IP Library › Granted Patent US 10,195,574
Granted Patent B2
US 10,195,574 · App. 15/618,274 · Granted Feb 5, 2019

Methane conversion apparatus and process using a supersonic flow reactor

Inventors: Robert L. Bedard (McHenry, IL); Christopher Naunheimer (Arlington Heights, IL); Gavin P. Towler (Inverness, IL); Laura E. Leonard (Western Springs, IL); Gregory O. Woodcock (Mesa, AZ); Donald L. Mittendorf (Gold Canyon, AZ)
Assignee: UOP LLC
B01J3/008B01J6/008B01J19/02B01J19/2415B01J19/26C07C2/78C10G50/00B01J2219/00094B01J2219/00123B01J2219/00157B01J2219/0204B01J2219/029B01J2219/0236B01J2219/0263B01J2219/0281B01J2219/0286C10G2300/1025C10G2400/24
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Quick Facts
Patent No.
US 10,195,574
App. No.
15/618,274
Granted
Feb 5, 2019
Kind
B2
Abstract

Apparatus and methods are provided for converting methane in a feed stream to acetylene. A hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream may be treated to convert acetylene to another hydrocarbon process.

Claims (27)

1. An apparatus for producing acetylene from a feed stream comprising methane comprising:

a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;

a reactor shell of the supersonic reactor for defining a reactor chamber;

a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;

an outer layer of the reactor shell for providing structural support thereto;

an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof; and

one or more sensors positioned within the channel and electronically connected to one or more of a display, a monitoring system and a control system.

2. The apparatus of claim 1 wherein the one or more sensors include pressure sensors, temperature sensors, chemical sensors, hydrogen sensors, hydrocarbon sensors, or methane sensors.

3. The apparatus of claim 1 wherein the channel houses one or more support structures to support the inner shell relative to the outer shell.

4. The apparatus of claim 1 wherein the channels are defined by a surface of the reactor shell.

5. The apparatus of claim 1 wherein the channels are within a wall of the reactor shell.

6. The apparatus of claim 1 wherein the channels axially along the reactor shell, circumferentially about the reactor shell, radially through the reactor shell, or helically about the annular reactor shell.

7. The apparatus of claim 1 further comprising an active cooling system for maintaining the reactor portion at a temperature below the melting temperature thereof.

8. An apparatus for producing acetylene from a feed stream comprising methane comprising:

a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;

a reactor shell of the supersonic reactor for defining a reactor chamber;

a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;

an outer layer of the reactor shell for providing structural support thereto;

an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof; and

an isolation valve at an inlet of the supersonic reactor and a control system capable of detecting a change in pressure and in connection with the isolation valve.

9. An apparatus for producing acetylene from a feed stream comprising methane comprising:

a supersonic reactor for receiving the methane feed stream and heating the methane feed stream to a pyrolysis temperature;

a reactor shell of the supersonic reactor for defining a reactor chamber;

a combustion zone of the supersonic reactor for combusting a fuel source to provide a high temperature carrier gas passing through the reactor space at supersonic speeds to heat and accelerate the methane feed stream to a pyrolysis temperature;

an outer layer of the reactor shell for providing structural support thereto;

an inner layer of the reactor shell having a thermal conductivity of between about 200 and about 500 W/m-K for conducting heat from the reactor chamber the inner layer comprising at least copper chrome, copper chrome zinc, copper chrome niobium, copper nickel and copper nickel tungsten and mixtures thereof; and

a pressure relief device in the reactor shell.

Continuity (3)
Continuation 13967391 · Aug 15, 2013
Provisional Application 61691321 · Aug 21, 2012
Related Publication 20170274337A1 · Sep 28, 2017
Cited By (2)
US 12,599,886 US 12,600,623