Electrostatic ink compositions
Herein is disclosed an electrostatic ink composition. In some examples, the electrostatic ink compositions comprise: a carrier liquid; a resin; and a phosphorescent pigment.
1. An electrostatic ink composition comprising:
a carrier liquid;
a charge director;
substantially no charge adjuvant;
a resin;
a phosphorescent pigment selected from the group consisting of an alkaline earth metal aluminate with titanium, a silicate aluminate, and a silicate; and
a tackifier selected from the group consisting of a rosin resin, a terpene resin, and a copolymer of vinyl acrylate, wherein between at least about 0.1 wt% and about 5 wt% of the tackifier is dissolved in the carrier liquid based on a total weight of the electrostatic ink composition.
2. An electrostatic ink composition according to claim 1 , wherein the phosphorescent pigment constitutes from about 10 wt. % to about 50 wt. % of the total solids of the electrostatic ink composition.
3. The electrostatic ink composition according to claim 1 , wherein the phosphorescent pigment is the alkaline earth metal aluminate with titanium.
4. The electrostatic ink composition according to claim 1 , wherein the phosphorescent pigment is the silicate aluminate.
5. The electrostatic ink composition according to claim 1 , wherein the resin comprises a polymer having acid side groups.
6. An electrostatic ink composition according to claim 5 , wherein the resin comprises a copolymer of an alkylene monomer and a monomer having an acid side group.
7. An electrostatic ink composition according to claim 6 , wherein the alkylene monomer is an ethylene or a propylene monomer and the monomer having an acid side group is an acrylic acid monomer or a methacrylic acid monomer.
8. An electrostatic ink composition according to claim 5 , wherein the polymer having acid side groups has a melt flow rate of greater than about 200 g/10 minutes.
9. An electrostatic ink composition according to claim 8 , wherein the polymer having acid side groups having a melt flow rate of greater than about 200 g/10 minutes constitutes at least 50 wt. % of the resin.
10. A method for producing the electrostatic ink composition according to claim 1 , the method comprising combining the resin, the phosphorescent pigment, the charge director, the substantially no charge adjuvant, the tackifier, and the carrier liquid.
11. The method according to claim 10 comprising first combining the resin and the carrier liquid to form a resin and carrier liquid mixture, and subsequently combining the phosphorescent pigment with the resin and carrier liquid mixture to form the electrostatic ink composition, and then adding the tackifier to the electrostatic ink composition.
12. The method according to claim 11 , wherein the resin and the carrier liquid are combined and mixed at a temperature in the range of 100 ° C. to 200 ° C., and the resulting mixture is cooled to have a temperature of lower than 100 ° C. before the phosphorescent pigment is added to the resin and carrier liquid mixture.
13. The method according to claim 11 , further comprising grinding a combination of the resin, the phosphorescent pigment, and the carrier liquid for about 2 hours at a grinding speed of about 250 rpm and a temperature of about 40 ° C.
14. The method according to claim 11 , further comprising grinding a combination of the resin, the phosphorescent pigment, and the carrier liquid in an attritor, wherein the overall material in the attritor is in the range of about 230g to about 1000g.
15. An electrostatic ink composition comprising:
a carrier liquid;
a charge director;
substantially no charge adjuvant;
a resin;
a phosphorescent pigment selected from the group consisting of an alkaline earth metal aluminate with titanium, a silicate alum inate, a zinc sulfide, and a silicate; and
a tackifier dissolved in the carrier liquid, the tackifier being a rosin resin.
16. The electrostatic ink composition according to claim 1 , wherein the charge director is selected from the group consisting of metal salts of sulfo-succinates, metal salts of oxyphosphates, metal salts of alkyl-benzenesulfonic acid, polyoxyethylated alkylamines, lecithin, polyvinylpyrrolidone, organic acid esters of polyvalent alcohols, polybutylene succinim ides, glyceride salts, and combinations thereof.
17. The electrostatic ink composition according to claim 1 , wherein the charge director is selected from the group consisting of metal salts of oxyphosphates, metal salts of alkyl-benzenesulfonic acid, polyoxyethylated alkylamines, polyvinylpyrrolidone, organic acid esters of polyvalent alcohols, polybutylene succinim ides, glyceride salts, and combinations thereof.
18. The electrostatic ink composition according to claim 15 , wherein the rosin resin is a dimerized rosin acid with an acid number of 145 and softening point of 144 ° C.