IP Library Granted Patent US 10,803,898
Granted Patent B2
US 10,803,898 · App. 15/664,013 · Granted Oct 13, 2020

Fluorine-containing ether compound, lubricant for magnetic recording medium, and magnetic recording medium

Inventors: Naoya Fukumoto (Tokyo, JP); Daisuke Yagyu (Tokyo, JP); Yuta Yamaguchi (Tokyo, JP); Shoko Uetake (Tokyo, JP); Tsuyoshi Kato (Tokyo, JP); Hiroyuki Tomita (Tokyo, JP); Ryuta Miyasaka (Tokyo, JP); Katsumi Murofushi (Tokyo, JP)
Assignee: SHOWA DENKO K.K.
G11B5/725C07C43/11C07C43/137C07D303/18C07D303/28C08G65/007C08G65/2639C10M105/54C10M147/04C10M2211/0425C10M2213/023C10N2020/04C10N2040/18C10N2050/025
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Quick Facts
Patent No.
US 10,803,898
App. No.
15/664,013
Granted
Oct 13, 2020
Kind
B2
Abstract

A fluorine-containing ether compound of the present invention is represented by Formula (1). R 1 —CH 2 —R 2 —CH 2 —R 3   (1) (In Formula (1), R 1 is an organic end group having 3 or more carbon atoms which includes two or more polar groups with each polar group being bonded to different carbon atoms and the carbon atoms to which the polar groups are bonded being bonded to each other via a linking group including the carbon atoms which are not bonded to the polar groups, R 2 includes a perfluoropolyether chain represented by Formula (3), and R 3 is a hydroxyl group or R 1 ) —(CF 2 ) y−1 —O—((CF 2 ) y O) z —(CF 2 ) y−1 —  (3) (In Formula (3), y represents an integer of 2 to 4, and z represents an integer of 1 to 30).

Claims (57)

1. A fluorine-containing ether compound represented by Formula (1),

R 1 —CH 2 —R 2 —CH 2 —R 3   (1)

(In Formula (1), R 1 is an organic end group having 3 or more carbon atoms which includes two or more polar groups with each polar group being bonded to different carbon atoms and the carbon atoms to which the polar groups are bonded being bonded to each other via a linking group including the carbon atoms which are not bonded to the polar groups, R 2 includes a perfluoropolyether chain represented by Formula (3), and R 3 is a hydroxyl group or R 1 )

—(CF 2 ) y−1 —O—((CF 2 ) y O) z —(CF 2 ) y−1 —  (3)

(In Formula (3), y represents an integer of 3 to 4, and z represents an integer of 1 to 30).

2. A fluorine-containing ether compound represented by Formula (2),

R 1 —CH 2 —R 2 —CH 2 —R 1   (2)

(In Formula (2), R 1 is an organic end group having 3 or more carbon atoms which includes two or more polar groups with each polar group being bonded to different carbon atoms and the carbon atoms to which the polar groups are bonded being bonded to each other via a linking group including the carbon atoms which are not bonded to the polar groups, and R 2 includes a perfluoropolyether chain represented by Formula (3),)

—(CF 2 ) y−1 —O—((CF 2 ) y O) z —(CF 2 ) y−1 —  (3)

(In Formula (3), y represents an integer of 3 to 4, and z represents an integer of 1 to 30).

3. The fluorine-containing ether compound according to claim 1 ,

wherein each of the two or more polar groups included in R 1 is a hydroxyl group.

4. The fluorine-containing ether compound according to claim 1 ,

wherein R 1 has an ether bond (—O—).

5. The fluorine-containing ether compound according to claim 1 ,

wherein R 1 is an end group of Formula (4),

(In Formula (4), x represents an integer of 1 to 3).

6. The fluorine-containing ether compound according to claim 1 ,

wherein the compound in Formula (1) is represented by Formula (5),

(In Formula (5), m represents an integer of 1 to 11).

7. The fluorine-containing ether compound according to claim 1 ,

wherein the compound in Formula (1) is represented by Formula (6),

(In Formula (6), n represents an integer of 1 to 7).

8. The fluorine-containing ether compound according to claim 1 ,

wherein the compound in Formula (1) is represented by Formula (7),

(In Formula (7), n represents an integer of 1 to 7).

9. The fluorine-containing ether compound according to claim 2 ,

wherein the compound in Formula (2) is represented by Formula (8),

(In Formula (8), m represents an integer of 1 to 11).

10. The fluorine-containing ether compound according to claim 2 ,

wherein the compound in Formula (2) is represented by Formula (9),

(In Formula (9), n represents an integer of 1 to 7).

11. The fluorine-containing ether compound according to claim 2 ,

wherein the compound in Formula (2) is represented by Formula (10),

(In Formula (10), n represents an integer of 1 to 7).

12. The fluorine-containing ether compound according to claim 1 ,

wherein a number-average molecular weight is in a range of 800 to 10,000.

13. A lubricant for a magnetic recording medium, comprising:

the fluorine-containing ether compound according to claim 1 .

14. A magnetic recording medium, comprising:

at least a magnetic layer;

a protective layer; and

a lubricating layer, which are sequentially provided on a substrate,

wherein the lubricating layer includes the fluorine-containing ether compound according to claim 1 .

15. A fluorine-containing ether compound represented by Formula (1),

R 1 —CH 2 —R 2 —CH 2 —R 3   (1)

(In Formula (1), R 1 is an end group of Formula (4), R 2 includes a perfluoropolyether chain represented by Formula (3), and R 3 is a hydroxyl group or R 1 )

—(CF 2 ) y−1 —O—((CF 2 ) y O) z —(CF 2 ) y−1 —  (3);

(In Formula (3), y represents an integer of 2 to 4, and z represents an integer of 1 to 30),

(In Formula (4), x represents an integer of 2 to 3).

16. A lubricant for a magnetic recording medium, comprising:

the fluorine-containing ether compound according to claim 15 .

17. A magnetic recording medium, comprising:

at least a magnetic layer;

a protective layer; and

a lubricating layer, which are sequentially provided on a substrate,

wherein the lubricating layer includes the fluorine-containing ether compound according to claim 15 .

Assignments (3)
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Jun 23, 2023
From: SHOWA DENKO K.K.
To: RESONAC CORPORATION
Reel/Frame 064082/0513 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 31, 2017
From: FUKUMOTO, NAOYA; YAGYU, DAISUKE; YAMAGUCHI, YUTA; UETAKA, SHOKO; KATO, TSUYOSHI; TOMITA, HIROYUKI; MIYASAKA, RYUTA; MUROFUSHI, KATSUMI
To: SHOWA DENKO K.K.
Reel/Frame 043143/0495 →