents selected from the group consisting of silica, zinc oxide, titanium oxide, calcium oxide, boron nitride, talc, mica, synthetic mica, alumina, and sericite.
5. A method for manufacturing the metal soap according to claim 1 through reaction, by a double decomposition method, of an inorganic metal salt, and a fatty acid alkali metal salt obtained from a fatty acid having from 6 to 22 carbons, the method comprising:
a step of dispersing an inorganic crystal nucleating agent having an average particle size of 0.01 to 20 μm into an aqueous solution of the fatty acid alkali metal salt at a level of 0.1 to 20 mass % with respect to the total amount of the fatty acid and the inorganic crystal nucleating agent to prepare a dispersion solution; and
a step of mixing and bringing about a reaction of the dispersion solution and the aqueous solution of the inorganic metal salt.