IP Library Granted Patent US 10,787,574
Granted Patent B2
US 10,787,574 · App. 15/699,732 · Granted Sep 29, 2020

Polymer derived ceramic effects particles, uses and methods of making

Inventors: Andrew R. Hopkins (Sylvania, OH); Mark S. Land (Houston, TX); Michael J. Mueller (Katy, TX); Michael Molnar (Summerfield, NC); Charles C. Rinzler (San Francisco, CA); Douglas Dukes (Troy, NY); Wen P. Liao (Clifton Park, NY)
Assignee: Melior Innovations, Inc.
C09C1/0021C04B35/571C08G77/04C01P2002/02C01P2004/20C01P2004/61C01P2004/80C01P2004/84C04B2235/483C04B2235/5292C04B2235/72C04B2235/725C09C2200/10C09C2200/301C09C2200/308
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Quick Facts
Patent No.
US 10,787,574
App. No.
15/699,732
Granted
Sep 29, 2020
Kind
B2
Abstract

A polysilocarb effect pigments, uncoated and coated, that exhibit among other things optical properties such as interference, shine, shimmer and sparkle. Pastes and coating including these polysilocarb effect pigments.

Claims (18)

1. A thin ceramic effects pigment flake, the flake comprising an amorphous ceramic polysilocarb; wherein the flake defines a thickness and a surface, wherein the surface defines a longest dimension, and wherein the longest dimension is less than 500 μm.

2. The flake of claim 1 , whereby upon exposure to sunlight the flake exhibits an optical effect selected from the group consisting of reflectance, refraction, opalescence, shine, twinkle and sparkle.

3. The flake of claim 1 , whereby upon exposure to sunlight exhibits an optical effect selected from the group consisting of interference, amplification and cancellation.

4. A plurality of ceramic effect pigment thin flakes, comprising a polysilocarb based ceramic, the flakes having an average thickness of about 1.0-1.3 microns; and 80% or more of the flakes having a particle size distribution of from about 1700-150 μm and 20% or less of the flakes having a particle size distribution of <150 μm.

5. The flakes of claim 4 , whereby upon exposure to sunlight exhibit an optical effect selected from the group consisting of sparkle, metallic, pearlescence, shine, shimmer, interference, amplification and cancellation.

6. The flakes of claim 4 , wherein the ceramic polysilocarb is amorphous.

7. The flakes of claim 4 , comprising a metal oxide coating over the ceramic polysilocarb.

8. The flakes of claim 5 , wherein the ceramic polysilocarb is amorphous.

9. The flakes of claim 5 , comprising a metal oxide coating over the ceramic polysilocarb.

10. The flake of claim 1 , wherein the flake is planar.

11. The flakes of claim 4 , wherein the flakes are planar.

12. The flakes of claim 4 , wherein the flakes are corn flake shaped.

13. A plurality of ceramic effect pigment thin flakes, comprising a polysilocarb based ceramic, the flakes having an average thickness of about 0.8-1.0 μm, and a particle size distribution of about D10 6.00 μm, D50 11.0-14.50 μm, and D90 21.00-25.00 μm; and a sieve residue 45 μm less than 2.00.

14. The flakes of claim 13 , whereby upon exposure to sunlight exhibit an optical effect selected from the group consisting of sparkle, metallic, pearlescence, shine, shimmer, interference, amplification and cancellation.

15. The flakes of claim 13 , wherein the ceramic polysilocarb is amorphous.

16. The flakes of claim 13 , comprising a metal oxide coating over the ceramic polysilocarb.

17. The flakes of claim 14 , wherein the ceramic polysilocarb is amorphous.

18. The flakes of claim 13 , comprising a metal oxide coating over the ceramic polysilocarb.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 30, 2019
From: HOPKINS, ANDREW R; LAND, MARK S; MUELLER, MICHAEL J; MOLNAR, MICHAEL; RINZLER, CHARLES C; DUKES, DOUGLAS; LIAO, WEN P
To: MELIOR INNOVATIONS, INC
Reel/Frame 049325/0352 →
Continuity (12)
Continuation In Part 15002773 · Jan 21, 2016
Continuation In Part 14634814 · Feb 28, 2015
Continuation In Part 15699732
Continuation In Part 14634819 · Feb 28, 2015
Continuation In Part 15699732
Continuation In Part 14864125 · Sep 24, 2015
Provisional Application 62385821 · Sep 9, 2016
Provisional Application 62106094 · Jan 21, 2015
Provisional Application 61946598 · Feb 28, 2014
Provisional Application 62106094 · Jan 21, 2015
Provisional Application 62055397 · Sep 25, 2014
Related Publication 20180194945A1 · Jul 12, 2018