Process for the manufacture of a crosslinkable composition

1. A process for the preparation of a RMA crosslinkable composition comprising at least one crosslinkable component comprising reactive components A and B each comprising at least 2 reactive groups wherein the at least 2 reactive groups of component A are acidic protons C—H in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups C═C and base catalyst C and one or more N—H group containing reactivity moderating component D that are also a Michael addition donor reactable with component B under the action of catalyst C, characterized in that the one or more reactivity moderating components D have a melting temperature above 60° C. and is first dissolved in one or more crosslinkable components comprising reactive components A or B and the obtained pre-dissolved product is later mixed with other components of the RMA crosslinkable composition and wherein component D is dissolved in the one or more crosslinkable component comprising reactive components A or B at a temperature above its melting temperature.

2. The process of claim 1 , wherein component D is dissolved in the one or more crosslinkable component comprising reactive components A at a temperature above the melting temperature of reactivity moderating component D.

3. The process of claim 1 , wherein the crosslinkable component is a polymer chosen from the group of polyesters, polyurethanes, polyacrylates, epoxy resins, polyamides and polyvinyl resins, which contains reactive components A or B in the main chain, pendant, terminal or combinations thereof.

4. The process of claim 1 , wherein the crosslinkable components are polymeric components with a weight average molecular weight Mw of at least 250 gr/mol.

5. The process of claim 1 , wherein the crosslinkable component is a polymer comprising reactive component A or B or both and is synthesised at a temperature above the melting temperature of component D and wherein component D is added directly after the synthesis of said polymer and dissolved therein before cooling to a temperature below the melting temperature of the component D.

6. The process of claim 5 , wherein the crosslinkable component is a polyester comprising reactive components A which is synthesised by forming a polyester polymer using reactive component A as monomer or by transesterification of polyester polymer with a reactive component A.

7. The process of claim 1 , wherein reactive component A is malonate or acetoacetate and reactive component B is acryloyl.

8. The process of claim 1 , wherein the N—H group in component D has a pKa (defined in aqueous environment) of at least one unit less than that of the C—H groups in component A.

9. The process of claim 1 , wherein the pKa of the N—H group in component D is lower than 13.

10. The process of claim 1 , wherein component D comprises a molecule containing the N—H as part of a group —(C═O)—NH—(C═O)—, or of a group —NH—(O═S═O)— or a heterocycle in which the nitrogen of the N—H group is contained in a heterocyclic ring.

11. The process of claim 1 , wherein component D is selected from the group consisting of a substituted or unsubstituted succinimide, phthalimide, glutarimide, hydantoin, triazole, pyrazole, imidazole and uracil or mixtures thereof.

12. The process of claim 1 , wherein component D is present in an amount between 0.1 and 10 wt %, relative to the total amount of component D and the amount of the one or more crosslinkable components comprising reactive component A or B.

13. The process of claim 1 , wherein component D is present in such amount that the amount of N—H groups in component D is no more than 30 mole %, relative to C—H donor groups from component A present in the crosslinkable polymer.