Protective layers for electrodes and electrochemical cells
Articles and methods including layers for protection of electrodes in electrochemical cells are provided. As described herein, a layer, such as a protective layer for an electrode, may comprise a plurality of particles (e.g., crystalline inorganic particles, amorphous inorganic particles). In some aspects, at least a portion of the plurality of particles (e.g., inorganic particles) are fused to one another. For instance, in some aspects, the layer may be formed by aerosol deposition or another suitable process that involves subjecting the particles to a relatively high velocity such that fusion of particles occurs during deposition. In some cases, the protective layer may be porous.
1. An electrochemical cell, comprising:
a first layer;
a second layer disposed on the first layer, wherein the second layer is porous and comprises a plurality of particles, wherein the plurality of particles in the second layer are formed from particles having an original surface,
wherein at least a portion of the plurality of particles comprise a non-ionically conductive material,
wherein the second layer has an ionic conductivity less than about 10 −6 S/cm,
wherein at least a portion of the plurality of particles are fused to one another such that at least a portion of the original surface of the particles can no longer be discerned in the plurality of particles fused to one another,
wherein the second layer has an average thickness between about 0.1 microns and about 5 microns; and
a liquid electrolyte,
wherein the second layer is permeable to the liquid electrolyte.
2. An article for use in an electrochemical cell, comprising:
a first layer comprising lithium metal; and
a second layer deposited on the first layer, wherein the second layer comprises a plurality of particles, wherein the plurality of particles in the second layer are formed from particles having an original surface, and wherein the second layer is porous,
wherein at least a portion of the plurality of particles are at least partially embedded within the lithium metal of the first layer,
wherein at least a portion of the plurality of particles are fused to one another such that at least a portion of the original surface of the particles can no longer be discerned in the plurality of particles fused to one another,
wherein the second layer has an average thickness between about 0.1 microns and about 5 microns.
3. An electrode, comprising:
a first layer comprising an electroactive layer and a coating, wherein the coating comprises a first material; and
a second layer deposited on the coating of the first layer, wherein the second layer is a protective layer and comprises a plurality of particles formed of a second material, and wherein the plurality of particles in the second layer are formed from particles having an original surface,
wherein the first material has a hardness greater than a hardness of the second material,
wherein at least a portion of the plurality of particles are fused to one another such that at least a portion of the original surface of the particles can no longer be discerned in the plurality of particles fused to one another, and
wherein the second layer has an average thickness between about 0.1 microns and about 5 microns.
4. An electrochemical cell as in claim 1 , wherein at least a portion of the plurality of particles are polymeric particles.
5. An electrochemical cell as in claim 1 , wherein the non-ionically conductive material comprises a ceramic material.
6. An electrochemical cell as in claim 1 , wherein the non-ionically conductive material is present in the second layer in an amount of at least about 20 wt % versus the total second layer composition.
7. An electrochemical cell as in claim 4 , wherein the polymeric particles are present in the second layer in an amount of at least about 10 wt % versus the total second layer composition.
8. An electrochemical cell as in claim 1 , wherein at least a portion of the surface of the second layer not in contact with the first layer has a surface roughness of greater than or equal to about 0.1 μm.
9. An electrochemical cell as in claim 1 , wherein the non-ionically conductive material is present in the second layer in an amount of at least about 80 wt % of the second layer.
10. An electrochemical cell as in claim 1 , wherein the plurality of particles have an average largest cross-sectional dimension between about 0.5 microns and about 20 microns.
11. An electrochemical cell as in claim 1 , wherein the second layer comprises an ionically conductive material, and wherein the ionically conductive material comprises an inorganic material.
12. An electrochemical cell as in claim 1 , wherein the second layer comprises an ionically conductive material, and wherein the ionically-conductive material comprises a ceramic, wherein the ceramic is a Li 24 SiP 2 S 19 .
13. An electrochemical cell as in claim 1 , wherein the second layer comprises an ionically conductive material, and wherein at least a portion of the ionically conductive material is crystalline.
14. An electrochemical cell as in claim 1 , wherein the second layer has a density of between 1.5 and 6 g/cm 3 .
15. An electrochemical cell as in claim 1 , wherein the second layer has a porosity of at least about 25%.
16. An electrochemical cell as in claim 1 , wherein the first layer comprises a polymer.
17. An electrochemical cell as in claim 16 , wherein the polymer is a polymer gel or forms polymer gel when exposed to liquid electrolyte.
18. An electrochemical cell as in claim 1 , wherein the first layer comprises an electroactive material.
19. An electrochemical cell as in claim 1 , wherein the first layer comprises lithium metal.
20. An electrochemical cell as in claim 1 , wherein the first layer is a separator.
21. An electrochemical cell as in claim 1 , wherein the non-ionically conductive material comprises alumina or silica.
22. An electrochemical cell as in claim 1 , wherein the non-ionically conductive material in the second layer has an electronic conductivity of less than about 10 −10 S/cm.
23. An electrochemical cell of claim 1 , wherein the first layer comprises a coating of a material on a surface of the first layer.
24. An electrochemical cell of claim 1 , wherein the first layer comprises a coating of a non-lithium ion conductive material on a surface of the first layer.
25. An electrochemical cell as in claim 1 , wherein particles fused to one another have a minimum cross-sectional dimension of greater than 0.75 microns.