Method and system for in situ sintering of conductive ink
A method of manufacturing a conductive element is disclosed. The method being executed by an additive manufacturing system and comprises: dispensing a modeling material on a receiving medium to form a layer, and dispensing a conductive ink on the layer of modeling material to form a conductive element. In some embodiments of the invention the modeling material comprises a sintering inducing agent, and in some embodiments of the present invention a sintering inducing composition is dispensed separately from the modeling material and separately from the conductive ink.
1. A method of manufacturing a conductive element, the method being executed by an additive manufacturing system and comprising:
dispensing on a receiving medium a curable modeling material containing a sintering inducing agent to form a layer; and
dispensing a conductive ink on said layer of modeling material to form a conductive element,
wherein said curable modeling material is formulated for use in additive manufacturing and is able to form a three-dimensional object on its own,
and wherein said sintering inducing agent is represented by the general formula:
wherein:
X is O or NH;
Y is a substituted or unsubstituted hydrocarbon chain from 1 to 20 carbon atoms in length;
R 1 is H, alkyl or cycloalkyl;
Ra and Rb are each independently H, alkyl or cycloalkyl,
R 2 -R 4 are each independently an alkyl; and
Z is an anion.
2. The method of claim 1 , wherein said conductive ink is non-curable.
3. The method of claim 1 , wherein said conductive ink is curable.
4. The method according to claim 1 , further comprising partially curing said modeling material prior to said dispensing of said conductive ink.
5. The method according to claim 1 , further comprising at least partially drying said conductive ink following said dispensing of said conductive ink, wherein said at least partially drying comprises evaporation of at least 10% of solvent in said conductive ink.
6. The method according to claim 1 , further comprising dispensing a curable modeling material to form a layer on a surface of said conductive element, wherein said curable modeling material dispensed on said surface of said conductive element also comprises said sintering inducing agent.
7. The method according to claim 1 , wherein said sintering inducing composition is dispensed at least on said conductive element.
8. The method according to claim 1 , wherein said counter anion is chloride.
9. A method of manufacturing a conductive element, the method being executed by an additive manufacturing system and comprising:
dispensing on a receiving medium a curable modeling material containing a sintering inducing agent to form a layer, said curable modeling material being formulated for use in additive manufacturing and being able to form a three-dimensional object on its own;
dispensing a conductive ink on said layer of modeling material to form a conductive element; and
dispensing a sintering inducing composition having a sintering inducing agent on at least one of said layer and said conductive element, wherein said sintering inducing agent is represented by the general formula:
wherein:
X is O or NH;
Y is a substituted or unsubstituted hydrocarbon chain from 1 to 20 carbon atoms in length;
R 1 is H, alkyl or cycloalkyl;
Ra and Rb are each independently H, alkyl or cycloalkyl,
R 2 -R 4 are each independently an alkyl; and
Z is an anion.
10. The method of claim 9 , wherein said conductive ink is curable.
11. The method of claim 9 , wherein said conductive ink is non-curable.
12. The method according to claim 9 , wherein said sintering inducing composition further comprises a sintering inert material selected from the group consisting of an acrylate, a methacrylate, an acrylamide, a methacrylamide, and a vinyl ether, each being monofunctional or multifunctional, wherein said sintering inert material does not comprise an ionic group, and an amount of said sintering inert material in said sintering inducing composition is at least 20% by weight.