Method for manufacturing nitride crystal substrate and nitride crystal laminate

1. A method for manufacturing a nitride crystal substrate comprising:

a first step of constituting a seed crystal substrate assembly by arranging and placing a plurality of seed crystal substrates which are made of nitride crystal and whose principal surfaces are c-planes, on a base plate so that side surfaces of the adjacent seed crystal substrates are in contact with each other; and

a second step of growing a crystal film on the seed crystal substrate assembly,

wherein in the first step, the seed crystal substrates are placed on the base plate in a state of regulating a position of the seed crystal substrates in an in-plane direction by a position regulating unit to regulate the position of the seed crystal substrates in the in-plane direction, and at least one of the seed crystal substrates is placed non-adhesively to the base plate,

wherein a fixing member is used as the position regulating unit, which is placed on the base plate so as to be in contact with an outer peripheral edge surface of the seed crystal substrate assembly, and which is adhered to a surface layer of the base plate, and

a material constituting the base plate is a material with which the adhered fixing member is separated from the base plate by peeling off the surface layer,

wherein the fixing member includes a first fixing member which is in contact with a first seed crystal substrate placed on an outer peripheral edge portion of the seed crystal substrate assembly, and a second fixing member which is in contact with a second seed crystal substrate placed on the outer peripheral edge portion of the seed crystal substrate assembly,

the first seed crystal substrate and the second seed crystal substrate are placed along an outer peripheral edge of the seed crystal substrate assembly, so that a seed crystal substrate which is not in contact with the fixing member, is interposed between the first seed crystal substrate and the second seed crystal substrate, and

movement of the seed crystal substrate which is not in contact with the fixing member toward an outer peripheral side direction of the seed crystal substrate assembly, is regulated by locking the seed crystal substrate which is not in contact with the fixing member, with the first seed crystal substrate whose movement toward the outer peripheral side direction of the seed crystal substrate assembly is regulated by the first fixing member and the second seed crystal substrate whose movement toward the outer peripheral side direction of the seed crystal substrate assembly is regulated by the second fixing member, and

wherein in the first step, the seed crystal substrate assembly is constituted of a pattern in which a configuration of tessellating regular-hexagonal seed crystal substrates in a planar appearance, is circulary cut with a center of a predetermined regular-hexagonal seed crystal substrate as a center,

the pattern is a pattern in which fan-shaped seed crystal substrates are placed at every other positions in the seed crystal substrates arranged along a circumference which is the outer peripheral edge of the seed crystal substrate assembly, and

the first seed crystal substrate and the second seed crystal substrate are constituted of the fan-shaped seed crystal substrates.

2. A method for manufacturing a nitride crystal substrate comprising:

a first step of constituting a seed crystal substrate assembly by arranging and placing a plurality of seed crystal substrates which are made of nitride crystal and whose principal surfaces are c-planes, on a base plate so that side surfaces of the adjacent seed crystal substrates are in contact with each other; and

a second step of growing a crystal film on the seed crystal substrate assembly,

wherein in the first step, the seed crystal substrates are placed on the base plate in a state of regulating a position of the seed crystal substrates in an in-plane direction by a position regulating unit to regulate the position of the seed crystal substrates in the in-plane direction, and at least one of the seed crystal substrates is placed non-adhesively to the base plate,

wherein a seed crystal substrate for fixing is used as the position regulating unit, which is the seed crystal substrate placed on an outer peripheral edge portion of the seed crystal substrate assembly and adhered to a surface layer of the base plate, and

a material constituting the base plate is a material with which the adhered seed crystal substrate for fixing is separated from the base plate by peeling off the surface layer,

wherein the seed crystal substrate for fixing includes a first seed crystal substrate for fixing and a second seed crystal substrate for fixing,

the first seed crystal substrate for fixing and the second seed crystal substrate for fixing are arranged along an outer peripheral edge of the seed crystal substrate assembly, so that a seed crystal substrate placed non-adhesively to the base plate is interposed between the first seed crystal substrate for fixing and the second seed crystal substrate for fixing, and

movement of the seed crystal substrate placed non-adhesively toward an outer peripheral side direction of the seed crystal substrate assembly, is regulated by locking the seed crystal substrate placed non-adhesively, with the first seed crystal substrate for fixing and the second seed crystal substrate for fixing, and

wherein in the first step, the seed crystal substrate assembly is constituted a pattern in which a configuration of tesselating regular-hexagonal seed crystal substrates in a planar appearance, is circulary cut with a center of a predetermined seed crystal substrate as a center,

the pattern is a pattern in which fan-shaped seed crystal substrates are placed at every other positions in the seed crystal substrates arranged along a circumference which is an outer peripheral edge of the seed crystal substrate assembly, and

the first seed crystal substrate for fixing and the second seed crystal substrate for fixing are constituted of the fan-shaped seed crystal substrates.

3. A method for manufacturing a nitride crystal substrate comprising:

a first step of constituting a seed crystal substrate assembly by arranging and placing a plurality of seed crystal substrates which are made of nitride crystal and whose principal surfaces are c-planes, on a base plate so that side surfaces of the adjacent seed crystal substrates are in contact with each other; and

a second step of growing a crystal film on the seed crystal substrate assembly,

wherein in the first step, the seed crystal substrates are placed on the base plate in a state of regulating a position of the seed crystal substrates in an in-plane direction by a position regulating unit to regulate the position of the seed crystal substrates in the in-plane direction, and at least one of the seed crystal substrates is placed non-adhesively to the base plate,

wherein an inclination support member is used as the position regulating unit to support the seed crystal substrates placed on the outer peripheral edge portion of the seed crystal substrate assembly in a posture inclined so that the outer peripheral side of the seed crystal substrates placed on the outer peripheral edge portion of the seed crystal substrate assembly becomes higher.

4. A method for manufacturing a nitride crystal substrate according to claim 1 , wherein each of the plurality of seed crystal substrates is a low warpage substrate with a curvature radius of the c-plane being 20 meters or more.

5. A method for manufacturing a nitride crystal substrate according to claim 2 , wherein each of the plurality of seed crystal substrates is a low warpage substrate with a curvature radius of the c-plane being 20 meters or more.

6. A method for manufacturing a nitride crystal substrate according to claim 3 , wherein each of the plurality of seed crystal substrates is a low warpage substrate with a curvature radius of the c-plane being 20 meters or more.