OLED device structures
Devices having multiple multicomponent emissive layers are provided, where each multicomponent EML includes at least three components. Each of the components in each EML is a host material or an emitter. The devices have improved color stability and relatively high luminance.
1. A device comprising:
a first electrode;
a second electrode;
a first emissive layer disposed between the first electrode and the second electrode, the first emissive layer comprising at least three components, each individually and uniquely selected from the group consisting of: a first host material, a second host material different than the first host material, a first emissive material, and a second emissive material different than the first emissive material; and
a second emissive layer disposed between the first electrode and the second electrode and in direct physical contact with the first emissive layer, the second emissive layer comprising at least three components, each individually and uniquely selected from the group consisting of: a third host material, a fourth host material different than the third host material, a third emissive material, and a fourth emissive material different than the third emissive material.
2. The device of claim 1 , wherein the first emissive layer has a thickness of not more than 70% of the thickness of the second emissive layer.
3. The device of claim 1 , wherein the first emissive layer comprises the first host material and the second host material, and the highest occupied molecular orbital (HOMO) of the first host material is within 15% of the HOMO of the second host material.
4. The device of claim 1 , wherein the first emissive layer comprises the first host material and the second host material, and the lowest unoccupied molecular orbital (LUMO) of the first host material is within 35% of the LUMO of the second host material.
5. The device of claim 1 , wherein the first emissive layer comprises:
the first host material;
the second host material; and
the first emissive material.
6. The device of claim 5 , wherein the second emissive layer comprises:
the third host material;
the fourth host material; and
the second emissive material.
7. The device of claim 1 , wherein the first emissive layer comprises:
the first host material;
the first emissive material; and
the second emissive material.
8. The device of claim 7 , wherein the second emissive layer comprises:
the third host material;
the third emissive material; and
the fourth emissive material.
9. The device of claim 7 , wherein the second emissive layer comprises:
the third host material;
the third emissive material, wherein the third emissive material comprises the first emissive material; and
the fourth emissive material, wherein the fourth emissive material comprises the second emissive material;
wherein the relative concentration of emissive materials is different in the first emissive layer than in the second emissive layer.
10. The device of claim 1 , wherein the first emissive layer comprises:
the first host material;
the second host material; and
a red organic emissive material; and
the second emissive layer comprises:
the third host material, wherein the third host material comprises the first host material;
the fourth host material; and
a green organic or organometallic emissive material.
11. The device of claim 10 , wherein the first emissive layer has a thickness of not more than 70% of the second emissive layer.
12. The device of claim 1 , further comprising a third emissive layer.
13. The device of claim 12 , wherein the device emits white light when operated.
14. The device of claim 1 , wherein each of the first, second, third, and fourth host materials is an organic compound, a metal complex, or a combination thereof.
15. The device of claim 1 , wherein the first and second emissive layers jointly produce yellow light when the device is operated.
16. The device of claim 1 , wherein the first and second emissive layers jointly produce light for which at least 25% of the total integrated intensity is at a wavelength of 500-600 nm.
17. The device of claim 1 , wherein the first and second emissive layers jointly produce light for which at least 25% of the total integrated intensity is at a wavelength of 600-750 nm.
18. The device of claim 1 , wherein one or more of the first emissive material, the second emissive material, the third emissive material, and the fourth emissive material are phosphorescent.
19. The device of claim 1 , wherein one or more of the first emissive material, the second emissive material, the third emissive material, and the fourth emissive material comprise an organic or organometallic compound.
20. The device of claim 1 , wherein the first emissive layer comprises:
the first host material;
the second host material, wherein the second host material is different than the first host material;
the first emissive material; and
the second emissive material, wherein the second emissive material is different than the first emissive material.
21. The device of claim 1 , wherein the second emissive layer comprises the same materials as the first emissive layer, in different relative concentrations than in the first emissive layer.
22. A consumer electronic product comprising:
an organic light emitting device (OLED) comprising:
a first electrode;
a second electrode;
a first emissive layer disposed between the first electrode and the second electrode, the first emissive layer comprising at least three components, each individually and uniquely selected from the group consisting of: a first host material, a second host material different than the first host material, a first emissive material, and a second emissive material different than the first emissive material; and
a second emissive layer disposed between the first electrode and the second electrode and in direct physical contact with the first emissive layer, the second emissive layer comprising at least three components, each individually and uniquely selected from the group consisting of: a third host material, a fourth host material different than the third host material, a third emissive material, and a fourth emissive material different than the third emissive material.
23. The consumer electronic product of claim 22 , wherein the consumer electronic product is a device selected from the group consisting of: a flat panel display, a computer monitor, a medical monitor, a television, a billboard, a light for interior or exterior illumination and/or signaling, a heads-up display, a fully or partially transparent display, a flexible display, a laser printer, a telephone, a cell phone, tablet, a phablet, a personal digital assistant (PDA), a wearable device, a laptop computer, a digital camera, a camcorder, a viewfinder, a micro-display that is less than 2 inches diagonal, a 3-D display, a virtual reality or augmented reality display, a vehicle, a video walls comprising multiple displays tiled together, a theater or stadium screen, and a sign.