Surface treatment composition
View Patent ↗The present invention relates to an acidic aqueous composition for treating of zirconium-pretreated metal-based substrate surfaces such as steel metals or aluminium surfaces, a process for treating the substrate surfaces with the composition and the use of the composition as post-treatment of zirconium-pretreated metal-based substrate surfaces for subsequent electrocoating of the surfaces to increase corrosion resistance of said metal-based surfaces prior to electro-coating (e-coat) applications and increases detergent and chemical resistance of treated surfaces used in the white goods industry. The acidic aqueous composition comprises trivalent chromium ions; and hexafluorozirconate ions; characterized in that the source of trivalent chromium ions is a trivalent chromium nitrate salt.
1. A process for treating of zirconium-pretreated metal-based substrate surfaces, comprising: i providing a zirconium-pretreated metal-based substrate; and ii. applying to surfaces of the substrate an acidic aqueous composition comprising: a. trivalent chromium ions; and b. hexafluorozirconate ions; characterized in that the sole source of the trivalent chromium ions is a trivalent chromium nitrate salt.
2. The process according to claim 1 wherein the concentration of trivalent chromium ions ranges between 10 and 5,000 mg/L.
3. The process according to claim 1 wherein the zirconium-pretreated metal-based substrate surfaces are obtained by pretreating with an aqueous chromium ion-free composition comprising hexafluorozirconate ions.
4. The process according to claim 1 wherein the trivalent chromium nitrate salt is Cr(NO 3 ) 3 or Cr(NO 3 ) 3 ·9 H 2 O.
5. The process according to claim 1 wherein the concentration of hexafluorozirconate ions independently ranges between 10 and 10,000 mg/L.
6. The process according to claim 1 wherein the source of hexafluorozirconate ions independently is selected from the group consisting of hexafluorozirconic acid, ammonium hexafluorozirconate, an alkali metal hexafluorozirconate, an alkaline earth metal hexafluorozirconate and a transition metal hexafluorozirconate.
7. The process according to claim 1 wherein a pH value of the acidic aqueous composition ranges between 2.0 and 5.5.
8. The process according to claim 1 wherein the acidic aqueous composition is free from added sulfate ions and chloride ions.
9. The process according to claim 1 wherein the acidic aqueous composition is free from added magnesium ions, nickel ions and zinc ions.
10. The process according to claim 1 wherein the zirconium-pretreated metal-based substrate surfaces are zirconium-pretreated steel substrate surfaces or zirconium-pretreated aluminum substrate surfaces or zirconium-pretreated aluminum alloy substrate surfaces.
11. The process according to claim 1 wherein the treating according to step ii. is by spraying the acidic aqueous composition onto the zirconium-pretreated metal-based substrate surfaces at a temperature of between 20 to 25° C.
12. The process according to claim 1 wherein the zirconium-pretreated metal-based substrate surfaces are derived by step i1, treating the metal-based substrate surfaces with an aqueous chromium ion-free composition comprising hexafluorozirconate ions to obtain said zirconium-pretreated metal-based substrate surfaces prior to step ii.
13. The process according to claim 12 wherein the aqueous chromium ion-free composition according to step i1 has a pH of between 4.0 and 5.0 and a concentration of hexafluorozirconate ions between 100 and 5,000 mg/L.