IP Library › Granted Patent US 10,367,202
Granted Patent B2
US 10,367,202 · App. 15/586,670 · Granted Jul 30, 2019

Electrodes, compositions, and devices having high structure carbon blacks

Inventors: Andriy Korchev (Westford, MA); Aurelien L. DuPasquier (Westford, MA); Miodrag Oljaca (Concord, MA); Geoffrey D. Moeser (Groton, MA)
Assignee: Cabot Corporation
H01M4/625C09C1/50C09C1/56H01G11/42H01G11/46H01M4/505H01M4/525H01M10/0525C01P2002/60C01P2002/82C01P2004/64C01P2006/12C01P2006/19C01P2006/22C01P2006/40H01M2004/021
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Quick Facts
Patent No.
US 10,367,202
App. No.
15/586,670
Granted
Jul 30, 2019
Kind
B2
Abstract

An electrode for an energy storage device includes carbon black particles having (a) a Brunauer-Emmett-Teller (BET) surface area ranging from 70 to 120 m 2 /g; (b) an oil absorption number (OAN) ranging from 180 to 310 mL/100 g; (c) a surface energy less than or equal to 15 mJ/m 2 ; and (d) either an L a crystallite size less than or equal to 29 Å, or a primary particle size less than or equal to 24 nm.

Claims (13)

1. An electrode for an energy storage device, comprising:

a lithium ion-based electroactive material; and

carbon black particles having (a) a Brunauer-Emmett-Teller (BET) surface area ranging from 70 to 120 m 2 /g; (b) an oil absorption number (OAN) ranging from 180 to 310 mL/100 g; (c) a surface energy less than or equal to 15 mJ/m 2 ; and (d) either an L a crystallite size less than or equal to 29 Å, or a primary particle size less than or equal to 24 nm.

2. The electrode of claim 1 , wherein the carbon black particles have both an La crystallite size less than or equal to 29 Å, and a particle size less than or equal to 24 nm.

3. The electrode of claim 1 , wherein the carbon black particles have a particle size less than or equal to 24 nm.

4. The electrode of claim 1 , wherein the carbon black particles have a surface energy less than or equal to 10 mJ/m 2 .

5. The electrode of claim 1 , wherein the carbon black particles have a % crystallinity (I G /I G+D ) less than or equal to 45%, as determined by Raman spectroscopy.

6. The electrode of claim 1 , wherein the carbon black particles have an oxygen content of less than or equal to 1 wt %.

7. The electrode of claim 1 , wherein the carbon black particles have a dispersability of less than one micron (D 50 by volume).

8. The electrode of claim 1 , wherein the carbon black particles have a ratio of statistical thickness surface area to Brunauer-Emmett-Teller surface area (STSA:BET) greater than 0.95:1.

9. The electrode of claim 1 , wherein the carbon black particles have a BET surface area ranging from 90 to 110 m 2 /g.

10. The electrode of claim 1 , wherein the carbon black particles have an OAN ranging from 220 to 270 mL/100 g.

11. The electrode of claim 1 , wherein the carbon black particles have an L c crystallite size ranging from 17 to 27 Angstroms.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 17, 2017
From: KORCHEV, ANDRIY; DUPASQUIER, AURELIEN L.; OLJACA, MIODRAG; MOESER, GEOFFREY D.
To: CABOT CORPORATION
Reel/Frame 042407/0824 →
Continuity (2)
Provisional Application 62332142 · May 5, 2016
Related Publication 20170324096A1 · Nov 9, 2017