IP Library Patent Application 15631779
Patent Application
App. No. 15/631,779

LITHIUM ION BATTERY MATERIALS

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Quick Facts
Patent No.
US None
App. No.
15/631,779
Abstract

The present disclosure relates to methodologies, systems and apparatus for generating lithium ion battery materials. Starting materials are combined to form a homogeneous precursor solution including lithium, and a droplet maker is used to generate droplets of the precursor solution having controlled size. These droplets are introduced into a microwave generated plasma, where micron or sub-micron scale lithium-containing particles are formed. These lithium-containing particles are collected and formed into a slurry to form lithium ion battery materials.

Claims (51)

1 . A method for generating lithium ion battery materials comprising:

combining starting materials to form a homogeneous precursor solution including lithium;

generating droplets with controlled size of the homogeneous precursor solution using a droplet maker;

introducing the droplets of the homogeneous precursor solution into a microwave generated plasma;

producing micron or sub-micron scale lithium-containing particles from the microwave generated plasma;

collecting the lithium-containing particles; and

forming a slurry with the lithium-containing particles to form lithium ion battery materials.

2 . The method of claim 1 , wherein collecting the lithium-containing particles includes quenching the lithium-containing particles, the method further comprising:

controlling a quenching rate of the lithium-containing particles by selecting a quenching fluid, controlling a quenching fluid flow speed, or controlling a quenching fluid temperature.

3 . The method of claim 1 , further comprising:

controlling a size of the droplets of the homogeneous precursor solution using the droplet maker.

4 . The method of claim 1 , further comprising:

controlling a residence time of the droplets of the homogeneous precursor solution within the microwave generated plasma by controlling at least one of: a plasma gas flow velocity, a power density of the microwave generated plasma, or a velocity of the droplets exiting the droplet maker.

5 . The method of claim 1 , wherein the homogeneous precursor solution includes an aqueous solution of hydrated or non-hydrated forms of lithium acetate, nickel acetate, manganese acetate, and cobalt acetate.

6 . The method of claim 1 , wherein the homogeneous precursor solution includes an aqueous solution of lithium nitrate, nickel nitrate, manganese nitrate, and cobalt nitrate.

7 . The method of claim 1 , wherein generating droplets with controlled size includes generating two or more streams of droplets having different diameters.

8 . The method of claim 1 , where the microwave generated plasma is generated in oxygen gas or an oxygen-containing gas.

9 . A method of tailoring lithium ion battery materials comprising:

combining starting materials to form a homogeneous precursor solution including lithium;

generating droplets with controlled size of the homogeneous precursor solution using a droplet maker;

introducing the droplets of the homogeneous precursor solution into a microwave generated plasma;

producing micron or sub-micron scale lithium-containing particles from the microwave generated plasma;

quenching the lithium-containing particles; and

tailoring at least one of: porosity, morphology, particle size, particle size distribution, or chemical composition of the lithium-containing particles by controlling at least one of: precursor solution chemistry, droplet size, plasma gas flow rates, residence time of the droplets within the microwave generated plasma, quenching rate, or power density of the microwave generated plasma.

10 . The method of claim 9 , wherein tailoring the morphology of the lithium-containing particles includes controlling the residence time of the droplets within the microwave generated plasma and an afterglow region of the microwave generated plasma.

11 . The method of claim 9 , wherein controlling the porosity of the lithium ion particles includes controlling at least one of: amounts of nitrate materials and acetate materials within the homogeneous precursor solution, solution precursor chemistry, or the residence time of the droplets within the microwave generated plasma.

12 . The method of claim 9 , wherein controlling the chemical composition of the lithium-containing particles includes controlling proportions of the starting materials within the precursor solution.

13 . The method of claim 9 , wherein controlling the particle size of the lithium ion particles includes at least one of: controlling the droplet size of the droplets of the precursor solution, or controlling a concentration of starting materials within the precursor solution.

14 . The method of claim 9 , wherein generating droplets with controlled size includes generating two or more streams of droplets having different diameters.

15 . The method of claim 14 , wherein the two or more streams of droplets are generated using different nozzles or openings in the droplet maker.

16 . The method of claim 9 , wherein tailoring the chemical composition of the lithium ion particles includes:

determining a desired chemical composition of the lithium ion particles prior to forming the homogeneous precursor solution; and

calculating stoichiometric proportions of the starting materials based on the desired chemical composition of the lithium ion particles.

17 . A method for preparing lithium-containing particles represented by the formula:

LiNi x Mn y Co z O 2

wherein x≧0, y≧0, z≧0, and x+y+z=1; the method comprising:

dissolving a combination of lithium salt, nickel salt, manganese salt, and cobalt salt in a solvent to form a homogeneous precursor solution;

generating droplets with controlled size of the homogeneous precursor solution using a droplet maker;

introducing the droplets into a microwave generated plasma;

producing micron or sub-micron scale particles of LiNi x Mn y Co z O 2 from the microwave generated plasma; and

collecting the particles of LiNi x Mn y Co z O 2 .

18 . The method of claim 17 , wherein generating droplets with controlled size includes generating two or more streams of droplets having different diameters in order to generate a multi-modal particle size distribution among the particles of LiNi x Mn y Co z O 2 .

19 . A method for preparing lithium-containing particles represented by the formula:

LiNi x Co y Al z O 2

wherein x=˜0.8, y=˜0.15, z=˜0.05; the method comprising:

dissolving a combination of lithium salt, nickel salt, cobalt salt, and aluminum salt in a solvent to form a homogeneous precursor solution;

generating uniformly sized droplets of the homogeneous precursor solution using a droplet maker;

introducing the uniformly sized droplets into a microwave generated plasma;

producing micron or sub-micron scale particles of LiNi x Co y Al z O 2 from the microwave generated plasma; and

collecting the particles of LiNi x Co y Al z O 2 .

20 . The method of claim 19 , wherein generating droplets with controlled size includes generating two or more streams of droplets having different diameters in order to generate a multi-modal particle size distribution among the particles of LiNi x Co y Al z O 2 .

Assignments (3)
CHANGE OF NAME Recorded Jun 18, 2020
From: AMASTAN TECHNOLOGIES INC.
To: 6K INC.
Reel/Frame 052984/0771 →
CHANGE OF NAME Recorded Dec 13, 2017
From: AMASTAN TECHNOLOGIES LLC
To: AMASTAN TECHNOLOGIES INC.
Reel/Frame 044862/0286 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 11, 2017
From: HADIDI, KAMAL; WROBEL, GREGORY
To: AMASTAN TECHNOLOGIES LLC
Reel/Frame 042968/0367 →