Organopolysiloxane emulsion composition for release paper or release film, method for producing same, and release paper and release film
An organopolysiloxane emulsion composition for release paper or a release film, said composition being produced by dispersing a mixture comprising components (A) to (D) as mentioned below in water: (A) an alkenyl-group-containing diorganopolysiloxane having at least two alkenyl groups per molecule and having a viscosity of 1,000 Pa·s or less at 25° C., in an amount of 100 parts by mass; (B) an organohydrogenpolysiloxane having at least two Si—H groups per molecule and having a viscosity of 1 Pa·s or less at 25° C., in such an amount that the number of moles of an Si—H group can become 0.5 to 10 times the number of moles of an alkenyl group in the component (A); (C) a curing catalyst, in an amount of 0.01 to 3 parts by mass; and (D) a polyether-modified and/or polyol-modified organosilicon compound, in an amount of 0.01 to 10 parts by mass.
1. An organopolysiloxane emulsion composition for release paper or release film that is obtained by dispersing in water a mixture comprising following components (A) to (D) and (G):
(A) 100 parts by weight of an alkenyl group-containing diorganopolysiloxane having at least two alkenyl groups per molecule and having a viscosity at 25° C. of not more than 1,000 Pa·s;
(B) an organohydrogenpolysiloxane having at least two Si—H groups per molecule and having a viscosity at 25° C. of not more than 1 Pa·s, in an amount corresponding to a number of moles of Si—H groups that is from 0.5 to 10 times the number of moles of alkenyl groups in component (A);
(C) from 0.01 to 3 parts by weight of a curing catalyst; and
(D) from 0.01 to 10 parts by weight of a polyol-modified organosilicon compound of formula (8) below
wherein each R 1 is independently a substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms without an aliphatic unsaturated bond; each R 3 is independently a hydrogen atom, a hydroxyl group, an alkoxy group of 1 to 4 carbon atoms, or a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms; each R 4 is independently a group having the following formulas:
—(CH 2 ) aa —O—(CH 2 —CH(OH)—CH 2 O) da —R 6
wherein R 6 is a substituted or unsubstituted monovalent hydrocarbon group of 1 to 10 carbon atoms without an aliphatic unsaturated bond, or a hydrogen atom; aa is an integer from 1 to 10; and da is an integer from 1 to 20; q, r, and s, are integers of 0 or more; q+r+s is integers from 0 to 98; each o is independently an integer from 0 to 3; p is an integer from 0 to 3; o +each p is independently an integer from 0 to 3; when o+p is 3 for each terminal group, s is 1 or more; and
(G) an emulsifying agent excluding component (D).
2. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein the mixture further comprises (E) from 0.1 to 10 parts by weight, per 100 parts by weight of component (A), of an organopolysiloxane resin composed primarily of M units of formula (1) below and Q units of formula (2) below in a molar ratio of M units to Q units (M/Q) in the range of 1/9 to 9/1:
wherein each R 1 is independently a substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms without an aliphatic unsaturated bond; each R 2 is independently a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms; the letter a is an integer from 0 to 3; and O 1/2 — indicates that another unit is bonded through O 1/2 —.
3. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein the mixture further comprises (F) from 0.1 to 50 parts by weight of an adhesion promoter per 100 parts by weight of component (A).
4. The organopolysiloxane emulsion composition for release paper or release film of claim 3 , wherein component (F) is an organopolysiloxane resin composed primarily of (R 1 SiO 3/2 ) units (T units) and (R 1 a R 2 (3-a) SiO 1/2 ) units (M units) (wherein each R 1 is independently a substituted or unsubstituted monovalent hydrocarbon group of 1 to 20 carbon atoms without an aliphatic unsaturated bond; each R 2 is independently a substituted or unsubstituted alkenyl group of 2 to 20 carbon atoms; and the letter a is an integer from 0 to 3) in a molar ratio of M units to T units (M/T) in the range of 1/9 to 9/1.
5. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein the content of the component (G) is from 0.1 to 20 parts by weight of an emulsifying agent per 100 parts by weight of component (A).
6. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein the mixture further comprises (H) from 0.1 to 10 parts by weight of a pot-life extender per 100 parts by weight of component (A).
7. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein component (D) is a compound of any of general formulas (9) to (10).
8. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein component (D) is a compound having the following formulas:
wherein “Me” stands for a methyl groups.
9. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein component (G) is selected from the group consisting of nonionic surfactants and water soluble polymers.
10. The organopolysiloxane emulsion composition for release paper or release film of claim 1 , wherein component (G) is nonionic surfactants and water soluble polymers.
11. A release paper or release film obtained by applying the organopolysiloxane emulsion composition for release paper or release film of claim 1 to a paper or film substrate, and curing the applied composition.
12. A method for preparing the organopolysiloxane emulsion composition for release paper or release film of claim 1 , comprising the steps of preparing:
emulsion composition 1 obtained by dispersing in water a mixture comprising component (B), lacking component (C), and optionally comprising some or all of component (A) and components (D) and (G), and
emulsion composition 2 obtained by dispersing in water a mixture comprising component (C), lacking component (B), and additionally comprising the remaining components,
such that the sum of the silicone components in composition 2 is 3 parts by weight or less per 100 parts by weight of the sum of the silicone components in compositions 1 and 2; and mixing together compositions 1 and 2 just prior to use.
13. A method for preparing the organopolysiloxane emulsion composition for release paper or release film of claim 1 , comprising the steps of preparing:
emulsion composition 1′ obtained by dispersing in water a mixture comprising component (B), lacking components (C) and (D), and optionally comprising some or all of component (A) and component (G),
emulsion composition 2′ obtained by dispersing in water a mixture comprising component (C), lacking components (B) and (D), and optionally comprising some or all of component (A) and component (G), and
emulsion composition 3′ obtained by dispersing in water a mixture comprising component (D), lacking component (B) and/or component (C), and additionally comprising the remaining components,
such that the sum of the silicone components in composition 2′ is 3 parts by weight or less per 100 parts by weight of the sum of the silicone components in compositions 1′, 2′ and 3′; and mixing together compositions 1′, 2′ and 3′ just prior to use.