Method for removing contaminants from cannabinoid distillates
View Patent ↗A method for removing contaminants such as pesticides and fungicides from cannabinoid extracts. Cannabinoid extracts containing contaminants may be dissolved in a water and ethanol solution, and then cooled to allow water-soluble contaminants to settle out of the mixture. The water and ethanol may then be removed via evaporation or distillation, leaving purified cannabinoids without contaminants. Contaminant removal may be incorporated into a method for producing a blended extract of cannabinoids and terpenes, which extracts terpenes using supercritical CO2, and extracts a cannabinoid concentrate from the residual material using a cold ethanol flush followed by distillation and then by contaminant removal; the CO2-extracted terpenes are then added back to the purified cannabinoid concentrate in a final blending step. Blending terpenes at the end of extraction may enhance the flavor and effectiveness of the purified cannabinoid concentrate.
1. A method for removing contaminants from cannabinoid distillates to yield purified cannabinoid distillates consisting essentially of:
obtaining cannabinoid distillates additionally consisting essentially of one or more contaminants;
mixing said cannabinoid distillates additionally consisting essentially of said one or more contaminants with ethanol and distilled water to yield a cannabinoid-ethanol-water solution;
allowing said one or more contaminants to settle out of said cannabinoid-ethanol-water solution;
separating said cannabinoid-ethanol-water solution into a purified cannabinoid-ethanol-water solution and residual contaminants separately;
distilling said ethanol and said distilled water from said purified cannabinoid-ethanol-water solution to yield purified cannabinoid distillates;
wherein the mixing of said cannabinoid distillates with said ethanol and said distilled water to yield said cannabinoid-ethanol-water solution consists essentially of
adding said ethanol to said cannabinoid distillates at a ratio between 2:1 and 4:1 of ethanol by volume in mL to cannabinoid distillates by mass in grams, to yield a cannabinoid-ethanol solution;
heating said cannabinoid-ethanol solution to a temperature between 40° C. and 80° C. to yield a dissolved cannabinoid-ethanol solution;
adding said distilled water to said dissolved cannabinoid-ethanol solution at a ratio between 1:4 and 1:10 of said distilled water by volume in mL to said cannabinoid distillates by mass in grams, to yield said cannabinoid-ethanol-water solution; and,
heating said cannabinoid-ethanol-water solution to a temperature between 40° C. and 60° C.; and,
wherein the allowing said one or more contaminants to settle out of said cannabinoid-ethanol-water solution consists essentially of
cooling said cannabinoid-ethanol-water solution to a temperature between −30° C. and 10° C., yielding a cooled cannabinoid-ethanol-water solution; and,
allowing said contaminants to settle out of said cooled cannabinoid-ethanol-water solution for a period of time between 2 hours and 7 days.
2. The method of claim 1 , wherein said one or more contaminants are water-soluble.
3. The method of claim 1 , wherein said one or more contaminants consists essentially of one or more of pesticides and fungicides.
4. The method of claim 1 , wherein said one or more contaminants consists essentially of one or more of Abamectin, Acephate, Acetamiprid, Aldicarb, Azoxystrobin, Bifenazate, Boscalid, Carbaryl, Carbofuran, Chlorpyrifos, Daminozide, Dichlorvos, Dimethoate, Ethoprophos, Fenarimol, Fenchlorphos, Fenhexamid, Fenoxycarb, Fipronil, Flonicamid, Fludioxonil, Fonofos, Imazalil, Imidacloprid, Iprodione, Kresoxim-methyl, Malathion, Metalaxyl, Methiocarb, Methomyl, MGK-264, Myclobutanil, Naled, Oxamyl, Paclobutrazol, Parathion, Phosmet, Piperonyl butoxide, Pirimiphos, Prallethrin, Promecarb, Propiconazole, Propoxur, Pyraclostrobin, Spinetoram, Spirotetramat, Spiroxamine, Tebuconazole, Thiacloprid, and Thiamethoxam.
5. The method of claim 1 , wherein said separating said cannabinoid-ethanol-water solution into said purified cannabinoid-ethanol-water solution and said residual contaminants separately consists essentially of one or more of
pouring said purified cannabinoid-ethanol-water solution off of said cannabinoid-ethanol-water solution;
siphoning said purified cannabinoid-ethanol-water solution off of said cannabinoid-ethanol-water solution; and,
filtering said residual contaminants out of said cannabinoid-ethanol-water solution to yield said purified cannabinoid-ethanol-water solution.
6. The method of claim 1 , wherein said removing said ethanol and said water from said purified cannabinoid-ethanol-water solution to yield said purified cannabinoid distillates consists essentially of one or more of
heating said purified cannabinoid-ethanol-water solution to cause said ethanol and said water to evaporate, leaving said purified cannabinoid distillates; and,
distilling said purified cannabinoid-ethanol-water solution to recover said purified cannabinoid distillates.