IP Library › Granted Patent US 10,308,743
Granted Patent B2
US 10,308,743 · App. 15/722,091 · Granted Jun 4, 2019

Water-soluble or water-disintegrable copolymer

Inventors: Juan-Carlos Ruggieri (Joncy, FR); Herbert Leder (Sinzheim, DE); Frank Osan (Kelkheim im Taunus, DE)
Assignee: BellandTechnology AG
C08F220/06C08F220/18C08F220/28
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Quick Facts
Patent No.
US 10,308,743
App. No.
15/722,091
Granted
Jun 4, 2019
Kind
B2
Abstract

A copolymer is based on α-β-unsaturated monocarboxylic acid, wherein the copolymer has a molar mass <100 000 g/mol. A process of preparing the copolymer compound includes mixing a copolymer in a melt with an impact modifier under action of shearing forces, a proportion of copolymer and impact modifier being selected preferably such that the copolymer forms a continuous phase and the impact modifier forms a discontinuous phase.

Claims (16)

1. A random copolymer based on α-β-unsaturated monocarboxylic acid, wherein the copolymer has a molar mass of 30,000 to <100 000 g/mol and a polydispersity of 2 to 3, and wherein the α-β-unsaturated monocarboxylic acid has a weight fraction of>50% by weight, based on the total weight of the copolymer, wherein the copolymer is in a form of a strand or profile, and the copolymer has in addition to the α-β-unsaturated monocarboxylic acid as comonomer an alkyl ester and/or alkoxy alkyl ester, of an α-β-unsaturated monocarboxylic acid.

2. The random copolymer according to claim 1 , wherein the molar mass is 30,000 g/mol to 90,000 g/mol.

3. The random copolymer according to claim 1 , wherein the α-β-unsaturated monocarboxylic acid has a weight fraction of 60% by weight to 95% by weight, based on the total weight of the copolymer.

4. The random copolymer according to claim 1 , wherein the ester of the α-β-unsaturated monocarboxylic acid is selected from the group consisting of methyl acrylate, ethyl acrylate, n-butyl acrylate, isobutyl acrylate, methoxyethyl acrylate, glycidyl acrylate, methyl methacrylate, ethyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, methoxyethyl methacrylate, glycidyl methacrylate and mixtures thereof.

5. The random copolymer according to claim 1 , wherein the ester has a weight fraction of 5% by weight to 40% by weight, based on the total weight of the copolymer.

6. The random copolymer according to claim 1 , wherein the copolymer is a copolymer of the α-β-unsaturated monocarboxylic acid and an ester of an α-β-unsaturated monocarboxylic acid.

7. A random copolymer based on α-β-unsaturated monocarboxylic acid, wherein the copolymer has a molar mass of 30,000 to <100 000 g/mol and a polydispersity of 2 to 3, the α-β-unsaturated monocarboxylic acid has a weight fraction of>50% by weight, based on the total weight of the copolymer, the copolymer is in a form of a strand or profile, and the copolymer is a solution copolymer.

8. The random copolymer according to claim 1 , wherein the copolymer has a glass transition temperature of 60° C. to 140° C.

9. The random copolymer according to claim 1 , wherein the copolymer has a melt flow index of 5 g/10 min to 50 g/10 min.

10. The random copolymer according to claim 1 , wherein the copolymer is disintegrable or soluble or substantially soluble in an aqueous, pH-neutral environment and/or in an aqueous, alkaline environment.

11. The copolymer according to claim 1 , wherein the copolymer is provided or compounded with an impact modifier reactive toward carboxyl groups.

12. The copolymer according to claim 11 , wherein the impact modifier has a weight fraction of 10% by weight to 40% by weight, based on the total weight of the copolymer provided or compounded with the impact modifier.

13. A process of preparing the copolymer according to claim 1 , wherein an α-β-unsaturated monocarboxylic acid and a comonomer comprising an ester of an α-β-unsaturated monocarboxylic acid, are copolymerized in solution.

14. A copolymer compound comprising a copolymer according to claim 1 , and an impact modifier.

15. A process of preparing a copolymer compound according to claim 14 , comprising mixing a copolymer in a melt with an impact modifier under action of shearing forces, a proportion of copolymer and impact modifier being selected preferably such that the copolymer forms a continuous phase and the impact modifier forms a discontinuous phase.

16. A random copolymer based on α-β-unsaturated monocarboxylic acid, wherein the copolymer has a molar mass of 30,000 to <100 000 g/mol and a polydispersity of 2 to 3, the α-β-unsaturated monocarboxylic acid has a weight fraction of>50% by weight, based on the total weight of the copolymer, the copolymer is in a form of a strand or profile, and the copolymer has in addition to the α-β-unsaturated monocarboxylic acid as comonomer an ester of an α-β-unsaturated monocarboxylic acid.

Assignments (2)
CORRECTIVE ASSIGNMENT TO CORRECT THE ASSIGNEES'S ADDRESS PREVIOUSLY RECORDED ON REEL 043753 FRAME 0903. ASSIGNOR(S) HEREBY CONFIRMS THE CORRECT ADDRESS IS KÜHLENFELSER STR.47, 91278 POTTENSTEIN, GERMANY. Recorded Jun 25, 2018
From: RUGGIERI, JUAN-CARLOS; LEDER, HERBERT; OSAN, FRANK
To: BELLANDTECHNOLOGY AG
Reel/Frame 046423/0038 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 2, 2017
From: RUGGIERI, JUAN-CARLOS; LEDER, HERBERT; OSAN, FRANK
To: BELLANDTECHNOLOGY AG
Reel/Frame 043753/0903 →
Priority Claims (1)
EP 10189433 · Oct 29, 2010 · regional
Continuity (3)
Division 15187974 · Jun 21, 2016
Division 13881536
Related Publication 20180022847A1 · Jan 25, 2018
Cited By (1)
US 12,624,161