Power storage device and manufacturing method thereof
View Patent ↗In initial charge and discharge, decomposition products or a gas is generated, degrading a battery. At least one of solvents (e.g., ethylene carbonate) used for an electrolytic solution is brought into contact with a positive electrode and a negative electrode and then charge is performed to some degree, and after that, a different solvent or electrolytic solution (e.g., ethyl methyl carbonate or vinylene carbonate) was added to adjust the electrolytic solution and then charge is performed. Through this process, stable coating films are formed in initial charge and discharge, which stably inhibits a side reaction between the electrolytic solution and an active material.
1. A method for manufacturing a power storage device, comprising:
putting a positive electrode and a negative electrode in a container with an opening;
injecting a first electrolytic solution containing an electrolyte, a first solvent, a second solvent, and a third solvent into the opening;
sealing the opening and then performing charge under a first condition;
performing a first step of removing a gas from the container;
further adding the third solvent into the first electrolytic solution;
performing charge under a second condition;
performing a second step of removing a gas from the container;
performing charge under a third condition; and
performing discharge and then repeating charge and discharge to obtain a power storage device containing a second electrolytic solution,
wherein a first solvent content in the first electrolytic solution is determined by analyzing a power storage device that is fabricated in advance using a deuterated product of the first solvent and a deuterated product of the second solvent, and subjected to initial charge and discharge so as to deteriorate.
2. The method for manufacturing a power storage device, according to claim 1 , wherein the electrolyte is a lithium salt.
3. The method for manufacturing a power storage device, according to claim 1 , further comprising:
injecting vinylene carbonate into the first electrolytic solution after the first step of removing a gas from the container.
4. The method for manufacturing a power storage device, according to claim 1 , wherein charge under the first condition, the second condition, or the third condition is performed with the container pressurized.
5. The method for manufacturing a power storage device, according to claim 4 , wherein in the pressurization, higher pressure is applied to a region overlapping with the negative electrode and the positive electrode than to the other region.
6. The method for manufacturing a power storage device, according to claim 1 , wherein the first solvent is ethylene carbonate.
7. The method for manufacturing a power storage device, according to claim 1 , wherein the second solvent is diethyl carbonate.
8. The method for manufacturing a power storage device, according to claim 1 , wherein the third solvent is ethyl methyl carbonate.
9. The method for manufacturing a power storage device, according to claim 1 ,
wherein the first electrolytic solution contains the first solvent at more than 50 vol %, and
wherein the second electrolytic solution contains the first solvent at 40 vol % or less.