Epoxy resin composition, prepreg, carbon fiber-reinforced composite material, and manufacturing methods therefor
The present invention provides an epoxy resin composition comprising at least the following component [A], component [B] and component [C], the epoxy resin composition being characterized in that: the mixture of component [A] and component [B] is a mixture that, when temperature is increased at 2° C./min, begins to thicken at temperature (T 1 ) and completes thickening at temperature (T 2 ), temperature (T 1 ) being 80-110° C. and temperature (T 1 ) and temperature (T 2 ) satisfying the relationship of expression (1) 5° C.≤(T 2 −T 1 )≤20° C. expression (1); and the mixture of component [A] and component [C] is a mixture that, when temperature is increased at 2° C./min, begins to cure at temperature (T 3 ), temperature (T 1 ) and temperature (T 3 ) satisfying the relationship of expression (2) 5° C.≤(T 3 −T 1 )≤80° C. expression (2). Component [A]: epoxy resin Component [B]: thickening particle Component [C]: curing agent.
1. An epoxy resin composition, comprising at least:
component [A];
3 to 20 parts by mass of component [B] with respect to 100 parts by mass of the component [A];
6 to 20 parts by mass of component [C] with respect to 100 parts by mass of the component [A]; and
5 to 35 parts by mass of component [D] with respect to 100 parts by mass of the component [A],
wherein a viscosity at 50° C. of the epoxy resin composition is 50 to 1000 Pa·s,
the mixture of component [A] and component [B] is a mixture that initiates thickening at temperature (T 1 ) and completes thickening at temperature (T 2 ) when temperature increases at 2° C./min, the temperature (T 1 ) being 85 to 110° C., and the temperature (T 1 ) and the temperature (T 2 ) satisfying a relationship of the following formula (1)
5° C.≤( T 2 −T 1)≤20° C. formula (1), and
the mixture of component [A] and component [C] is a mixture that initiates curing at temperature (T 3 ) when temperature increases at 2° C./min, and the temperature (T 1 ) and the temperature (T 3 ) satisfying a relationship of the following formula (2)
5° C.≤( T 3 −T 1)≤80° C. formula (2), and
wherein
component [A] is epoxy resin containing 40 to 85 mass % of a glycidylamine type epoxy resin,
component [B] is thickening particles which is a polymer including one or more polymerization units selected from the group consisting of a methacrylic acid ester-based compound, an acrylic acid ester-based compound, and a vinyl-based compound, and wherein the thickening particles are dispersed in and swell in the epoxy resin [A] by heating,
component [C] is curing agent, and
component [D] is thermoplastic resin in which at least a part is dissolved in the component [A].
2. The epoxy resin composition according to claim 1 , wherein the viscosity (η2) of the epoxy resin composition at the temperature (T 2 ) is 5 to 300 Pa·s.
3. The epoxy resin composition according to claim 1 , wherein the component [C] contains dicyandiamide and a urea compound.
4. The epoxy resin composition according to claim 1 , wherein the component [B] contains an alkyl methacrylate polymer having an average polymerization degree of 4,000 to 40,000.
5. The epoxy resin composition according to claim 1 , wherein the glass transition temperature of a molded product obtained by heating and curing at 180° C. for 10 minutes is 160° C. or higher.
6. A prepreg, comprising:
a reinforcing fiber base material made of carbon fiber; and
the epoxy resin composition according to claim 1 ,
wherein the prepreg is formed by impregnating the reinforcing fiber base material with a part or all of the epoxy resin composition.
7. The prepreg according to claim 6 , wherein the reinforcing fiber base material is a mat formed of short fibers having a fiber length of 5 to 100 mm.
8. A method for manufacturing a carbon fiber-reinforced composite material, comprising:
heating and pressing the prepreg according to claim 6 in a mold at a temperature of 130 to 180° C. and a pressure of 0.2 to 10 MPa for 10 to 30 minutes.
9. A method for manufacturing a carbon fiber-reinforced composite material, comprising:
laminating the prepregs according to claim 6 on both sides of a honeycomb core to obtain a honeycomb core laminate having a honeycomb core therein;
sequentially stacking the honeycomb core laminate and a film bag in a mold to seal the honeycomb core laminate between the mold and the film bag; and
evacuating a space formed between the mold and the film bag and heating and pressing the honeycomb core laminate at a temperature increase rate of 1 to 50° C./min, a pressure of 0.1 to 0.7 MPa and a temperature of 130 to 180° C. for 10 to 30 minutes.
10. A method for manufacturing a carbon fiber-reinforced composite material, comprising:
laminating the prepregs according to claim 6 on both sides of a foam core to obtain a foam core laminate having a foam core therein;
sequentially stacking the foam core laminate and a film bag in a mold to seal the foam core laminate between the mold and the film bag; and
evacuating a space formed between the mold and the film bag and heating and pressing the foam core laminate at a temperature increase rate of 1 to 50° C./min, a pressure of 0.1 to 0.7 MPa and a temperature of 130 to 180° C. for 10 to 30 minutes.