Stripline detector for in situ battery NMR
Provided are batteries and fuel cells incorporating a stripline detector for use in nuclear magnetic resonance (NMR). The stripline batteries and fuel cells can be used for in situ NMR measurement of battery or fuel cell chemistry. Also provided are methods for measuring in situ battery and fuel cell NMR using the stripline batteries and fuel cells of the invention.
1. A battery comprising a stripline detector for in situ NMR inside the battery, comprising metallic cathode and anode support plates arranged in parallel planes and situated on opposite sides of the stripline detector.
2. The battery of claim 1 , wherein the metallic cathode support plate comprises aluminum.
3. The battery of claim 1 , wherein the metallic cathode support plate further comprises a cathode material deposited on the cathode support plate.
4. The battery of claim 3 , wherein the cathode material deposited on the cathode support plate is selected from the group consisting of lithium iron phosphate (LiFePO 4 ), lithium cobalt oxide (LiCoO 2 ), and spinel cathode materials.
5. The battery of claim 1 , wherein the metallic anode support plate comprises copper.
6. The battery of claim 5 , wherein the metallic anode support plate further comprises an anode material deposited on the anode support plate.
7. The battery of claim 6 , wherein the anode material deposited on the anode support plate is graphite.
8. The battery of claim 1 , further comprising a first nonconductive separator situated between the stripline detector and the metallic cathode support plate, and a second nonconductive separator situated between the stripline detector and the metallic anode support plate, wherein the first nonconductive separator electrically isolates the stripline detector from the cathode, and the second nonconductive separator electrically isolates the stripline detector from the anode.
9. The battery of claim 8 , wherein the first nonconductive separator and the second nonconductive separator independently comprise a material selected from the group consisting of polyethylene, polypropylene, and polytetrafluoroethylene (PTFE).
10. The battery of claim 8 , wherein the first nonconductive separator and the second nonconductive separator are comprised of the same material.
11. The battery of claim 8 , wherein the first nonconductive separator and the second nonconductive separator are a single nonconductive separator.
12. A method for measuring in situ battery nuclear magnetic resonance (NMR), comprising
providing the battery of claim 1 ;
connecting the stripline detector to an NMR circuit;
isolating electrode leads of the battery from alternating current NMR circuitry; and
cycling the battery while acquiring NMR data from the battery.