Optical filter and ambient light sensor including optical filter
An optical filter including a base member having a layer containing near-infrared absorbing fine particles and a dielectric multilayer film, the optical filter satisfying a requirement that, in a wavelength range of 400 nm to 650 nm, an average of transmittance of any of light incident from a direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees, and light obliquely incident at an angle of 60 degrees is 45% or higher and lower than 85%; and a requirement that, in a wavelength range of 800 nm to 1,200 nm, an average of optical density (OD value) of any of light incident from the direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 1.7 or higher.
1. An optical filter, comprising:
a base member comprising a layer comprising near-infrared absorbing fine particles which absorb light in a wavelength of 800 nm to 1,200 nm;
a resin layer over and in contact with the base member, the resin layer comprising near-infrared absorbing fine particles; and
a first dielectric multilayer film over and in contact with the resin layer, the first dielectric multilayer film reflecting infrared rays,
wherein the near-infrared absorbing fine particles comprise a metal oxide represented by a general formula M x W y Oz, wherein M is one or a plurality of elements selected from H, alkali metals, alkaline earth metals, rare earth elements, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re, Be, Hf, Os, Bi, and I; W is tungsten; O is oxygen; 0.001≤x/y≤1; and 2.2≤z/y≤3.0,
wherein the optical filter satisfies requirements (a), (b), (c), (d), (e) and (f) below:
(a) in a wavelength range of 400 nm to 650 nm, an average of transmittance of any of light incident from a direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 45% or higher and lower than 85%;
(b) in a wavelength range of 800 nm to 1,200 nm, an average of optical density (OD value) of any of light incident from the direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 1.7 or higher;
(c) in a wavelength range of 400 nm to 650 nm, an average of transmittance of light obliquely incident at an angle of 30 degrees with respect to a direction perpendicular to the optical filter is higher than an average of transmittance of light incident from the direction perpendicular to the optical filter and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction;
(d) in a wavelength range of 430 nm to 470 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 45% or higher and lower than 85%;
(e) in a wavelength range of 520 nm to 560 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 60% or higher and lower than 88%; and
(f) in a wavelength range of 580 nm to 620 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 50% or higher and lower than 85%.
2. The optical filter according to claim 1 , wherein the near-infrared absorbing fine particles have an average particle diameter of 1 nm to 200 nm.
3. The optical filter according to claim 1 , wherein the layer comprising the near-infrared absorbing fine particles is transparent in a visible region.
4. The optical filter according to claim 3 , wherein the transparent resin substrate comprises a resin selected from the group consisting of a cyclic (poly)olefin-based resin, an aromatic polyether-based resin, a polyimide-based resin, a fluorene polycarbonate-based resin, a fluorene polyester-based resin, a polycarbonate-based resin, a polyamide-based resin, a polyarylate-based resin, a polysulfone-based resin, a polyether sulfone-based resin, a polyparaphenylene-based resin, a polyamide-imide-based resin, a polyethylene naphthalate-based resin, a fluorinated aromatic polymer-based resin, a (modified) acrylic resin, an epoxy-based resin, a curable allyl ester-based resin, an ultraviolet-curable silsesquioxane-based resin, an ultraviolet-curable acrylic resin, and an ultraviolet-curable vinyl-based resin.
5. The optical filter according to claim 1 , further comprising a second dielectric multilayer film under the base member.
6. The optical filter according to claim 1 , wherein the base member is a transparent resin substrate or a glass substrate.
7. The optical filter according to claim 6 , wherein the transparent resin substrate comprises a resin selected from the group consisting of a cyclic (poly)olefin-based resin, an aromatic polyether-based resin, a polyimide-based resin, a fluorene polycarbonate-based resin, a fluorene polyester-based resin, a polycarbonate-based resin, a polyamide-based resin, a polyarylate-based resin, a polysulfone-based resin, a polyether sulfone-based resin, a polyparaphenylene-based resin, a polyamide-imide-based resin, a polyethylene naphthalate-based resin, a fluorinated aromatic polymer-based resin, a (modified) acrylic resin, an epoxy-based resin, a curable allyl ester-based resin, an ultraviolet-curable silsesquioxane-based resin, an ultraviolet-curable acrylic resin, and an ultraviolet-curable vinyl-based resin.
8. The optical filter according to claim 1 , satisfying the requirements (a) and (c) below:
(a) in a wavelength range of 400 nm to 650 nm, an average of transmittance of any of light incident from a direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 55% or higher and lower than 75%; and
(c) in a wavelength range of 400 nm to 650 nm, an average of transmittance of light obliquely incident at an angle of 30 degrees with respect to a direction perpendicular to the optical filter is higher than an average of transmittance of light incident from the direction perpendicular to the optical filter and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction.
9. The optical filter according to claim 1 , wherein M is Cs.
10. An ambient light sensor, comprising:
a photoelectric conversion element; and
an optical filter on a light-receiving surface side of the photoelectric conversion element,
wherein the optical filter comprises: a base member comprising a layer comprising near-infrared absorbing fine particles which absorb light in a wavelength of 800 nm to 1,200 nm; a resin layer over and in contact with the base member, the resin layer comprising near-infrared absorbing fine particles; and a dielectric multilayer film over and in contact with the resin layer, the dielectric multilayer film reflecting infrared rays
wherein the near-infrared absorbing fine particles is a metal oxide represented by a general formula M x W y Oz, wherein M is one or a plurality of elements selected from H, alkali metals, alkaline earth metals, rare earth elements, Zr, Cr, Mn, Fe, Ru, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au, Zn, Cd, Al, Ga, In, Tl, Si, Ge, Sn, Pb, Sb, B, F, P, S, Se, Br, Te, Ti, Nb, V, Mo, Ta, Re, Be, Hf, Os, Bi, and I; W is tungsten; O is oxygen; 0.001≤x/y≤1; and 2.2≤z/y≤3.0,
wherein the optical filter satisfies requirements (a), (b), (c). (d), (e) and (f) below:
(a) in a wavelength range of 400 nm to 650 nm, an average of transmittance of any of light incident from a direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to a perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 45% or higher and lower than 85%;
(b) in a wavelength range of 800 nm to 1,200 nm, an average of optical density (OD value) of any of light incident from the direction perpendicular to the optical filter, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 1.7 or higher;
(c) in a wavelength range of 400 nm to 650 nm, an average of transmittance of light obliquely incident at an angle of 30 degrees with respect to a direction perpendicular to the optical filter is higher than an average of transmittance of light incident from the direction perpendicular to the optical filter and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction;
(d) in a wavelength range of 430 nm to 470 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 45% or higher and lower than 85%;
(e) in a wavelength range of 520 nm to 560 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 60% or higher and lower than 88%; and
(f) in a wavelength range of 580 nm to 620 nm, the average of transmittance of any of light incident from a direction perpendicular to the base member, light obliquely incident at an angle of 30 degrees with respect to the perpendicular direction, and light obliquely incident at an angle of 60 degrees with respect to the perpendicular direction is 50% or higher and lower than 85%.
11. An electronic device, comprising the ambient light sensor according to claim 10 .
12. The ambient light sensor according to claim 10 , wherein M is Cs.