IP Library › Granted Patent US 10,570,332
Granted Patent B2
US 10,570,332 · App. 15/680,907 · Granted Feb 25, 2020

Y-grade NGL fluids for enhanced oil recovery

Inventors: John A. Babcock (Houston, TX); Charles P. Siess, III (Conroe, TX); Kevin G. Watts (Spring, TX)
Assignee: Linde Aktiengesellschaft
C09K8/594C09K8/34C09K8/584C09K8/588C10L3/06E21B43/162E21B43/166
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Quick Facts
Patent No.
US 10,570,332
App. No.
15/680,907
Granted
Feb 25, 2020
Kind
B2
Abstract

Systems and methods for enhanced or improved oil recovery includes injecting a Y-Grade NGL enhanced oil recovery fluid through an injection well into a hydrocarbon bearing reservoir to mobilize and displace hydrocarbons. The Y-Grade NGL enhanced oil recovery fluid comprises an unfractionated hydrocarbon mixture. Simultaneously and/or subsequently, a mobility control fluid is injected into the hydrocarbon bearing formation. Hydrocarbons from the hydrocarbon bearing reservoir are produced through a production well or the same injection well.

Claims (27)

1. A method for enhanced or improved oil recovery, comprising:

injecting a Y-Grade NGL enhanced oil recovery fluid through an injection well into a hydrocarbon bearing reservoir to mobilize and displace hydrocarbons, wherein the Y-Grade NGL enhanced oil recovery fluid comprises an unfractionated hydrocarbon mixture that is a byproduct of a condensed and de-methanized hydrocarbon stream that is miscible with hydrocarbons in the hydrocarbon bearing reservoir, wherein the unfractionated hydrocarbon mixture comprises ethane, propane, and butane in an amount of at least 75% by volume, and wherein the unfractionated hydrocarbon mixture comprises pentane plus in an amount less than 30% by volume, wherein the unfractionated hydrocarbon mixture is condensed out of the hydrocarbon stream at a temperature at or below 0 degrees Fahrenheit;

injecting a mobility control fluid through the injection well into the hydrocarbon bearing formation to inhibit mobility of the Y-Grade NGL enhanced oil recovery fluid from the injection well to a production well; and

producing hydrocarbons through the production well.

2. The method of claim 1 , wherein the injection well comprises an array of vertical or horizontal injection wells, and wherein the production well comprises an array of vertical or horizontal production wells offset from the array of injection wells.

3. The method of claim 1 , further comprising alternating injections of the Y-Grade NGL enhanced oil recovery fluid with injections of the mobility control fluid into the hydrocarbon bearing reservoir.

4. The method of claim 1 , wherein the mobility control fluid comprises at least one of carbon dioxide, nitrogen, natural gas, methane, LNG, ethane, water, and viscosified water.

5. The method of claim 1 , further comprising injecting a final displacement fluid into the hydrocarbon bearing reservoir at the conclusion of the injection of the Y-Grade NGL enhanced oil recovery fluid, wherein the final displacement fluid comprises at least one of carbon dioxide, nitrogen, natural gas, methane, LNG, ethane, water, and viscosified water.

6. The method of claim 1 , wherein the hydrocarbon bearing reservoir is a carbonate reservoir, a clastic reservoir, or a residual oil zone (ROZ).

7. The method of claim 1 , further comprising mixing the Y-Grade NGL enhanced oil recovery fluid, the mobility control fluid, and a surfactant to form a hydrocarbon foam, wherein the mobility control fluid is a gas comprising at least one of carbon dioxide, nitrogen, natural gas, methane, and ethane.

8. The method of claim 7 , wherein the surfactant is at least one of a nonionic surfactant and anionic surfactant, wherein the surfactant comprises a mass concentration of up to 5%.

9. The method of claim 8 , wherein the nonionic surfactant comprises at least one of a siloxane surfactant, a fluorosurfactant, a fatty acid ester, a glyceride, and a silicon emulsifier.

10. The method of claim 7 , further comprising adding a foam stabilizer to the hydrocarbon foam, wherein the foam stabilizer comprises a hydrocarbon soluble copolymer.

11. The method of claim 7 , further comprising adding a secondary fluid to the hydrocarbon foam, wherein the secondary fluid comprises at least one of aromatics, alcohols, alkanes, and crude oil, and wherein the secondary fluid comprises 10% or less by volume of the hydrocarbon foam.

12. The method of claim 11 , wherein the crude oil comprises at least one of residual oil in the hydrocarbon bearing reservoir, heavy oil, medium oil, light oil, condensate, and residual oil in the ROZ.

13. The method of claim 7 , further comprising adding nanoparticles to the hydrocarbon foam.

14. The method of claim 1 , further comprising mixing the Y-Grade NGL enhanced oil recovery fluid, the mobility control fluid, a surfactant, and water to form an emulsion based foam, wherein the mobility control fluid is a gas.

15. The method of claim 14 , wherein the surfactant acts as a foaming agent, an emulsifying agent, or both.

16. The method of claim 14 , wherein the water is formation water and comprises up to 10% of the liquid phase of the emulsion based foam.

17. The method of claim 14 , wherein the water is potassium chloride water and comprises up to 10% of the liquid phase of the emulsion based foam, wherein the potassium chloride water comprises up to 4% potassium chloride.

18. The method of claim 14 , wherein the gas comprises at least one of nitrogen, carbon dioxide, natural gas, methane, and ethane.

19. The method of claim 14 , wherein the surfactant is at least one of a nonionic surfactant, an anionic surfactant, and a cationic surfactant, wherein the surfactant comprises a mass concentration of up to 5%.

20. The method of claim 19 , wherein the nonionic surfactant comprises at least one of a siloxane surfactant, a fluorosurfactant, a fatty acid ester, a glyceride, and a silicon emulsifier.

21. The method of claim 14 , further comprising adding a foam stabilizer to the emulsion based foam, wherein the foam stabilizer comprises at least one of a hydrocarbon soluble copolymer and a water soluble copolymer.

22. The method of claim 14 , further comprising adding a secondary fluid to the emulsion based foam, wherein the secondary fluid comprises at least one of aromatics, alcohols, alkanes, and crude oil, and wherein the secondary fluid comprises 10% or less by volume of the emulsion based foam.

23. The method of claim 22 , wherein the crude oil comprises at least one of residual oil in the hydrocarbon bearing reservoir, heavy oil, medium oil, light oil, condensate, and residual oil in the ROZ.

24. The method of claim 14 , further comprising adding nanoparticles to the emulsion based foam.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 4, 2018
From: WATTS, KEVIN G.
To: LINDE AKTIENGESELLSCHAFT
Reel/Frame 045433/0539 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 7, 2017
From: SIESS, CHARLES P., III
To: LINDE AKTIENGESELLSCHAFT
Reel/Frame 044057/0264 →
Continuity (1)
Related Publication 20180058182A1 · Mar 1, 2018