Processes for preparing lithium hydroxide
There are provided methods for preparing lithium hydroxide. For example, such methods can comprise submitting an aqueous composition comprising a lithium compound to an electrolysis under conditions suitable for converting at least a portion of said lithium compound into lithium hydroxide. There are also provided methods for preparing lithium sulphate.
1. A process for preparing lithium sulphate, said process comprising:
leaching an acid roasted lithium-containing material with water so as to obtain an aqueous composition comprising Li + and at least one metal ion, wherein the lithium-containing material is a material that has been previously reacted with H 2 SO 4 ;
reacting said aqueous composition comprising Li + and said at least one metal ion with a base so as to obtain a pH of about 4.5 to about 6.5 and thereby at least partially precipitating said at least one metal ion under the form of at least one hydroxide so as to obtain a precipitate comprising said at least one hydroxide and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate;
optionally reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with another base so as to obtain a pH of about 9.5 to about 11.5 and with at least one metal carbonate thereby at least partially precipitating at least one metal ion under the form of at least one carbonate so as to obtain a precipitate comprising said at least one carbonate and an aqueous composition comprising Li + and having a reduced content of said at least one metal ion, and separating said aqueous composition from said precipitate; and
contacting said aqueous composition comprising Li + and having a reduced content of said at least one metal ion with an ion-exchange resin so as to at least partially remove at least one metal ion from said composition, thereby obtaining an aqueous composition comprising a lithium sulphate.
2. The process of claim 1 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.0 to about 6.2.
3. The process of claim 2 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 10 to about 11.
4. The process of claim 1 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.2 to about 6.0.
5. The process of claim 1 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with said base so as to obtain a pH of about 5.4 to about 5.8.
6. The process of claim 1 , wherein said aqueous composition comprising Li + and at least one metal ion is reacted with lime.
7. The process of claim 1 , wherein said at least one metal ion comprised in said aqueous composition that is reacted with said base so as to obtain a pH of about 4.5 to about 6.5 comprises Fe 3+ .
8. The process of claim 1 , wherein said at least one metal ion comprised in said aqueous composition that is reacted with said base so as to obtain a pH of about 4.5 to about 6.5 comprises Al 3+ .
9. The process of claim 2 , wherein said at least one hydroxide comprised in said precipitate is chosen from Al(OH) 3 and Fe(OH) 3 .
10. The process of claim 1 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 9.5 to about 11.5.
11. The process of claim 2 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 10 to about 10.5.
12. The process of claim 1 , wherein said process comprises reacting said aqueous composition comprising Li + and having said reduced content of said at least one metal ion with said another base so as to obtain a pH of about 9.8 to about 10.2.
13. The process of claim 1 , wherein said base used so as to obtain a pH of about 9.5 to about 11.5 is NaOH.
14. The process of claim 1 , wherein said at least one metal carbonate is chosen from Na 2 CO 3 , NaHCO 3 , and (NH 4 ) 2 CO 3 .
15. The process of claim 1 , wherein said aqueous composition comprising Li + and having said reduced content of said at least one metal ion is reacted with said another base over a period of time sufficient for reducing the content of said at least one metal ion in said aqueous composition below a predetermined value.
16. The process of claim 1 , wherein said ion exchange resin is a cationic resin.
17. The process of claim 1 , wherein said ion exchange resin is a cationic resin that is substantially selective for divalent and/or trivalent metal ions.
18. The process of claim 1 , wherein said acid roasted lithium-containing material is leached with water so as to obtain said aqueous composition comprising Li + and at least three metal ions chosen from the following metals iron, aluminum, manganese and magnesium.
19. The process of claim 1 , wherein said acid roasted lithium-containing material is leached with water so as to obtain said aqueous composition comprising Li + and at least four metal ions chosen from Al 3+ , Fe 2+ , Fe 3+ , Mg 2+ , Ca 2+ , Cr 2+ , Cr 3+ , Cr 6+ , Zn 2+ and Mn 2+ .
20. The process of claim 10 , wherein said acid roasted lithium-containing material is β-spodumene that has been previously reacted with H 2 SO 4 .
21. The process of claim 1 , wherein said acid roasted lithium-containing material is α-spodumene, β-spodumene, lepidolite, pegmatite, petalite, amblygonite, hectorite, smectite, clays, or mixtures thereof, that has been previously reacted with H 2 SO 4 .