Graphene laminate and preparation method therefor
Disclosed is a graphene laminate including a first graphene layer, containing an electron-donating functional group, and a second graphene layer, disposed on the first graphene layer and configured to include graphene, wherein the second graphene layer is n-doped with the first graphene layer. Thereby, graphene is doped with amino-group-modified graphene, thus preventing the transparency of graphene from decreasing, and the extent of doping of graphene can be adjusted, and the doping effect can last a long time even without any protective layer.
1. A graphene laminate, comprising:
a functionalized graphene layer containing an electron-donating functional group and a graphene layer, wherein the graphene layer is functionalized by the electron-donating functional group to form the functionalized graphene layer; and
a second graphene layer disposed on the functionalized graphene layer and configured to include graphene,
wherein the second graphene layer is in direct contact with the functionalized graphene layer such that the second graphene layer is n-doped with the functionalized graphene layer.
2. The graphene laminate of claim 1 , wherein the electron-donating functional group is at least one selected from the group consisting of an amino group, a C1 to C10 aminoalkyl group, and a C2 to C10 methoxyalkyl group.
3. The graphene laminate of claim 2 , wherein the electron-donating functional group is an amino group or a C1 to C10 aminoalkyl group.
4. The graphene laminate of claim 3 , wherein the amino group or the C1 to C10 aminoalkyl group is subjected to amide bonding with the functionalized graphene layer.
5. The graphene laminate of claim 1 , wherein the functionalized graphene layer includes single-layer or multilayer graphene.
6. An electrode, including the graphene laminate of claim 1 .
7. An electronic device, including the electrode of claim 6 .
8. The electronic device of claim 7 , wherein the electronic device is any one selected from among an organic thin film transistor, an organic solar cell, an organic light-emitting diode, and an organic photodetector.
9. The electronic device of claim 8 , wherein a source or drain electrode of the organic thin film transistor includes the graphene laminate.