Method for manufacturing silicon carbide single crystal
View Patent ↗The present invention provides a method of manufacturing by the sublimation-recrystallization method more accurately detecting a thermal state of a starting material in a crucible and enabling control of the growth conditions while manufacturing an SiC single crystal. The method obtains the high frequency current to be supplied through the induction coil by a converter for converting AC current to DC current and an inverter means for converting the DC current output from the converter to a high frequency to obtain a high frequency current, obtains a grasp, in advance, of a relationship between a variation over time of a DC equivalent resistivity (DCV/DCI), calculated from a DC voltage value (DCV) and DC current value (DCI) converted by the converter at the time of growth of the silicon carbide single crystal, and a density of micropipes formed in the grown silicon carbide single crystal, and adjusts at least one of the DCV or DCI at the converter based on the relationship of the DC equivalent resistivity and micropipe density grasped in advance.
1. A method for manufacturing a silicon carbide single crystal comprising surrounding a crucible holding a starting material powder and a seed crystal by an induction coil, supplying a high frequency current through the induction coil to heat the crucible, and making the starting material powder sublimate to grow a silicon carbide single crystal on the seed crystal,
the method comprising: supplying the high frequency current through the induction coil by a converter for converting AC current to DC current and an inverter means for converting the DC current output from the converter to a high frequency current; determining, a relationship between variations in a DC equivalent resistivity (DCV/DCI) calculated from a DC voltage value (DCV) and DC current value (DCI) converted by the converter during crystal growth, and a density of micropipes formed in the grown silicon carbide single crystal; and
controlling at least one of the DC voltage value (DCV) or DC current value (DCI) at the converter based on the relationship of the variations in the DC equivalent resistivity over time and the density of micropipe.
2. The method for manufacturing a silicon carbide single crystal according to claim 1 , wherein the micropipe density in the relationship of the DC equivalent resistivity and micropipe density is equal to or less than a threshold value.
3. The method for manufacturing a silicon carbide single crystal according to claim 2 , wherein the threshold value of the micropipe density is 5/cm 2 or less.