Polar solvent solution and production method thereof
A polar solvent solution of the present invention is a polar solvent solution in which a solute containing a polyamine acid is dissolved in a polar solvent. An inorganic salt is added to the solution, and a mole ratio of moisture to the inorganic salt in the solution is 2.5×m×n or less, where m represents the number of cations forming the inorganic salt and n represents a charge number of the cation. A production method of the present invention is a method for producing the above solution, including: changing at, least one of a moisture content and a content of the inorganic salt in the solution to adjust a viscosity of the solution. Thus, the present invention provides a polar solvent solution whose viscosity can be easily adjusted to a desired value and thus enables stable spinning and casting when used as dopes for spinning, film, etc., and methods for producing the same.
1. A polar solvent solution comprising:
a solute containing a polyamino acid;
a polar solvent; and
an inorganic salt,
wherein the solute containing a polyamino acid is dissolved in the polar solvent, and the inorganic salt is added to the solution,
a mole ratio of moisture to the inorganic salt in the solution is 2.5×m×n or less, where m represents the number of cations forming the inorganic salt and n represents a charge number of the cation, and
at least one of a moisture content and a content of the inorganic salt in the solution is chosen to provide a desired viscosity for the solution, and the viscosity of the solution is 100 to 10000 mPa·s.
2. The polar solvent solution according to claim 1 , wherein the polyamino acid is a polypeptide.
3. The polar solvent solution according to claim 2 , wherein the polypeptide is a structural protein.
4. The polar solvent solution according to claim 3 , wherein the structural protein includes a crystal region.
5. The polar solvent solution according to claim 2 , wherein the polypeptide is a spider silk protein.
6. The polar solvent solution according to claim 1 , wherein the solution has a moisture content of 0.6% by mass or more and 9.1% by mass or less based on 100% by mass of the solution.
7. The polar solvent solution according to claim 1 , wherein the polar solvent contains at least one selected from the group consisting of dimethylsulfoxide (DMSO), N,N-dimethylformamide (DMF), N,N-dimethylacetamide (DMA), and N-methyl-2-pyrrolidone (NMP).
8. The polar solvent solution according to claim 1 , wherein the inorganic salt is at least one selected from alkali metal halides, alkaline-earth metal halides, alkaline-earth metal nitrates, and thiocyanates.
9. The polar solvent solution according to claim 1 , wherein the solution has a content of the inorganic salt of 1 w/v% or more and 15 w/v% or less based on 100% by volume of the solution.