Protected electrode structures and methods
An electrode structure and its method of manufacture are disclosed. The disclosed electrode structures may be manufactured by depositing a first release layer on a first carrier substrate. A first protective layer may be deposited on a surface of the first release layer and a first electroactive material layer may then be deposited on the first protective layer. The first protective layer may have a low mean peak to valley surface roughness and/or may be thin. In some embodiments, an interface between the first protective layer and the first electroactive material layer has a low mean peak to valley surface roughness.
1. An electrode structure comprising:
a first release layer, wherein the first release layer is formed of a material that can be dissolved in an electrolyte solvent to be used with the electrode structure;
a substantially continuous protective layer disposed on the first release layer, wherein a mean peak to valley roughness of the substantially continuous protective layer is between about 0.1 μm and about 1 μm, and wherein a thickness of the substantially continuous protective layer is between about 0.1 μm and about 2 μm; and
a first electroactive material layer disposed on the substantially continuous protective layer, and wherein the thickness of the substantially continuous protective layer is at least two times greater than the mean peak to valley roughness of the substantially continuous protective layer.
2. The electrode structure of claim 1 , wherein the first release layer is at least one of a polymer, a gel polymer, and a wax.
3. The electrode structure of claim 1 , wherein the thickness of the substantially continuous protective layer is greater than the mean peak to valley roughness of the substantially continuous protective layer.
4. The electrode structure of claim 1 , wherein the first release layer comprises a material that is substantially amorphous.
5. The electrode structure of claim 1 , wherein an adhesive strength between the first release layer and the substantially continuous protective layer is greater than an adhesive strength between the first release layer and a first carrier substrate on which the first release layer is disposed.
6. The electrode structure of claim 5 , further comprising a second carrier substrate disposed on a second release layer, wherein the second release layer is disposed on a second protective layer, and wherein the second protective layer is disposed on a second electroactive material layer.
7. The electrode structure of claim 6 , wherein a current collector is disposed between the first electroactive material layer and the second electroactive material layer.
8. The electrode structure of claim 6 , wherein an intermediate layer is disposed between at least one of the first carrier substrate and the first release layer, the first release layer and the substantially continuous protective layer, and the first protective layer and the first electroactive material layer.
9. The electrode structure of claim 1 , wherein the first release layer is conductive to lithium ions.
10. The electrode structure of claim 1 , wherein the first release layer comprises a lithium salt.
11. The electrode structure of claim 1 , wherein the first electroactive material layer comprises lithium metal.
12. The electrode structure of claim 5 , wherein a mean peak to valley roughness of an interface between the first release layer and the substantially continuous protective layer is less than a mean peak to valley roughness of the first carrier substrate.
13. The electrode structure of claim 1 , wherein the first electroactive material layer comprises an alkali metal.
14. The electrode structure of claim 5 , wherein the first electroactive material layer comprises lithium metal, wherein the first release layer is at least one of a polymer, a gel polymer, and a wax, wherein an adhesive strength between the first release layer and the substantially continuous protective layer is greater than an adhesive strength between the first release layer and the first carrier substrate, wherein the thickness of the substantially continuous protective layer is at least two times greater than the mean peak to valley roughness of the substantially continuous protective layer, and wherein a thickness of the first protective layer has a thickness of between about 0.1 μm and about 2 μm.
15. An electrode structure comprising:
a first release layer, wherein the first release layer is formed of a material that can be dissolved in an electrolyte solvent to be used with the electrode structure;
a first protective layer disposed on the first release layer; and
a first electroactive material layer disposed on the first protective layer, wherein a mean peak to valley roughness of an interface between the first protective layer and the first electroactive material layer is between about 0.1 μm and about 1 μm, wherein a thickness of the first protective layer is between about 0.1 μm and about 2 μm, wherein the first protective layer is substantially continuous, and wherein the thickness of the substantially continuous protective layer is at least two times greater than the mean peak to valley roughness of the substantially continuous protective layer.