Nonaqueous redox flow battery electrolyte comprising an ionic liquid with a metal cation coordinated to redox-active ligands
Nonaqueous redox flow batteries (RFB) hold the potential for high energy density grid scale storage, though are often limited by the solubility of the redox-active species in their electrolytes. A systematic approach enables an increase the concentration of redox-active species in electrolytes for nonaqueous RFB, starting from a metal-coordination-cation-based ionic liquid. As an example, starting with an ionic liquid consisting of a metal coordination cation (MetIL), ferrocene-containing ligands and iodide anions can be substituted into the original MetIL structure, enabling a nearly 4× increase in capacity compared to original MetIL structure. Application of this strategy to other chemistries, optimizing electrolyte melting point and conductivity could yield >10 M redox-active electrons.
1. A nonaqueous redox flow battery electrolyte, comprising a redox-active ionic liquid comprising a metal coordination cation coordinated to a number of redox-active ligands and an anion having an oxidation state, wherein the metal coordination cation comprises a transition metal ion and at least one of the redox-active ligands comprises an aminoalcohol, or a dialcoholamine, wherein the ionic liquid comprises Fe(EA) 6-x (FcEA) x (OTf) 2-y I y , wherein iron is the transition metal ion having a coordination number of 6, wherein the aminoalcohol is ethanolamine, 6-x is the number of ethanolamine ligands, and x is the number of {[(2-hydroxyethyl)amino]carbonyl}ferrocene redox-active ligands substituted for ethanolamine ligands, and wherein the anion is iodide, 2 is the oxidation state, and y is the number of iodide anions substituted for triflate anions.
2. The electrolyte of claim 1 , wherein x is 6 or less.
3. The electrolyte of claim 2 , wherein x is 1 or 2.
4. The electrolyte of claim 1 , wherein y is 2 or less.
5. The electrolyte of claim 4 , wherein y is 0 or 1.
6. The electrolyte of claim 1 , wherein the Fe(EA) 6-x (FcEA) x (OTf) 2-y I y comprises greater than 1.79 M and less than 4.2 M redox-active electrons in the ionic liquid.