IP Library Granted Patent US 10,879,360
Granted Patent B2
US 10,879,360 · App. 15/592,712 · Granted Dec 29, 2020

Composite oxide semiconductor and transistor

Inventors: Shunpei Yamazaki (Setagaya, JP); Yasuharu Hosaka (Tochigi, JP); Yukinori Shima (Tatebayashi, JP); Junichi Koezuka (Tochigi, JP); Kenichi Okazaki (Tochigi, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L29/24H01L29/0692H01L29/1037H01L29/42384H01L29/4908H01L29/7869H01L29/78648H01L29/78696
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Quick Facts
Patent No.
US 10,879,360
App. No.
15/592,712
Granted
Dec 29, 2020
Kind
B2
Abstract

A novel material is provided. A composite oxide semiconductor includes a first region and a second region. The first region contains indium. The second region contains an element M (the element M is one or more of Ga, Al, Hf, Y, and Sn). The first region and the second region are arranged in a mosaic pattern. The composite oxide semiconductor further includes a third region. The element M is gallium. The first region contains indium oxide or indium zinc oxide. The second region contains gallium oxide or gallium zinc oxide. The third region contains zinc oxide.

Claims (28)

1. A composite oxide semiconductor comprising:

a plurality of first regions each comprising more indium than an element M; and

a plurality of second regions each comprising more of the element M than any other metal element, a diameter of each of the plurality of second regions being greater than or equal to 0.5 nm and less than or equal to 10 nm,

wherein:

the element M is one or more of Ga, Al, Hf, Y, and Sn, and

the plurality of first regions and the plurality of second regions are mixed in the composite oxide semiconductor.

2. The composite oxide semiconductor according to claim 1 , wherein the diameter of each of the plurality of second regions is greater than or equal to 1 nm and less than or equal to 2 nm.

3. The composite oxide semiconductor according to claim 1 , wherein an atomic ratio between indium and the element M is 4:2, or in a neighborhood thereof in the composite oxide semiconductor.

4. The composite oxide semiconductor according to claim 1 , wherein an atomic ratio between indium and the element M is 5:1, or in a neighborhood thereof in the composite oxide semiconductor.

5. The composite oxide semiconductor according to claim 1 , wherein an atomic ratio between indium and the element M is 1:1, or in a neighborhood thereof in the composite oxide semiconductor.

6. A transistor comprising the composite oxide semiconductor according to claim 1 .

7. The composite oxide semiconductor according to claim 1 , wherein the composite oxide semiconductor has a single crystal structure, a polycrystalline structure, or a c-axis-aligned crystalline (CAAC) structure.

8. The composite oxide semiconductor according to claim 1 , wherein density of the element M is gradually lowered from a central portion toward a surrounding portion in one of the plurality of second regions.

9. The composite oxide semiconductor according to claim 1 , wherein elements included in the composite oxide semiconductor are unevenly distributed to form the mixed first region and second region.

10. A composite oxide semiconductor comprising:

a plurality of first regions each comprising indium oxide or indium zinc oxide as a main component;

a plurality of second regions each comprising gallium oxide or gallium zinc oxide as a main component, a diameter of each of the plurality of second regions being greater than or equal to 0.5 nm and less than or equal to 10 nm; and

a plurality of third regions each comprising zinc oxide,

wherein the plurality of first regions, and the plurality of second regions, and the plurality of third regions are mixed in the composite oxide semiconductor.

11. The composite oxide semiconductor according to claim 10 , wherein each of the plurality of first regions, the plurality of second regions, and the plurality of third regions has a blurred periphery and a cloud-like composition.

12. The composite oxide semiconductor according to claim 10 , wherein the diameter of each of the plurality of second regions is greater than or equal to 1 nm and less than or equal to 2 nm.

13. The composite oxide semiconductor according to claim 10 , wherein an atomic ratio between indium, gallium, and zinc is 4:2:3, or in a neighborhood thereof in the composite oxide semiconductor.

14. The composite oxide semiconductor according to claim 10 , wherein an atomic ratio between indium, gallium, and zinc is 5:1:6, or in a neighborhood thereof in the composite oxide semiconductor.

15. The composite oxide semiconductor according to claim 10 , wherein an atomic ratio between indium, gallium, and zinc is 1:1:1, or in a neighborhood thereof in the composite oxide semiconductor.

16. A transistor comprising the composite oxide semiconductor according to claim 10 .

17. The composite oxide semiconductor according to claim 10 , wherein the composite oxide semiconductor has a single crystal structure, a polycrystalline structure, or a c-axis-aligned crystalline (CAAC) structure.

18. The composite oxide semiconductor according to claim 10 , wherein density of gallium is gradually lowered from a central portion toward a surrounding portion in one of the plurality of second regions.

19. The composite oxide semiconductor according to claim 10 , wherein elements included in the composite oxide semiconductor are unevenly distributed to form the mixed first region, second region, and third region.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 19, 2017
From: YAMAZAKI, SHUNPEI; HOSAKA, YASUHARU; SHIMA, YUKINORI; KOEZUKA, JUNICHI; OKAZAKI, KENICHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 042745/0246 →
Priority Claims (1)
JP 2016-100939 · May 19, 2016 · national
Continuity (1)
Related Publication 20170338315A1 · Nov 23, 2017