Nanomaterial having tunable infrared absorption characteristics and associated method of manufacture
A quantum nanomaterial having a bandgap that may be tuned to enable the quantum nanomaterial to detect IR radiation in selected regions including throughout the MWIR region and into the LWIR region is provided. The quantum nanomaterials may include tin telluride (SnTe) nanomaterials and/or lead tin telluride (Pb x Sn 1-x Te) nanomaterials. Additionally, a method of manufacturing nanomaterial that is tunable for detecting IR radiation in selected regions, such as throughout the MWIR region and into the LWIR region, is also provided.
1. A method of manufacturing a lead tin telluride (Pb x Sn 1-x Te) nanomaterial in which x has a value between 0.1 and 0.6, the method comprising:
introducing a dried lead chloride solution into a container;
adding a tin (Sn) precursor solution and a telluride (Te) solution to the dried lead chloride solution within the container to form a mixed solution; and
maintaining the mixed solution at an elevated temperature for a period of time prior to cooling to an ambient temperature to form the Pb x Sn 1-x Te nanomaterial.
2. A method according to claim 1 further comprising maintaining the dried lead chloride solution at a first elevated temperature while adding the Sn precursor solution and the Te solution, and wherein maintaining the mixed solution at an elevated temperature for a period of time prior to cooling comprises maintaining the mixed solution at a second elevated temperature, less than the first elevated temperature, for the period of time after adding the Sn precursor solution and the Te solution.
3. A method according to claim 1 wherein maintaining the mixed solution at an elevated temperature comprises maintaining the mixed solution at 120° C. or more for the period of time after adding the Sn precursor solution and the Te solution.
4. A method according to claim 1 wherein maintaining the mixed solution at an elevated temperature comprises maintaining the mixed solution at the elevated temperature for at least 90 seconds prior to cooling to the ambient temperature to form the Pb x Sn 1-x Te nano material.
5. A method according to claim 1 further comprising:
after maintaining the temperature of the mixed solution at the elevated temperature for the period of time and prior to cooling to the ambient temperature, repeatedly injecting additional amounts of the Sn precursor solution, the Te solution and a lead solution into the mixed solution at different points in time; and
maintaining the mixed solution at an elevated temperature for a period of time following each injection of an additional amount of the Sn precursor solution, the Te solution and the lead solution into the mixed solution prior to a subsequent injection of an additional amount of the Sn precursor solution, the Te solution and the lead solution.
6. A method of manufacturing a lead tin telluride (Pb x Sn 1-x Te) nanomaterial in which x has a value between 0.1 and 0.6, the method comprising:
introducing lead into a container;
adding a tin (Sn) precursor solution and a telluride (Te) solution to the lead within the container to form a mixed solution;
maintaining the mixed solution at an elevated temperature for a period of time prior to cooling to an ambient temperature to form the Pb x Sn 1-x Te nanomaterial;
after maintaining the temperature of the mixed solution at the elevated temperature for the period of time and prior to cooling to the ambient temperature, repeatedly injecting additional amounts of the Sn precursor solution, the Te solution and a lead solution into the mixed solution at different points in time; and
maintaining the mixed solution at an elevated temperature for a period of time following each injection of an additional amount of the Sn precursor solution, the Te solution and the lead solution into the mixed solution prior to a subsequent injection of an additional amount of the Sn precursor solution, the Te solution and the lead solution.
7. A method according to claim 6 wherein introducing lead into the container comprises introducing a dried lead chloride solution into the container.
8. A method according to claim 6 further comprising maintaining the lead at a first elevated temperature while adding the Sn precursor solution and the Te solution, and wherein maintaining the mixed solution at an elevated temperature for a period of time prior to cooling comprises maintaining the mixed solution at a second elevated temperature, less than the first elevated temperature, for the period of time after adding the Sn precursor solution and the Te solution.
9. A method according to claim 6 wherein maintaining the mixed solution at an elevated temperature comprises maintaining the mixed solution at 120° C. or more for the period of time after adding the Sn precursor solution and the Te solution.
10. A method according to claim 6 wherein maintaining the mixed solution at an elevated temperature comprises maintaining the mixed solution at the elevated temperature for at least 90 seconds prior to cooling to the ambient temperature to form the Pb x Sn 1-x Te nanomaterial.