Particle size measuring method and device

1. A particle size measuring device which measures the particle size of particles that perform Brownian motion in a dispersion medium, the device comprising:

a transparent column which accommodates a dispersion medium therein;

a laser light irradiating unit which irradiates the dispersion medium in the column with laser light;

an imaging unit which includes a camera that images the dispersion medium in the column;

an image analyzing unit which acquires a displacement of corresponding particles from at least a plurality of images captured at a predetermined time interval Δt; and

a calculating unit which calculates the particle size based on the fact that a root mean square value of the displacement is proportional to k B T/3πηd where k B represents a Boltzmann constant, T represents an absolute temperature, η represents a viscosity coefficient of the dispersion medium, and d represents the particle size;

wherein the image analyzing unit obtains a scattered light intensity and a number concentration of a plurality of the particles from the images, and

the calculating unit determines a material of the particles by acquiring a relative refractive index m using a relational expression between a scattered light intensity I which is the intensity of the scattered light and an incident light intensity I 0 which is the intensity of the laser light and performing absorption correction, where c represents the number concentration, r represents the distance between the particles and the camera, λ represents a wavelength of the laser light, d represents the particle size, and m represents a relative refractive index of the particles with respect to the dispersion medium:

I

∝

I

0

⁢

c

2

⁢

r

2

⁢

(

2

⁢

⁢

π

λ

)

4

⁢

(

d

2

)

6

⁢



m

2

-

1

m

2

+

2



2

.

2. The particle size measuring device according to claim 1 ,

wherein the dispersion medium is allowed to flow along an axis line in the column,

an optical axis of the camera is disposed toward a direction perpendicular to the axis line, and

the image analyzing unit further acquires the displacement by subtracting a moving component due to a flow velocity of the dispersion medium from a moving component in a direction along the axis line of the particles in the images.

3. The particle size measuring device according to claim 1 ,

wherein the image analyzing unit further acquires a moving component in a vertical direction and a moving component in a horizontal direction of the corresponding particles in the images, and

the calculating unit calculates the particle size of only the corresponding particles in which a difference or a ratio between the root mean square value of the moving component in the vertical direction and the root mean square value of the moving component in the horizontal direction is set to be in a predetermined range.

4. A particle size measuring method of measuring the particle size of particles that perform Brownian motion in a dispersion medium of a column, the method comprising:

a step of imaging the dispersion medium in the column by an imaging unit which includes a camera while irradiating inside the column with laser light;

an image analyzing step of acquiring a displacement of corresponding particles from at least a plurality of images captured at a predetermined time interval Δt; and

a calculating step of calculating the particle size based on the fact that k B T/3πηd is proportional to a root mean square value of the displacement where k B represents a Boltzmann constant, T represents an absolute temperature, η represents a viscosity coefficient of the dispersion medium, and d represents the particle size;

wherein the image analyzing step further includes a step of obtaining a scattered light intensity and a number concentration of a plurality of the particles from the images, and

the calculating step further includes a step of determining a material of the particles by acquiring a relative refractive index m using a relational expression between a scattered light intensity I which is the intensity of the scattered light and an incident light intensity I 0 which is the intensity of the laser light and performing absorption correction, where c represents the number concentration, r represents the distance between the particles and the camera, λ represents a wavelength of the laser light, d represents the particle size, and m represents a relative refractive index of the particles with respect to the dispersion medium:

I

∝

I

0

⁢

c

2

⁢

r

2

⁢

(

2

⁢

⁢

π

λ

)

4

⁢

(

d

2

)

6

⁢



m

2

-

1

m

2

+

2



2

.

5. The particle size measuring method according to claim 4 ,

wherein the dispersion medium is allowed to flow along an axis line in the column,

an optical axis of the camera is disposed toward a direction perpendicular to the axis line, and

the displacement is acquired by subtracting a moving component due to a flow velocity of the dispersion medium from a moving component in a direction along the axis line of the particles in the images in the image analyzing step.

6. The particle size measuring method according to claim 4 ,

wherein a moving component in a vertical direction and a moving component in a horizontal direction of the corresponding particles in the images are acquired in the image analyzing step, and

the particle size of only the corresponding particles in which a difference or a ratio between the root mean square value of the moving component in the vertical direction and the root mean square value of the moving component in the horizontal direction is set to be in a predetermined range is calculated in the calculating step.