IP Library › Granted Patent US 10,442,942
Granted Patent B2
US 10,442,942 · App. 15/635,641 · Granted Oct 15, 2019

Radiation-curable ink jet composition and ink jet printing method

Inventors: Keitaro Nakano (Matsumoto, JP); Toshiyuki Yoda (Matsumoto, JP)
Assignee: Seiko Epson Corporation
C09D11/101B41J2/01B41J11/002C09D11/30C09D11/322C09D11/324
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Quick Facts
Patent No.
US 10,442,942
App. No.
15/635,641
Granted
Oct 15, 2019
Kind
B2
Abstract

A radiation-curable ink jet composition contains at least one monomer A represented by general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 , wherein R 1 represents a hydrogen atom or a methyl group, R 2 represents a divalent organic moiety having a carbon number of 2 to 20, and R 3 represents a hydrogen atom or a monovalent organic moiety having a carbon number of 1 to 11. The composition also contains a cyclic, linear, or branched monomer B containing a (meth)acryloyloxy or (meth)acryloyl group in which the total number of nitrogen atoms and oxygen atoms other than the oxygen atoms contained in the (meth)acryloyloxy or (meth)acryloyl group is at least 2, and at least one monomer C represented by the following general formula (II): wherein n represents an integer of 2 to 6. The total content of monomer A is 10% by mass or more relative to the total mass of the ink jet composition.

Claims (31)

1. A non-aqueous radiation-curable ink jet composition, comprising:

at least one monomer A represented by the following general formula (I): CH 2 ═CR 1 —COOR 2 —O—CH═CH—R 3 , wherein R 1 represents a hydrogen atom or a methyl group, R 2 represents a divalent organic moiety having a carbon number of 2 to 20, and R 3 represents a hydrogen atom or a monovalent organic moiety having a carbon number of 1 to 11;

a monomer B having one of a cyclic, a linear, and a branched structure and containing a (meth)acryloyloxy or (meth)acryloyl group and nitrogen, wherein the total number of nitrogen atoms and oxygen atoms other than the oxygen atoms contained in the (meth)acryloyloxy or (meth)acryloyl group is at least 2;

at least one monomer C represented by the following general formula (II):

wherein n represents an integer in the range of 2 to 6; and

a photopolymerization initiator,

wherein the monomer A, the monomer B, and the monomer C constitute a medium of the ink jet composition in which the photopolymerization initiator is dissolved or dispersed;

the total content of monomer A is 10% by mass or more relative to the total mass of the ink jet composition; and

the monomer B is at least one selected from the group consisting of hydroxyethyl methacrylamide and dimethylaminopropyl acrylamide (DMAPAA).

2. The radiation-curable ink jet composition according to claim 1 , wherein the total content of monomer C is 23% by mass or less relative to the total mass of the ink jet composition.

3. The radiation-curable ink jet composition according to claim 1 , wherein the total content of monomer A is 25% by mass or less relative to the total mass of the ink jet composition.

4. The radiation-curable ink jet composition according to claim 1 , wherein the total content of monomer C is 5% by mass or more relative to the total mass of the ink jet composition.

5. The radiation-curable ink jet composition according to claim 1 , wherein the total content of monomer C is in the range of 10% by mass to 25% by mass relative to the total mass of the ink jet composition.

6. An ink jet printing method comprising:

applying the radiation-curable ink jet composition as set forth in claim 1 onto a printing medium; and

irradiating the radiation-curable ink jet composition with light from an ultraviolet light emitting diode.

7. An ink jet printing method comprising:

applying the radiation-curable ink jet composition as set forth in claim 2 onto a printing medium; and

irradiating the radiation-curable ink jet composition with light from an ultraviolet light emitting diode.

8. An ink jet printing method comprising:

applying the radiation-curable ink jet composition as set forth in claim 3 onto a printing medium; and

irradiating the radiation-curable ink jet composition with light from an ultraviolet light emitting diode.

9. An ink jet printing method comprising:

applying the radiation-curable ink jet composition as set forth in claim 4 onto a printing medium; and

irradiating the radiation-curable ink jet composition with light from an ultraviolet light emitting diode.

10. An ink jet printing method comprising:

applying the radiation-curable ink jet composition as set forth in claim 5 onto a printing medium; and

irradiating the radiation-curable ink jet composition with light from an ultraviolet light emitting diode.

11. The ink jet printing method according to claim 6 , wherein the irradiation energy of the ultraviolet light emitting diode is 50 mJ/cm 2 to 1000 mJ/cm 2 .

12. The ink jet printing method according to claim 6 , wherein the irradiation intensity of the ultraviolet light emitting diode is 10 mW/cm 2 to 1000 mW/cm 2 .

13. The ink jet printing method according to claim 6 , wherein the printing medium onto which the ink jet composition is applied has a temperature of less than 45° C.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 28, 2017
From: NAKANO, KEITARO; YODA, TOSHIYUKI
To: SEIKO EPSON CORPORATION
Reel/Frame 042846/0128 →
Priority Claims (2)
JP 2016-128884 · Jun 29, 2016 · national
JP 2017-075087 · Apr 5, 2017 · national
Continuity (1)
Related Publication 20180002552A1 · Jan 4, 2018