Integrated propane dehydrogenation process
Processes and systems for the integrated production of propylene and an alkylate, such as cumene, may include feeding a hydrocarbon feedstock containing propane to a propane dehydrogenation reaction zone to convert a portion of the propane to propylene. The propylene is separated in a separation system to form a polymer-grade propylene stream, a low purity propylene stream, and a propane stream. The low purity propylene stream is then fed to an alkylation reaction zone where the propylene is reacted to produce an alkylated product and generate a low pressure steam. The low pressure steam may then be fed to the separation system as a heat source, integrating the dehydrogenation system and the alkylation system.
1. A process for the production of cumene comprising:
feeding a hydrocarbon feedstock comprising propane to a propane dehydrogenation reaction zone, converting a portion of the propane to propylene, forming a dehydrogenated effluent;
separating the dehydrogenated effluent in a separation system, forming a polymer-grade propylene stream, a low purity propylene stream, and a propane stream;
feeding the low purity propylene stream to an alkylation reaction zone, wherein propylene is reacted with benzene to concurrently produce an alkylated product comprising cumene and generate a low pressure steam stream; and
feeding the low pressure steam stream to the separating step as a heat source.
2. The process of claim 1 , further comprising recycling the propane stream to the propane dehydrogenation reaction zone.
3. The process of claim 1 , further comprising separating the alkylated product into one or more of a benzene stream, a C3 stream, a cumene product stream, and a heavies effluent, wherein the C3 stream comprises one or more of propane and propylene.
4. The process of claim 3 , wherein the separating the alkylated product comprises recovering the C3 stream at a higher pressure than an operating pressure of the propane dehydrogenation reaction zone.
5. The process of claim 4 , further comprising recycling the C3 stream to the propane dehydrogenation reaction zone as a vapor.
6. The process of claim 5 , wherein the recycling is performed without pressurization or liquefaction.
7. The process of claim 1 , wherein the low pressure steam stream is at a temperature in a range of 100° C. to 120° C. and a pressure of less than or equal to 1 bar.
8. The process of claim 1 , wherein the separation system comprises a low pressure separation column and a high pressure separation column, the process further comprising feeding a first portion of the dehydrogenated effluent to the low pressure separation column and feeding a second portion of the dehydrogenated effluent to the high pressure separation column.
9. The process of claim 8 , wherein a feed ratio of the first portion of the dehydrogenated effluent and the second portion of the dehydrogenated effluent is in a range of 1:1 to 5:1.
10. The process of claim 8 , further comprising operating the low pressure separation column at a temperature in a range of 5° C. to 25° C. and a pressure in a range of 4 barg to 10 barg and operating the high pressure separation column at a temperature in a range of 25° C. to 80° C. and a pressure in a range of 12 barg to 26 barg.
11. The process of claim 8 , further comprising producing a propylene product comprising at least 98 wt % propylene from the low pressure separation column, and producing a propylene product comprising 60-95 wt % propylene from the high pressure separation column.
12. The process of claim 1 , further comprising:
concurrently generating a high pressure steam stream in the propane dehydrogenation reaction zone; and
feeding the high pressure steam stream to the alkylation reaction zone as a heat source.