High-performance glass fiber composition, glass fiber thereof, and composite material
The present invention provides a glass fiber composition, glass fiber and composite material therefrom. The glass fiber composition comprises the following components expressed as percentage by weight: 58.5-62.5% SiO 2 , 14.5-17% Al 2 O 3 , 10.5-14.5% CaO, 8-10% MgO, 0.5%<Li 2 O≤1%, 0.05-1% Na 2 O, 0.05-1% K 2 O, 0.05-1% Fe 2 O 3 , 0.15-1.5% TiO 2 , wherein the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.105-0.22, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.435-0.55. Said composition can increase the mechanical properties of the glass while reducing the glass viscosity, crystallization risk and amount of bubbles, thereby making it more suitable for large-scale production with refractory-lined furnaces.
1. A glass fiber composition; comprising the following components expressed as percentage by weight:
SiO 2
58.5-62.5%
Al 2 O 3
14.5-17%
CaO
10.5-13.2%
MgO
8-10%
Li 2 O
>0.6%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.15-1.5%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.125-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.55.
2. The glass fiber composition according to claim 1 , comprising SrO at a content of 0-2% expressed as percentage by weight.
3. The glass fiber composition according to claim 2 , comprising SrO at a content of 0.2-1.5% expressed as percentage by weight.
4. The glass fiber composition according to claim 3 , wherein the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
5. The glass fiber composition according to claim 1 , wherein the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
6. The glass fiber composition according to claim 1 , wherein the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
7. The glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.6%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.15-1.5%
SrO
0-2%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.125-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
8. The glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.75%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.2-1.5%
SrO
0-2%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.155-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
9. The glass fiber composition according to claim 1 , comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.6%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.15-1.5%
SrO
0.2-1.5%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.125-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.55, and the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
10. A glass fiber being produced from the glass fiber composition described in claim 1 .
11. The glass fiber according to claim 10 , wherein the glass fiber composition comprising SrO at a content of 0-2% expressed as percentage by weight.
12. The glass fiber according to claim 10 , wherein the glass fiber composition comprising SrO at a content of 0.2-1.5% expressed as percentage by weight.
13. The glass fiber according to claim 12 , wherein the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
14. The glass fiber according to claim 10 , wherein the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
15. The glass fiber according to claim 10 , wherein the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
16. The glass fiber according to claim 10 , wherein the glass fiber composition comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.6%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.15-1.5%
SrO
0-2%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.125-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
17. The glass fiber according to claim 10 , wherein the glass fiber composition comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.75%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.2-1.5%
SrO
0-2%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.155-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.53.
18. The glass fiber according to claim 10 , wherein the glass fiber composition comprising the following components expressed as percentage by weight:
SiO 2
59-62%
Al 2 O 3
15-16.5%
CaO
11.8-13.2%
MgO
8-10%
Li 2 O
>0.6%, and ≤1%
Na 2 O
0.05-1%
K 2 O
0.05-1%
Fe 2 O 3
0.05-1%
TiO 2
0.15-1.5%
SrO
0.2-1.5%
wherein, the range of the molar percentage ratio C1=Li 2 O/Al 2 O 3 is 0.125-0.177, and the range of the molar percentage ratio C2=MgO/(CaO+MgO) is 0.471-0.55, and the range of the weight percentage ratio C3=(MgO+SrO)/CaO is 0.58-0.9.
19. A composite material incorporating the glass fiber described in claim 10 .