Polymer blend in granular form and process for making same
Provided is a polymer blend in granular form and a process for making the blend. The blend is suitable for use as an additive in a variety of applications, such as in detergent formulations. The blend comprises: (i) one or more first polymers each independently having a weight-average molecular weight of 35,000 to 100,000 g/mol and each independently comprising polymerized units of (a) 22 to 80 wt % of one or more monoethylenically unsaturated C3-C6 carboxylic acid monomers, and (b) 20 to 78 wt % of one or more C1-C12 alkyl (meth)acrylate monomers; and (ii) one or more second polymers each independently having a weight-average molecular weight of 1,000 to 45,000 g/mol and each independently comprising polymerized units of 50 to 100 wt % of one or more monoethylenically unsaturated C3-C6 carboxylic acid monomers, wherein component (i) comprises from 1 wt % to 50 wt % based on the total weight of (i) and (ii), wherein the polymer blend is in granular form, and wherein one or more polymers of the polymer blend is at least partially neutralized.
1. A polymer blend comprising:
(i) one or more first polymers each independently having a weight-average molecular weight of 35,000 to 100,000 g/mol and each independently comprising polymerized units of
(a) 22 to 80 wt % of one or more monoethylenically unsaturated C 3 -C 6 carboxylic acid monomers, and
(b) 20 to 78 wt % of one or more C 1 -C 12 alkyl (meth)acrylate monomers,
wherein at least one of the one or more first polymer comprises polymerized units of:
55 to 80 wt % of methacrylic acid units,
10 to 35 wt % of ethyl acrylate units, and
10 to 35 wt % of butyl acrylate units; and
(ii) one or more second polymers each independently having a weight-average molecular weight of between 2,000 to 35,000 g/mol and each independently comprising polymerized units of 50 to 100 wt % of one or more monoethylenically unsaturated C 3 -C 6 carboxylic acid monomers,
wherein component (i) comprises from 1 wt % to 50 wt % based on the total weight of (i) and (ii), wherein the polymer blend is in granular form, and wherein one or more polymers of the polymer blend is at least partially neutralized.
2. The polymer blend of claim 1 , made by a process comprising:
(a) providing an aqueous solution of the one or more first polymers at pH 5 to 9;
(b) providing an aqueous solution of the one or more second polymers at pH 5 to 12;
(c) mixing together the solution of step (a) and the solution of step (b); and
(d) drying the mixture prior to gross phase separation of the mixture.
3. A process for making the polymer blend of claim 1 , the process comprising:
(a) providing an aqueous solution of the one or more first polymers at pH 5 to 9;
(b) providing an aqueous solution of the one or more second polymers at pH 5 to 12;
(c) mixing together the solution of step (a) and the solution of step (b); and
(d) drying the mixture prior to gross phase separation of the mixture.
4. The polymer blend of claim 1 , wherein at least one of the one or more first polymers is a product of free-radical emulsion polymerization in the presence of a C 2 -C 24 alkanethiol.
5. The polymer blend of claim 1 , wherein at least one of the one or more second polymers is a homopolymer comprising polymerized units of a monoethylenically unsaturated C 3 -C 6 carboxylic acid monomer.
6. The polymer blend of claim 1 , wherein the one or more second polymers is a mixture of (a) a homopolymer comprising polymerized units of a monoethylenically unsaturated C 3 -C 6 carboxylic acid monomer; and (b) a polymer comprising polymerized units of: one or more monoethylenically unsaturated C 3 -C 6 carboxylic acid monomers; an ethylenically unsaturated sulfonic acid monomer; and optionally a further monomer selected from ethyl acrylate, butyl acrylamide, and maleic anhydride.
7. A detergent composition comprising: a surfactant, a builder, and the polymer blend of claim 1 .