Solid state image sensor, production method thereof and electronic device
A solid state image sensor includes a semiconductor substrate where photoelectric conversion regions for converting light into charges are arranged per pixel planarly arranged; an organic photoelectric conversion film laminated at a light irradiated side of the semiconductor substrate via an insulation film and formed at the regions where the pixels are formed; a lower electrode formed at and in contact with the organic photoelectric conversion film at a semiconductor substrate side; a first upper electrode laminated at a light irradiated side of the organic photoelectric conversion film and formed such that ends of the first upper electrode are substantially conform with ends of the organic photoelectric conversion film when the solid state image sensor is planarly viewed; and a film stress suppressor for suppressing an effect of a film stress on the organic photoelectric conversion film, the film stress being generated on the first upper electrode.
1. An imaging device, comprising:
a semiconductor substrate including a plurality of pixels, each pixel of the plurality of pixels including a photoelectric conversion region;
an insulating layer provided at a light-incident side of the semiconductor substrate;
a plurality of lower electrodes provided at a light-incident side of the insulating layer, each lower electrode of the plurality of lower electrodes corresponding to a pixel of the plurality of pixels;
a continuously formed organic photoelectric conversion film provided at a light-incident side of the plurality of lower electrodes; and
an upper electrode provided at a light-incident side of the organic photoelectric conversion film,
wherein each lower electrode of the plurality of lower electrodes is located between the continuously formed organic photoelectric conversion film and the photoelectric conversion region, and
wherein light-incident sides of the plurality of lower electrodes are substantially coplanar with the light-incident side of the insulating layer.
2. The imaging device according to claim 1 , further comprising:
a second upper electrode provided at a light-incident side of the upper electrode.
3. The imaging device according to claim 2 , wherein the upper electrode and the second upper electrode are formed of a same material or a material having a property that is substantially the same.
4. The imaging device according to claim 2 , wherein the second upper electrode is formed around an outer periphery of the upper electrode to connect ends of the first upper electrode and the insulating layer.
5. The imaging device according to claim 2 , wherein the second upper electrode is laminated on the upper electrode such that ends of the upper electrode substantially conform with the second upper electrode.
6. The imaging device according to claim 1 , further comprising:
a second insulating layer provided on the upper electrode such that ends of the organic photoelectric conversion film, the upper electrode, and the second insulating layer are substantially coplanar.
7. The imaging device according to claim 1 , wherein the organic photoelectric conversion film is disposed on a portion of the insulating layer between the plurality of lower electrodes.
8. The imaging device according to claim 1 , where the upper electrode includes a material that absorbs ultraviolet light having a wavelength of about 400 nm or less.
9. The imaging device according to claim 1 , wherein the organic photoelectric conversion film includes a structure having at least one of an organic p type semiconductor and an organic n type semiconductor.
10. An electronic device, comprising:
an image sensor, including:
a semiconductor substrate including a plurality of pixels, each pixel of the plurality of pixels including a photoelectric conversion region,
an insulating layer provided at a light-incident side of the semiconductor substrate,
a plurality of lower electrodes provided at a light-incident side of the insulating layer, each lower electrode of the plurality of lower electrodes corresponding to a pixel of the plurality of pixels,
a continuously formed organic photoelectric conversion film provided at a light-incident side of the plurality of lower electrodes, and
an upper electrode provided at a light-incident side of the organic photoelectric conversion film,
wherein each lower electrode of the plurality of lower electrodes is located between the continuously formed organic photoelectric conversion film and the photoelectric conversion region, and
wherein light-incident sides of the plurality of lower electrodes is substantially coplanar with the light-incident side of the insulating layer; and
at least one lens configured to guide light to a light-receiving surface of the image sensor.
11. The electronic device according to claim 10 , further comprising:
a second upper electrode provided at a light-incident side of the upper electrode.
12. The electronic device according to claim 11 , wherein the upper electrode and the second upper electrode are formed of a same material or a material having a property that is substantially the same.
13. The electronic device according to claim 11 , wherein the second upper electrode is formed around an outer periphery of the upper electrode to connect ends of the first upper electrode and the insulating layer.
14. The electronic device according to claim 11 , wherein the second upper electrode is laminated on the upper electrode such that ends of the upper electrode substantially conform with the second upper electrode.
15. The electronic device according to claim 10 , further comprising:
a second insulating layer provided on the upper electrode such that ends of the organic photoelectric conversion film, the upper electrode, and the second insulating layer are substantially coplanar.
16. The electronic device according to claim 10 , wherein the organic photoelectric conversion film is disposed on a portion of the insulating layer between the plurality of lower electrodes.
17. The electronic device according to claim 10 , where the upper electrode includes a material that absorbs ultraviolet light having a wavelength of about 400 nm or less.
18. The electronic device according to claim 10 , wherein the organic photoelectric conversion film includes a structure having at least one of an organic p type semiconductor and an organic n type semiconductor.