IP Library Granted Patent US 11,285,704
Granted Patent B2
US 11,285,704 · App. 15/698,473 · Granted Mar 29, 2022

Ultrathin graphene/polymer laminate films

Inventors: Michael Stadermann (Pleasanton, CA); Patrick Campbell (Oakland, CA); Philip E. Miller (Livermore, CA); Chantel Aracne-Ruddle (Livermore, CA); Sung Ho Kim (Livermore, CA); Francisco J. Espinosa-Loza (Bellevue, WA)
Assignee: Lawrence Livermore National Security, LLC.
B32B27/06B29D99/005B32B9/007B32B18/00B32B37/14C01B32/184C01B32/194B32B2309/105Y10T428/30
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Quick Facts
Patent No.
US 11,285,704
App. No.
15/698,473
Granted
Mar 29, 2022
Kind
B2
Abstract

According to one embodiment, a product includes a composite film comprising a polymer layer directly adjacent a graphene layer. According to another embodiment, a process includes layering a graphene layer onto a polymer layer to form a composite film.

Claims (31)

1. A product comprising:

a composite film comprising a polymer layer directly adjacent a graphene layer,

wherein the graphene layer includes islands of graphene that are held together by van der Waals forces,

wherein a weight fraction of graphene in the composite film is greater than 10% relative to the total weight of the polymer layer and the graphene layer.

2. The product of claim 1 , wherein the polymer layer has a thickness of less than about 100 nm.

3. The product of claim 1 , wherein the graphene layer includes several layers of graphene.

4. The product of claim 1 , wherein the composite film includes a second graphene layer directly adjacent a second side of the polymer layer.

5. The product of claim 1 , wherein the composite film includes a second graphene layer directly adjacent the graphene layer.

6. The product of claim 1 , wherein the composite film includes a second polymer layer directly adjacent a second side of the graphene layer.

7. The product of claim 1 , wherein the composite film has a stiffness that is at least five times a stiffness of the polymer layer.

8. A method, comprising using the product of claim 1 as a separation medium for separating a component from a liquid.

9. A process of forming the product of claim 1 , the process comprising:

layering the graphene layer onto the polymer layer to form the composite film.

10. The process of claim 9 , wherein the layering is performed in a solution.

11. The product of claim 1 , wherein the weight fraction of graphene in the composite film is greater than 10%.

12. The product of claim 1 , wherein the composite film has a stiffness that is at least five times a stiffness of the polymer layer, wherein the composite film has a yield strength that is greater than three times a yield strength of the polymer layer.

13. The product of claim 1 , wherein the composite film has a yield strength that is greater than two times a yield strength of the polymer layer.

14. A product comprising:

a composite film comprising a polymer layer directly adjacent a graphene layer,

wherein the graphene layer includes islands of graphene that are held together by van der Waals forces,

wherein the composite film has a stiffness greater than three times a stiffness of the polymer layer,

wherein a weight fraction of graphene is greater than 10% relative to the total weight of the polymer layer and graphene layer.

15. The product of claim 14 , wherein the composite film includes a second graphene layer directly adjacent a second side of the polymer layer.

16. The product of claim 14 , wherein the composite film has a stiffness that is at least five times a stiffness of the polymer layer.

17. The product of claim 14 , wherein the polymer layer has a thickness of less than about 100 nm.

18. A product comprising:

a composite film comprising a polymer layer directly adjacent a graphene layer,

wherein the composite film has a yield strength that is at least three times a yield strength of the polymer layer,

wherein a weight fraction of graphene is greater than 10% relative to the total weight of the polymer layer and the graphene layer.

19. The product of claim 18 , wherein the composite film has a stiffness that is at least five times a stiffness of the polymer layer.

20. The product of claim 18 , wherein the polymer layer has a thickness of less than about 100 nm.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2020
From: ESPINOSA-LOZA, FRANCISCO J.
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 052013/0810 →
CONFIRMATORY LICENSE Recorded Aug 22, 2019
From: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
To: U.S. DEPARTMENT OF ENERGY
Reel/Frame 050130/0203 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 11, 2017
From: STADERMANN, MICHAEL; CAMPBELL, PATRICK; MILLER, PHILIP E.; ARACNE-RUDDLE, CHANTEL; KIM, SUNG HO
To: LAWRENCE LIVERMORE NATIONAL SECURITY, LLC
Reel/Frame 043549/0257 →
Continuity (1)
Related Publication 20190070832A1 · Mar 7, 2019