Brazing sheet having improved corrosion resistance after brazing
The present invention relates to an aluminum alloy brazing sheet with a thickness of 0.30 nm or less, including: a core material; a sacrificial material cladding one surface of the core material; and a brazing material cladding the other surface of the core material, in which the core material is made of A1—Mn—Si-based aluminum alloy containing by mass %, Cu: 0.5 to 1.3%, the sacrificial material is made of aluminum alloy containing, by mass %, Zn: 4.0 to 7.0%, the brazing material is made of aluminum alloy containing, by mass %, Si: 6.0 to 11.0% and Zn: 0.1 to 3.0%, in a pitting potential after brazing beat treatment, a thickness of a region in which a potential difference from the noblest potential in the core material is 100 mV or more is 10% to 50% of the thickness of the brazing sheet.
1. A method of brazing an aluminum alloy brazing sheet, the method comprising:
attaching an aluminum alloy brazing sheet to a part that is subjected to a brazing treatment; and
subjecting the aluminum alloy brazing sheet to a heat treatment which is conducted by heating at a heating rate in which the arrival time from room temperature to 400° C. is 7 to 9 minutes, the arrival time from 400° C. to 550° C. is 1 to 2 minutes, the arrival time from 550° C. to a target temperature is 3 to 6 minutes; holding at the target temperature of 600° C. for 3 minutes; cooling to 300° C. at 60° C./min; and then air-cooling to room temperature,
wherein:
the aluminum alloy brazing sheet comprises:
a core material,
a sacrificial material cladding one surface of the core material, and
a brazing material cladding another surface of the core material,
wherein,
the core material is made of Al—Mn—Si-based aluminum alloy comprising, by mass %, Cu: 0.5 to 1.3%,
the sacrificial material is made of aluminum alloy comprising: by mass %, Zn: 4.0 to 7.0%; and the balance being Al and inevitable impurities,
the brazing material is made of aluminum alloy comprising: by mass %, Si: 6.0 to 11.0%; Zn: 0.1 to 3.0%; and the balance being Al and inevitable impurities; and
the aluminum alloy brazing sheet has a thickness of 0.30 mm or less.
2. The method of brazing an aluminum brazing sheet according to claim 1 , wherein
in the pitting potential after the heat treatment, within a region in which a potential difference from the noblest potential in the core material is 100 mV or more, 1<(A+1)/(B+1)<81 is satisfied where A (μm) is a length of the region from a surface of the sacrificial material in the thickness direction and B (μm) is a length of the region from a surface of the brazing material in the thickness direction.
3. The method of brazing an aluminum brazing sheet according to claim 1 , wherein
a pitting potential difference after the heat treatment between the core material and the sacrificial material is 160 to 290 mV.
4. The method of brazing an aluminum brazing sheet according to claim 1 , wherein
after the heat treatment, a thickness of a region in which Zn concentration is 0.2% or less is 20% to 70% of the thickness of the brazing sheet.
5. The method of brazing an aluminum brazing sheet according to claim 1 , wherein the core material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 0.5 to 1.8%; Si: 0.05 to 1.3%; Fe: 0.05 to 0.5%; Mg: 0.05 to 0.5%; Zr: 0.05 to 0.3%; Ti: 0.05 to 0.3%; and Cr: 0.05 to 0.3%.
6. The method of brazing an aluminum brazing sheet according to claim 1 , wherein the sacrificial material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 1.0 to 1.8%; and Si: 0.2 to 1.2%.
7. The method of brazing an aluminum brazing sheet according to claim 2 , wherein
a pitting potential difference after the heat treatment between the core material and the sacrificial material is 160 to 290 mV.
8. The method of brazing an aluminum brazing sheet according to claim 2 , wherein
after the heat treatment, a thickness of a region in which Zn concentration is 0.2% or less is 20% to 70% of the thickness of the brazing sheet.
9. The method of brazing an aluminum brazing sheet according to claim 2 , wherein the core material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 0.5 to 1.8%; Si: 0.05 to 1.3%; Fe: 0.05 to 0.5%; Mg: 0.05 to 0.5%; Zr: 0.05 to 0.3%; Ti: 0.05 to 0.3%; and Cr: 0.05 to 0.3%.
10. The method of brazing an aluminum brazing sheet according to claim 2 , wherein the sacrificial material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 1.0 to 1.8%; and Si: 0.2 to 1.2%.
11. The method of brazing an aluminum brazing sheet according to claim 3 , wherein
after the heat treatment, a thickness of a region in which Zn concentration is 0.2% or less is 20% to 70% of the thickness of the brazing sheet.
12. The method of brazing an aluminum brazing sheet according to claim 3 , wherein the core material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 0.5 to 1.8%; Si: 0.05 to 1.3%; Fe: 0.05 to 0.5%; Mg: 0.05 to 0.5%; Zr: 0.05 to 0.3%; Ti: 0.05 to 0.3%; and Cr: 0.05 to 0.3%.
13. The method of brazing an aluminum brazing sheet according to claim 3 , wherein the sacrificial material is made of the aluminum alloy further comprising one or more selected from the group consisting of: by mass %, Mn: 1.0 to 1.8%; and Si: 0.2 to 1.2%.